INTRO TO CHEMISTRY CUSTOM
19th Edition
ISBN: 9780135315590
Author: Pearson
Publisher: Pearson Custom Publishing
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Textbook Question
Chapter 10, Problem 119DIA
The VSEPR model is useful in predicting bond for many compounds. Consider the tabulated data for bond angles in related species and answer the questions.
Bond Angles in NO2 and Associated lons | |
Species | Bond Angles |
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(a) Draw Lewis structure for all of the species in the table.
(b) Use the Lewis structure from part a) to explain the observed bond angles in
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Chapter 10 Solutions
INTRO TO CHEMISTRY CUSTOM
Ch. 10 - Q1. Which pair of elements has the most similar...Ch. 10 - What is the Lewis structure for the compound that...Ch. 10 - Prob. 3SAQCh. 10 - Q4. What is the correct Lewis structure for?
a....Ch. 10 - Q5. How many electron dots are in the Lewis...Ch. 10 - Prob. 6SAQCh. 10 - What is the molecular geometry of PBr3 ? a. Bent...Ch. 10 - What is the molecular geometry of N2O ? (Nitrogen...Ch. 10 - Prob. 9SAQCh. 10 - Q10. Which molecular is polar?
a.
b.
c.
d.
Ch. 10 - Prob. 1ECh. 10 - Write the election configuration for Ne and Ar....Ch. 10 - In the Lewis model, what is an octet? What is a...Ch. 10 - 4. What is the different between ionic bonding and...Ch. 10 - Prob. 5ECh. 10 - Prob. 6ECh. 10 - 7. How are double and triple bonds physically...Ch. 10 - What is the procedure for writing a covalent Lewis...Ch. 10 - 9. How do you determine the number of electrons...Ch. 10 - How do you determine the number of electrons that...Ch. 10 - Prob. 11ECh. 10 - What are resonance structures? Why are they...Ch. 10 - Prob. 13ECh. 10 - 14. If all of the election group around a central...Ch. 10 - Prob. 15ECh. 10 - What is the difference between electron geometry...Ch. 10 - Prob. 17ECh. 10 - 18. What is the most electronegative element on...Ch. 10 - Prob. 19ECh. 10 - What is a dipole moment?Ch. 10 - Prob. 21ECh. 10 - Prob. 22ECh. 10 - Write an electron configuration for each element...Ch. 10 - 24. Write an electron configuration for each...Ch. 10 - Write the Lewis structure for each element. a. I...Ch. 10 - Write the Lewis structure for each element. a. Kr...Ch. 10 - Write a generic Lewis structure for the halogens....Ch. 10 - Write a generic Lewis structure for the alkali...Ch. 10 - Prob. 29ECh. 10 - Prob. 30ECh. 10 - Prob. 31ECh. 10 - 32. Write the Lewis structure for each ion.
a.
b....Ch. 10 - Indicate the noble gas that has the same Lewis...Ch. 10 - 34. Indicate the noble gas that has the same Lewis...Ch. 10 - Lewis structure for lonic compounds
35. Is each...Ch. 10 - Is each compound best represented by an ionic or a...Ch. 10 - Write the Lewis structure for each ionic compound....Ch. 10 - Write the Lewis structure for each ionic compound....Ch. 10 - Use the Lewis model to determine the formula for...Ch. 10 - 40. Use the Lewis model to determine the formula...Ch. 10 - Prob. 41ECh. 10 - Prob. 42ECh. 10 - Prob. 43ECh. 10 - Determine what is wrong with each ionic Lewis...Ch. 10 - Use the Lewis model to explain why each element...Ch. 10 - Use the Lewis model to explain why the compound...Ch. 10 - Write the Lewis structure for each molecule. a....Ch. 10 - 48. Write the Lewis structure for each...Ch. 10 - 49. Write the Lewis structure for each...Ch. 10 - 50. Write the Lewis structure for each...Ch. 10 - Write the Lewis structure for each molecule. a....Ch. 10 - Write the Lewis structure for each molecule. a....Ch. 10 - 53. Determine what is wrong with each Lewis...Ch. 10 - 54. Determine what is wrong with each Lewis...Ch. 10 - 55. Write the Lewis structure for each molecule or...Ch. 10 - Write the Lewis structure for each molecule or...Ch. 10 - 57. Write the Lewis structure for each ion....Ch. 10 - Prob. 58ECh. 10 - Write the Lewis structure for each molecule. These...Ch. 10 - Write the Lewis structure for each molecule. These...Ch. 10 - 61. Determine the number of electron groups around...Ch. 10 - 62. Determine the number of electron groups around...Ch. 10 - 63. Determine the number of bonding groups and the...Ch. 10 - Determine the number of bonding groups and the...Ch. 10 - 65. Determine the molecular geometry of each...Ch. 10 - Determine the molecular geometry of each molecule....Ch. 10 - ...Ch. 10 - 66. Determine the molecular geometry of each...Ch. 10 - Determine the electron and molecular geometries of...Ch. 10 - Determine the electron and molecular geometries of...Ch. 10 - 71. Determine the bond angles for each molecule in...Ch. 10 - 72. Determine the bond angles for each molecule in...Ch. 10 - Determine the electron and molecular geometry of...Ch. 10 - Determine the electron and molecular geometries of...Ch. 10 - Determine the molecular geometry of each...Ch. 10 - 76. Determine the molecular geometry of each...Ch. 10 - Refer to Figure10.2 to determine the...Ch. 10 - Refer to figure 10.2 to determine the...Ch. 10 - List these elements in order of decreasing...Ch. 10 - 80. List these elements in order of increasing...Ch. 10 - 81. Refer to figure10.2 to find the...Ch. 10 - Refer to figure 10.2 to find the electronegativity...Ch. 10 - Arrange these diatomic molecules in order of...Ch. 10 - Arrange these diatomic molecules in order of...Ch. 10 - Classify each diatomic molecule as polar or...Ch. 10 - 86. Classify each diatomic molecule as polar or...Ch. 10 - Prob. 87ECh. 10 - Prob. 88ECh. 10 - Classify each molecule as polar nonpolar. a. CS2...Ch. 10 - 90. Classify each molecule as polar or...Ch. 10 - 91. Classify each molecule as polar nonpolar.
