ORGANIC CHEMISTRY W/ST.GDE W/ACCESS
8th Edition
ISBN: 9780134892566
Author: Bruice
Publisher: PEARSON
expand_more
expand_more
format_list_bulleted
Concept explainers
Textbook Question
Chapter 1, Problem 66P
Draw a Lewis structure for each of the following:
- a. (CH3)3COH
- b. CH3CH(OH)CH2CN
- c. (CH3)2CHCH(CH3)CH2C(CH3)3
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
the context is "Cosmone is a molecule used by fragrance manufacturers to provide a rich and elegant musky essence to many perfumes. Cosmone has the molecular formula C15H26O." I need help on part (e) and (f).
10.12 Answer true or false. (a) In organic compounds, carbon normally has fourbonds and no unshared pairs of electrons. (b) When found in organic compounds, nitrogen nor-mally has three bonds and one unshared pair ofelectrons. (c) The most common bond angles about carbon inorganic compounds are approximately 109.5°and 180°.
1. (A) Provide an example for each of the following:
(a) a molecule that only has dispersion forces as IMFs
(b) a molecule that has dispersion and dipolar IMFs
(c) a molecule that can experience hydrogen bonding
(B) Why does NH3 have a higher boiling point than BH3? To answer this question, draw out the Lewis structure for each molecule, and then draw out the VSEPR shape for each molecule.
Chapter 1 Solutions
ORGANIC CHEMISTRY W/ST.GDE W/ACCESS
Ch. 1.1 - Oxygen has three isotopes, 16O, 17O, and 18O. The...Ch. 1.1 - a. How many protons do the following species...Ch. 1.1 - Chlorine has two isotopes, 35Cl and 37Cl; 75.77%...Ch. 1.2 - Prob. 4PCh. 1.2 - a. Write the ground-state electronic configuration...Ch. 1.2 - Look at the relative positions of each pair of...Ch. 1.3 - a. Find potassium (K) in the periodic table and...Ch. 1.3 - Which bond is more polar? a. b. c. d.Ch. 1.3 - Which of the following has a. the most polar bond?...Ch. 1.3 - Use the symbols + and to show the direction of...
Ch. 1.3 - Explain why HCL has a smaller dipole moment than...Ch. 1.3 - After examining the potential maps for LiH, HF,...Ch. 1.4 - An atom with a formal charge does not necessarily...Ch. 1.4 - Prob. 16PCh. 1.4 - a. Draw two Lewis structure for C2H6O. b. Draw...Ch. 1.4 - Draw the lone-pair electrons that are not shown in...Ch. 1.4 - Prob. 20PCh. 1.4 - Which of the atoms in the molecular models in...Ch. 1.4 - Prob. 22PCh. 1.4 - Prob. 23PCh. 1.5 - Draw the following orbitals: a. 3s orbital b. 4s...Ch. 1.6 - Prob. 25PCh. 1.6 - Indicate the kind of molecular orbital (, , , or )...Ch. 1.7 - What orbitals are used to form the 10 sigma bonds...Ch. 1.7 - Explain why a bond formed by overlap of s orbital...Ch. 1.9 - Put n number in each of the blanks: a. __ s...Ch. 1.9 - For each of the given species: a. Draw its Lewis...Ch. 1.11 - Predict the approximate bond angles in a. the...Ch. 1.11 - According to the potential map for the ammonium...Ch. 1.12 - Prob. 35PCh. 1.13 - a. What are the relative lengths and strengths of...Ch. 1.13 - Prob. 38PCh. 1.14 - Describe the orbitals used in bonding and the bond...Ch. 1.15 - Which of the bond in a carbon-oxygen double bond...Ch. 1.15 - Would you expect a CC bond formed by sp2sp2...Ch. 1.15 - Caffeine is a natural insecticide found in the...Ch. 1.15 - a. What is the hybridization of each of the carbon...Ch. 1.15 - Predict the approximate bond angles for a. the CNC...Ch. 1.16 - What of the following molecules would you expect...Ch. 1.16 - Account for the difference in the shape and color...Ch. 1.16 - If the dipole moment of CH3F is 1.847 D and the...Ch. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - Prob. 50PCh. 1 - What is the hybridization of all the atoms (other...Ch. 1 - Draw the condensed structure of a compound that...Ch. 1 - Predict the approximate bond angles: a. the CNH...Ch. 1 - Prob. 54PCh. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - What is the hybridization of each of the carbon...Ch. 1 - Rank the bonds from most polar. a. CO, CF, CN b....Ch. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - Prob. 59PCh. 1 - What is the hybridization of the indicated atom in...Ch. 1 - Predict the approximate bond angles for the...Ch. 1 - Prob. 62PCh. 1 - Draw the missing lone-pair electrons and assigns...Ch. 1 - a. Which of the indicated bonds in each molecule...Ch. 1 - For each of the following molecules, indicate the...Ch. