The reason as to why the addition of HBr to alkenes A and C forms the addition products B and D is to be stated. Concept introduction: According to Markovinokov’s rule, the positive part of halogen acid attached to that carbon atom in C=C bond which carries maximum number of hydrogen atoms and the negative part of halogen acid will attach to that carbon atom in C=C bond which has minimum number of hydrogen atoms. The steps followed by electrophilic addition reaction are stated below: • First protonation of the alkene take place to generate the carbocation. • The halide ion will attack on the carbocation to give the final product.

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Answer 1

Question

Chapter 10, Problem 10.65P

Interpretation Introduction

Interpretation: The reason as to why the addition of HBr to alkenes A and C forms the addition products B and D is to be stated.

Concept introduction: According to Markovinokov’s rule, the positive part of halogen acid attached to that carbon atom in C=C bond which carries maximum number of hydrogen atoms and the negative part of halogen acid will attach to that carbon atom in C=C bond which has minimum number of hydrogen atoms.

The steps followed by electrophilic addition reaction are stated below:

• First protonation of the alkene take place to generate the carbocation.

• The halide ion will attack on the carbocation to give the final product.

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Explain why the addition of HBr to alkenes A and C is regioselective,forming addition products B and D, respectively.

(a) What is the major alkene formed when A is dehydrated with HS2O4? (b) What is the major alkene formed when A is treated with POCl3 and pyridine? Explain why the major product is different in these reactions.

Explain the characteristics of electrophilic addition of HX to alkenes ?

Answer 2

Question

Chapter 10, Problem 10.65P

Interpretation Introduction

Interpretation: The reason as to why the addition of HBr to alkenes A and C forms the addition products B and D is to be stated.

Concept introduction: According to Markovinokov’s rule, the positive part of halogen acid attached to that carbon atom in C=C bond which carries maximum number of hydrogen atoms and the negative part of halogen acid will attach to that carbon atom in C=C bond which has minimum number of hydrogen atoms.

The steps followed by electrophilic addition reaction are stated below:

• First protonation of the alkene take place to generate the carbocation.

• The halide ion will attack on the carbocation to give the final product.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 10, Problem 10.65P

Interpretation Introduction

Interpretation: The reason as to why the addition of HBr to alkenes A and C forms the addition products B and D is to be stated.

Concept introduction: According to Markovinokov’s rule, the positive part of halogen acid attached to that carbon atom in C=C bond which carries maximum number of hydrogen atoms and the negative part of halogen acid will attach to that carbon atom in C=C bond which has minimum number of hydrogen atoms.

The steps followed by electrophilic addition reaction are stated below:

• First protonation of the alkene take place to generate the carbocation.

• The halide ion will attack on the carbocation to give the final product.

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Answer 4

Question

Chapter 10, Problem 10.65P

Interpretation Introduction

Interpretation: The reason as to why the addition of HBr to alkenes A and C forms the addition products B and D is to be stated.

Concept introduction: According to Markovinokov’s rule, the positive part of halogen acid attached to that carbon atom in C=C bond which carries maximum number of hydrogen atoms and the negative part of halogen acid will attach to that carbon atom in C=C bond which has minimum number of hydrogen atoms.

The steps followed by electrophilic addition reaction are stated below:

• First protonation of the alkene take place to generate the carbocation.

• The halide ion will attack on the carbocation to give the final product.

Expert Solution & Answer

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Answer 5

Chapter 10, Problem 10.65P

Interpretation Introduction

Interpretation: The reason as to why the addition of HBr to alkenes A and C forms the addition products B and D is to be stated.

Concept introduction: According to Markovinokov’s rule, the positive part of halogen acid attached to that carbon atom in C=C bond which carries maximum number of hydrogen atoms and the negative part of halogen acid will attach to that carbon atom in C=C bond which has minimum number of hydrogen atoms.

The steps followed by electrophilic addition reaction are stated below:

• First protonation of the alkene take place to generate the carbocation.

• The halide ion will attack on the carbocation to give the final product.

Answer 6

Chapter 10, Problem 10.65P

Interpretation Introduction

Interpretation: The reason as to why the addition of HBr to alkenes A and C forms the addition products B and D is to be stated.

Concept introduction: According to Markovinokov’s rule, the positive part of halogen acid attached to that carbon atom in C=C bond which carries maximum number of hydrogen atoms and the negative part of halogen acid will attach to that carbon atom in C=C bond which has minimum number of hydrogen atoms.

The steps followed by electrophilic addition reaction are stated below:

• First protonation of the alkene take place to generate the carbocation.

• The halide ion will attack on the carbocation to give the final product.

Answer 7

Chapter 10, Problem 10.65P

Interpretation Introduction

Interpretation: The reason as to why the addition of HBr to alkenes A and C forms the addition products B and D is to be stated.

Concept introduction: According to Markovinokov’s rule, the positive part of halogen acid attached to that carbon atom in C=C bond which carries maximum number of hydrogen atoms and the negative part of halogen acid will attach to that carbon atom in C=C bond which has minimum number of hydrogen atoms.

The steps followed by electrophilic addition reaction are stated below:

• First protonation of the alkene take place to generate the carbocation.

• The halide ion will attack on the carbocation to give the final product.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 10 - Prob. 10.1P Ch. 10 - Problem 10.2 How many degrees of unsaturation are...Ch. 10 - Give an example of a compound with molecular...Ch. 10 - Give the IUPAC name for each alkene.Ch. 10 - Give the IUPAC name for each polyfunctional...Ch. 10 - Prob. 10.6P Ch. 10 - Prob. 10.7P Ch. 10 - Prob. 10.8P Ch. 10 - Prob. 10.9P Ch. 10 - Problem 10.10 Rank the following isomers in order...

Solution Summary: The author explains that the addition of HBr to alkenes A and C is regioselective and forms addition products B and D.

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Chapter 10 Solutions