Inorganic Chemistry
5th Edition
ISBN: 9780321811059
Author: Gary L. Miessler, Paul J. Fischer, Donald A. Tarr
Publisher: Prentice Hall
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- Would you expect the complex [Co(en)3]Cl3 to have any unpaired electrons? Any isomers?arrow_forwardTrimethylphosphine, P(CH3)3, can act as a ligand by donating the lone pair of electrons on the phosphorus atom. If trimethylphosphine is added to a solution of nickel(Il) chloride in acetone, a blue compound that has a molecular mass of approximately 270 g and contains 21.5% Ni, 26.0% Cl, and 52.5% P(CH3)3 can be isolated. This blue compound does not have any isomeric forms. What are the geometry and molecular formula of the blue compound?arrow_forwardWhich of the following ligands is expected to be monodentate, and which might be polydentate? (a) CH3NH2 (b) CH3CN (c) N3 (d) en (e) Br (f) phenarrow_forward
- The square-planar complex Pt(en)Cl2 has chloride ligands in a cis configuration. No trans isomer is known. Based on the bond lengths and bond angles of carbon and nitrogen in the ethylenediamine ligand, explain why the trans compound is not possible.arrow_forwardExperiments show that K4[Cr(CN)6] is paramagnetic and has two unpaired electrons. The related complex K4[Cr(SCN)6] is paramagnetic and has four unpaired electrons. Account for the magnetism of each compound using the ligand field model. Predict where the SCN ion occurs in the spectro-chemical series relative to CN.arrow_forwardTwo different compounds are known with the formula Pd(py)2Cl2, but there is only one compound with the formula Zn(py)2Cl2. The symbol py is for pyridine, a mono-dentate ligand. Explain the differences in the Pd and Zncompounds.arrow_forward
- Is it possible for a complex of a metal in the transition series to have six unpaired electrons? Explain.arrow_forwardFor complexes of the same metal ion with no change in oxidation number, the stability increases as the number of electrons in the t2g orbitals increases. Which complex in each of the following pairs of complexes is more stable? (a) [Fe(H2O)6]2+ or [Fe(CN)6]4-. (b) [Co(NH3)6]3+ or [CoF6]3-. (c) [Mn(CN)6]4- or [MnCl6]4-arrow_forward
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