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - Prob. 67PCh. 1 - Rank the following compounds from highest dipole...Ch. 1 - In which orbitals are the lone pairs in nicotine?Ch. 1 - Prob. 70PCh. 1 - Prob. 71PCh. 1 - a. Which of the species have bond angles of 109.5?...Ch. 1 - Prob. 73PCh. 1 - Which compound has a larger dipole moment: CH3Cl...Ch. 1 - Prob. 75PCh. 1 - Explain why CH3Cl has a greater dipole moment than...Ch. 1 - a. Draw a Lewis structure for each of the...Ch. 1 - There are three isomers with molecular formula...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- A. Draw the structure for compound X at pH=9. What is the charge of the molecule? B. Draw the structure for Compound X at pH=2. What is the charge of the molecule?arrow_forwardConsider the molecule CO. If the electronegativity of C is 2.5 and the electronegativity of O is 3.5: Group of answer choices the C≡O bond is polar; the C is electron rich and the O is electron poor. the C≡O bond is non-polar. the C≡O bond is polar; the C is electron poor and the O is electron rich. the C≡O bond is polar; both the C and the O are electron rich.arrow_forward3. A. Draw and label an energy diagram for a slow endothermic reaction B. A weather balloon contains 222 L of helium gas at 20.8 °C and 754 mm Hg. What is the volume in liters of the balloon when it rises to an altitude where the pressure is 552 mm Hg and the temperature is -40.0 °C C. Draw two different Lewis structures for C2H4O2, connecting the atoms differently in your two structures. Label the shape of each carbon atom in both structures.arrow_forward
- 7.35 Which one of the following contains botb ionic and covalent bonds? (a) BaCO3 , (b) MgCl2 , (c) BaO , (d) H2S , (e) So42arrow_forwardWhy is the HNH angle in NH3 smaller than the HCH bond angle in CH4? Why is the HNH angle in NH4+ identical to the HCH bond angle in CH4?arrow_forwardBreak compound A into several small (less or equals to 6 carbon atom) molecules. You need to explain the reasons why you choose to break those bonds.arrow_forward
- the context is "Cosmone is a molecule used by fragrance manufacturers to provide a rich and elegant musky essence to many perfumes. Cosmone has the molecular formula C15H26O." I need help on part (h).arrow_forwardHow many equivalent carbons are in C2H3Cl3 ? A) 2 B) 1 C) 0 D) 3arrow_forwardHow many moles of bonds between which pairs of atoms are broken during the combustion of 3 moles of methane (CH4) gas? Treat a double bond or a triple bond as one bonding interaction (i.e., 1 mole of triple bonds equals 1 mole of bonds). Choose one or more: A. 12 moles O–H bonds B. 6 moles of C–O bonds C. 3 moles of C–O bonds D. 6 moles of O–H bonds E. 3 moles of C–H bonds F. 6 moles of O–O bonds G. 12 moles of C–H bondsarrow_forward
- methanol (image) there are five chemical bonds, three of which are between different kinds of atoms.1. What are the three bonds between different kinds of atoms? Use electronegativityvalues to rank the three bonds from most to least polar.2. Each atom has a number. Some atoms will have a slight positive or negative charge.Write who has what. Explain why.3. One of the four hydrogen atoms will be able to participate in hydrogen bonds. Which one and why?arrow_forwardConsider Unknown Chemical X A. Chemical X is covalent and has the generic chemical formula of YZ3. Atom Y has 5 valence electrons. Each Atom Z has 1 valence electron. Identify the molecular geometry and bond angles. B. Draw a 3D structure with dipoles and slight charges for Chemical X given the following electronegativity values: Y = 2.8 Z = 1.9 C. Identify Chemical X as polar or nonpolar overall. D. Jason predicts Chemical X would have a higher melting point than methane (CH4). Do you agree or disagree with Jason? Justify your response with intermolecular forces.arrow_forwardRefer to the nomenclature flowchart (Figure 3.11) to name each compound.a. KClO3 b. I2O5 c. PbSO4arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry for Engineering StudentsChemistryISBN:9781337398909Author:Lawrence S. Brown, Tom HolmePublisher:Cengage LearningIntroductory Chemistry: A FoundationChemistryISBN:9781337399425Author:Steven S. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStax
- Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningPrinciples of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage Learning
Chemistry for Engineering Students
Chemistry
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Cengage Learning
Introductory Chemistry: A Foundation
Chemistry
ISBN:9781337399425
Author:Steven S. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:OpenStax
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning
Types of bonds; Author: Edspira;https://www.youtube.com/watch?v=Jj0V01Arebk;License: Standard YouTube License, CC-BY