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Concept explainers
When a gaseous compound X containing only C, H, and O is burned in
(a) Calculate a formula for the unknown gas, and write a balanced equation for the combustion reaction.
(b) Is the formula you calculated an empirical formula or a molecular formula? Explain.
(c) Draw two different possible electron-dot structures for the compound X.
(d) Combustion of 5.000 g of X releases 144.2 kJ heat. Look up
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Chapter 10 Solutions
Chemistry, Books a la Carte Edition and Modified Mastering Chemistry with Pearson eText & ValuePack Access Card (7th Edition)
- Pyruvic acid, HC3H3O3, is involved in cell metabolism. It can be assayed for (that is, the amount of it determined) by using a yeast enzyme. The enzyme makes the following reaction go to completion: HC3H3O3(aq)C2H4O(aq)+CO2(g) If a sample containing pyruvic acid gives 21.2 mL of carbon dioxide gas, CO2, at 349 mmHg and 30C, how many grams of pyruvic acid are there in the sample?arrow_forwardSilane, SiH4, is the silicon analogue of methane, CH4. It is prepared industrially according to the following equations: Si(s)+3HC1(g)HSiCl3(l)+H2(g)4HSiCl3(l)SiH4(g)+3SiCl4(l) a. If 156 mL HSiCl3 (d = 1.34 g/mL) is isolated when 15.0 L HC1 at 10.0 atm and 35C is used, what is the percent yield of HSiCl3? b. When 156 mL HSiCl3 is heated, what volume of SiH4 at 10.0 atm and 35C will be obtained if the percent yield of the reaction is 93.1%?arrow_forwardLiquid oxygen was first prepared by heating potassium chlorate, KClO3, in a closed vessel to obtain oxygen at high pressure. The oxygen was cooled until it liquefied. 2KClO3(s)2KCl(s)+3O2(g) If 171 g of potassium chlorate reacts in a 2.70-L vessel, which was initially evacuated, what pressure of oxygen will be attained when the temperature is finally cooled to 25C? Use the preceding chemical equation and ignore the volume of solid product.arrow_forward
- A mixture contained zinc sulfide, ZnS, and lead sulfide, PbS. A sample of the mixture weighing 6.12 g was reacted with an excess of hydrochloric acid. The reactions are ZnS(s)+2HCL(aq)ZnCl2(aq)+H2S(g)PbS(s)+2HCL(aq)PbCl2(aq)+H2S(g) If the sample reacted completely and produced 1.049 L of hydrogen sulfide, H2S, at 23C and 762 mmHg, what were the percentages of ZnS and PbS in the mixture?arrow_forwardDichlorine oxide is used as bactericide to purify water. It is produced by the chlorination of sulfur dioxide gas. SO2(g)+2Cl2(g)SOCl2(l)+Cl2O(g)How many liters of Cl2O can be produced by mixing 5.85 L of SO2 and 9.00 L of Cl2? How many liters of the reactant in excess are present after reaction is complete? Assume 100% yield and that all the gases are measured at the same temperature and pressure.arrow_forwardYou have a 550.-mL tank of gas with a pressure of 1.56 atm at 24 C. You thought the gas was pure carbon monoxide gas, CO, but you later found it was contaminated by small quantities of gaseous CO2 and O2. Analysis shows that the tank pressure is 1.34 atm (at 24 C) if the CO2 is removed. Another experiment shows that 0.0870 g of O2 can be removed chemically. What are the masses of CO and CO2 in the tank, and what is the partial pressure of each of the three gases at 25 C?arrow_forward
- A student prepares phosphorous acid, H3PO3, by reacting solid phosphorus triiodide with water. PI3(s)+3H2O(l)H3PO3(s)+3HI(g) The student needs to obtain 0.250 L of H3PO3(d=1.651g/cm3). The procedure calls for a 45.0% excess of water and a yield of 75.0%. How much phosphorus triiodide should be weighed out? What volume of water (d=1.651g/cm3) should be used?arrow_forwardTitanium(III) chloride is used in the manufacture of polyethylene. It is produced by the reaction (at high temperatures) between TiCl4 gas and H2. 2TiCl4(g)+H2(g)2TiCl3(s)+2HCl(g)Assume 100% yield and constant temperature and pressure. (a) How many liters of HCI gas can be produced by mixing 3.72 L of TiCl4 and 4.50 L of H2? (b) How many liters of reactant in excess are present after the reaction is complete?arrow_forward47 HCl(g) reacts with ammonia gas, NH3(g), to form solid ammonium chloride. If a sample of ammonia occupying 250 mL at 21 C and a pressure of 140 torr is allowed to react with excess HCl, what mass of NH4Cl will form?arrow_forward
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