Inorganic Chemistry
5th Edition
ISBN: 9781292134147
Author: Housecroft, Catherine E.
Publisher: Pearson,
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Chapter 1, Problem 32P
(a) Write down an equation that defines the process to which the value of
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Chapter 1 Solutions
Inorganic Chemistry
Ch. 1 - Chromium has four isotopes C2450r, C2452r, C2453r...Ch. 1 - Prob. 2PCh. 1 - Using the list of naturally occurring isotopes in...Ch. 1 - Hydrogen possesses three isotopes, but tritium ,...Ch. 1 - (a) By using the data in appendix 5, account for...Ch. 1 - Calculate the corresponding wavelength of...Ch. 1 - State which of the following n'n transitions in...Ch. 1 - Calculate the energy (in kJ per mole of photons)...Ch. 1 - 1.9 Four of the lines in Balmer series are at...Ch. 1 - 1.10 Using the Bohr model, determine the values of...
Ch. 1 - 1.11 How is the (a) energy and (b) size of an ns...Ch. 1 - 1.12 Write down a set of quantum numbers that...Ch. 1 - Do the three 4p atomic orbitals possess the same...Ch. 1 - How many radial nodes does each of the following...Ch. 1 - 1.15 Comment on the differences between plots of...Ch. 1 - 1.16 Write down the sets of quantum numbers that...Ch. 1 - Write down the three sets of quantum numbers that...Ch. 1 - How many atomic orbitals make up the set with n=4...Ch. 1 - Prob. 19PCh. 1 - (a) Will a plot of R(r) for the 1s atomic orbital...Ch. 1 - Prob. 21PCh. 1 - Prob. 22PCh. 1 - Write down the six sets of quantum numbers that...Ch. 1 - For a neutral atom, X, the following atomic...Ch. 1 - Using the concepts of shielding and penetration,...Ch. 1 - For each of the following atoms, write down a...Ch. 1 - 1.27 Draw energy level diagrams (see Fig. 1.15) to...Ch. 1 - 1.28 Write down the ground state electronic...Ch. 1 - Write down (with reasoning) the ground state...Ch. 1 - Draw energy level diagrams to show the ground...Ch. 1 - The ground state electronic configuration of a...Ch. 1 - (a) Write down an equation that defines the...Ch. 1 - 1.33 The first four ionization energies of an atom...Ch. 1 - 1.34 In Fig. 1.16, identify the trend in the first...Ch. 1 - 1.35 Figure 1.17 shows the values of for the...Ch. 1 - Using the data in Table 1.5, determine a value for...Ch. 1 - Prob. 37PCh. 1 - What is the evidence that the aufbau principle is...Ch. 1 - The first list in the table on the left contains...Ch. 1 - Prob. 40PCh. 1 - Using data from appendix 8, construct a graph to...Ch. 1 - The sign convention for electron affinity can...Ch. 1 - Prob. 43PCh. 1 - 1.45 Figure 1.18 shows the emission spectrum of...
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- Which of the four atoms Na, P, Cl, or K (a) has the largest atomic radius? (b) has the highest ionization energy? (c) is the most electronegative?arrow_forwardOf the five elements Sn, Si, Sb, O, Te, which has the most endothermic reaction? (E represents an atom.) What name is given to the energy for the reaction? E(g)E+(g)+earrow_forwardA) Which of the halogen elements has the highest density in its standard state? B) Which of the elements of the third period should have the highest 2nd ionization energy? C) For which of Al, Si or P is the absolute value of the Electron Affinity greatest? D) Which of the ions Mg2+, Sr2+, Ca2+, Be2+, Ba2+, or Ra2+ is the smallest? E) For the elements: X = Br, I, Cl, or H, which has the the smallest average X-C bond energy?arrow_forward
- Calculate the energy (a) in eV and (b) in joules of the third energy level (n=3) of a hydrogen atom.arrow_forwardWrite any two multiplicities of higher energy in the form 2s+1L J, giving a diagrammatic illustration of each.arrow_forwardAt large interatomic separations, an alkali halide moleculeMX has a lower energy as two neutral atoms, M + X; atshort separations, the ionic form (M+)(X-) has a lowerenergy. At a certain distance, Rc, the energies of the twoforms become equal, and it is near this distance that theelectron will jump from the metal to the halogen atom during a collision. Because the forces between neutral atomsare weak at large distances, a reasonably good approximation can be made by ignoring any variation in potentialV(R) for the neutral atoms between Rc and R - `. For theions in this distance range, V(R) is dominated by theirCoulomb attraction.(a) Express Rc for the first ionization energy of the metalM and the electron affinity of the halogen X.(b) Calculate Rc for LiF, KBr, and NaCl using data fromAppendix F.arrow_forward
- In group 15 elements, there is considerable increase in covalent radius from N to P but small increase from As to Bi. Why?arrow_forwardThe first three ionization energies of an element X are 900, 1745, and 14912 kJ·mol–1. What is the most likely formula for the stable ion of X?arrow_forwardThe lattice energy of an ionic solid such as NaCl is the enthalpy change H for the process in which the solid changes to ions. For example, NaCl(s)Na+(g)+Cl(g)H=786kJ/mol Assume that the ionization energy and electron a affinity are H values for the processes defined by those terms. The ionization energy of Na is 496 kJ/mol. Use this, the electron affinity from Table 8.4, and the lattice energy of NaCl to calculate H for the following process: Na(g)+Cl(g)NaCl(s)arrow_forward
- Palladium, with an electron configuration of [Kr] 4d10, is an exception to the aufbau principle. Write the electron configuration of the 2+ cation of palladium. Does the fact that palladium is an exception influence the electron configuration of Pd2+?arrow_forwardIn a lithium-ionbattery that is discharging to power a device, for every Li+that inserts into the lithium cobalt oxide electrode, a Co4+ion must be reduced to a Co3+ ion to balance charge. Usingthe CRC Handbook of Chemistry and Physics or other standardreference, find the ionic radii of Li+, Co3+, and Co4+. Orderthese ions from smallest to largest.arrow_forwardUse the periodic table to arrange the following elements in order of increasing firstionisation energy: P, S, O. Give a brief explanation why you chose this arrangement.arrow_forward
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