ORGANIC CHEMISTRY W/SSM >CB<
8th Edition
ISBN: 9781323748688
Author: Bruice
Publisher: PEARSON C
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Textbook Question
Chapter 1, Problem 55P
Draw a Lewis structure for each of the following:
- a. CH3NH2
- b. HNO2
- c. NaNH2
- d. NH2O–
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Chapter 1 Solutions
ORGANIC CHEMISTRY W/SSM >CB<
Ch. 1.1 - Oxygen has three isotopes, 16O, 17O, and 18O. The...Ch. 1.1 - a. How many protons do the following species...Ch. 1.1 - Chlorine has two isotopes, 35Cl and 37Cl; 75.77%...Ch. 1.2 - Prob. 4PCh. 1.2 - a. Write the ground-state electronic configuration...Ch. 1.2 - Look at the relative positions of each pair of...Ch. 1.3 - a. Find potassium (K) in the periodic table and...Ch. 1.3 - Which bond is more polar? a. b. c. d.Ch. 1.3 - Which of the following has a. the most polar bond?...Ch. 1.3 - Use the symbols + and to show the direction of...
Ch. 1.3 - Explain why HCL has a smaller dipole moment than...Ch. 1.3 - After examining the potential maps for LiH, HF,...Ch. 1.4 - An atom with a formal charge does not necessarily...Ch. 1.4 - Prob. 16PCh. 1.4 - a. Draw two Lewis structure for C2H6O. b. Draw...Ch. 1.4 - Draw the lone-pair electrons that are not shown in...Ch. 1.4 - Prob. 20PCh. 1.4 - Which of the atoms in the molecular models in...Ch. 1.4 - Prob. 22PCh. 1.4 - Prob. 23PCh. 1.5 - Draw the following orbitals: a. 3s orbital b. 4s...Ch. 1.6 - Prob. 25PCh. 1.6 - Indicate the kind of molecular orbital (, , , or )...Ch. 1.7 - What orbitals are used to form the 10 sigma bonds...Ch. 1.7 - Explain why a bond formed by overlap of s orbital...Ch. 1.9 - Put n number in each of the blanks: a. __ s...Ch. 1.9 - For each of the given species: a. Draw its Lewis...Ch. 1.11 - Predict the approximate bond angles in a. the...Ch. 1.11 - According to the potential map for the ammonium...Ch. 1.12 - Prob. 35PCh. 1.13 - a. What are the relative lengths and strengths of...Ch. 1.13 - Prob. 38PCh. 1.14 - Describe the orbitals used in bonding and the bond...Ch. 1.15 - Which of the bond in a carbon-oxygen double bond...Ch. 1.15 - Would you expect a CC bond formed by sp2sp2...Ch. 1.15 - Caffeine is a natural insecticide found in the...Ch. 1.15 - a. What is the hybridization of each of the carbon...Ch. 1.15 - Predict the approximate bond angles for a. the CNC...Ch. 1.16 - What of the following molecules would you expect...Ch. 1.16 - Account for the difference in the shape and color...Ch. 1.16 - If the dipole moment of CH3F is 1.847 D and the...Ch. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - Prob. 50PCh. 1 - What is the hybridization of all the atoms (other...Ch. 1 - Draw the condensed structure of a compound that...Ch. 1 - Predict the approximate bond angles: a. the CNH...Ch. 1 - Prob. 54PCh. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - What is the hybridization of each of the carbon...Ch. 1 - Rank the bonds from most polar. a. CO, CF, CN b....Ch. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - Prob. 59PCh. 1 - What is the hybridization of the indicated atom in...Ch. 1 - Predict the approximate bond angles for the...Ch. 1 - Prob. 62PCh. 1 - Draw the missing lone-pair electrons and assigns...Ch. 1 - a. Which of the indicated bonds in each molecule...Ch. 1 - For each of the following molecules, indicate the...Ch. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - Prob. 67PCh. 1 - Rank the following compounds from highest dipole...Ch. 1 - In which orbitals are the lone pairs in nicotine?Ch. 1 - Prob. 70PCh. 1 - Prob. 71PCh. 1 - a. Which of the species have bond angles of 109.5?...Ch. 1 - Prob. 73PCh. 1 - Which compound has a larger dipole moment: CH3Cl...Ch. 1 - Prob. 75PCh. 1 - Explain why CH3Cl has a greater dipole moment than...Ch. 1 - a. Draw a Lewis structure for each of the...Ch. 1 - There are three isomers with molecular formula...
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- Which of the following species will combine with a chloride ion to produce ammonium chloride? a.NH3 b.K+ c.NH4+ d.Al+++arrow_forwardDraw a Lewis structure and use VSEPR theory to determine the geometry of each molecule. If the molecule has more than one central atom, indicate the geometry about each of these and draw the three-dimensional structure. a.ClNO(nitrogenisthecentralatom)b.H3CCH3(twocarbonatomsinthemiddle,eachwiththreehydrogenatomsattached)c.N2F2(nitrogenatomsinthecenterandfluorineatomsontheends)d.N2H4(nitrogenatomsinthecenterandtwohydrogenatomsattachedtoeachnitrogen)arrow_forwardDraw the Lewis structures and predict the shape of each compound or ion: (a) CO2 (b) NO2 (c) SO3 (d)SO32arrow_forward
- a.) Atom A is more electronegative and will have a d+ in an A-B bond b.) Atom B is more electronegative and will have a d- in an A-B bond c.) Atom B is more electronegative and will have a d+ in an A-B bond d.) Atom A is more electronegative and will have a d- in an A-B bondarrow_forward3. A. Draw and label an energy diagram for a slow endothermic reaction B. A weather balloon contains 222 L of helium gas at 20.8 °C and 754 mm Hg. What is the volume in liters of the balloon when it rises to an altitude where the pressure is 552 mm Hg and the temperature is -40.0 °C C. Draw two different Lewis structures for C2H4O2, connecting the atoms differently in your two structures. Label the shape of each carbon atom in both structures.arrow_forwardDraw an octet-rule Lewis structure for POCl3: Total count of valence e¯’s: a) in the formula = __ b) as dots and dashes in your O.R.-Lewis structure = _____ Bond orders: P–O _______ P–Cl _______ (like triple in N2, single in H2O …) Count e¯-groups around P: _____ --> e¯-group shape around P is ________________ Molecular shape is _______________ The molecule is ? not polar (mark one) Oxidation numbers: O ____ Cl ____ P ____arrow_forward
- 29. Draw the Lewis structure for SiS₂arrow_forwardPredict the electron pair geometry and the molecular structure of each of the following molecules or ions: (a) SF6 (b) PCl5 (c) BeH2 (d) CH3+arrow_forward7.37 Draw the Lewis structure for each of the following molecules. (a) CO , (b) H2S , (c) SF6 , (d) NCl3arrow_forward
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