a....Ch. 10 - Classify each molecule as polar or nonpolar. a....Ch. 10 - Prob. 93ECh. 10 - Prob. 94ECh. 10 - 95. Determine whether each compound is ionic or...Ch. 10 - Determine whether each compound is ionic or...Ch. 10 - Write the Lewis structure for OCCI2 (carbon is...Ch. 10 - Prob. 98ECh. 10 - Prob. 99ECh. 10 - Prob. 100ECh. 10 - Prob. 101ECh. 10 - 102. Consider the precipitation reaction.
Write...Ch. 10 - Prob. 103ECh. 10 - Prob. 104ECh. 10 - 105. Each compound listed contains both ionic and...Ch. 10 - Prob. 106ECh. 10 - 107. Each molecule listed contains an expanded...Ch. 10 - Prob. 108ECh. 10 - Formic acid is responsible for the sting you feel...Ch. 10 - Diazomethane has the following composition by...Ch. 10 - Free radicals are molecules that contain an odd...Ch. 10 - Prob. 112ECh. 10 - Prob. 113ECh. 10 - Prob. 114ECh. 10 - Prob. 115ECh. 10 - Prob. 116QGWCh. 10 - Draft a list stepbystep instructions for writing a...Ch. 10 - for each of the following molecules:...Ch. 10 - The VSEPR model is useful in predicting bond for...
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- Predict die molecular structure and bond angles for each molecule or ion in Exercises 88 and 94. a. POCl3, SO42, XeO4, PO43, ClO4 b. NF3, SO32, PO33, ClO3 c.ClO2, SCl2, PCl2 d. Considering your answers to parts a, b, and c. what conclusions can you draw concerning the structures of species containing the same number of atoms and the same number of valence electrons? (O3), sulfur dioxide, and sulfur trioxide.arrow_forwardConsider the following molecules: SiH4, PH3, H2S. In each case, a central atom is surrounded by four electron pairs. In which of these molecules would you expect the bond angle to be less than 109.5? Explain your reasoning.arrow_forwardIn each of the following molecules, a central atom is surrounded by a total of three atoms or unshared electron pairs: SnCl2, BCl3, SO2. In which of these molecules would you expect the bond angle to be less than 120? Explain your reasoning.arrow_forward
- Formamide, HC(O)NH2, is prepared at high pressures from carbon monoxide and ammonia, and serves as an industrial solvent (the parentheses around the O indicate that it is bonded only to the carbon atom and that the carbon atom is also bonded to the H and the N atoms). Two resonance forms (one with formal charges) can be written for formamide. Write both resonance structures, and predict the bond angles about the carbon and nitrogen atoms for each resonance form. Are they the same? Describe how the experimental determination of the HNH bond angle could be used to indicate which resonance form is more important.arrow_forwardWhich has the greater bond lengths: NO2 or NO3? Explain.arrow_forwardTwo compounds have the molecular formula N3H3. One of the compounds, triazene, contains an NN bond; the other compound, triaziridene, does not. (a) Write the correct Lewis structures for each compound. (b) Approximate the bond angle between the three nitrogen atoms in each compound.arrow_forward
- In addition to CO, CO2, and C3O2, there is another molecular oxide of carbon, pentacarbon dioxide, C5O2, a yellow solid. (a) What is the approximate C-to-C-to-O bond angle in pentacarbon dioxide? (b) What is the approximate C-to-C-to-C bond angle in this compound?arrow_forwardPredict the molecular structure and bond angles for each molecule or ion in Exercises 87 and 93. a. CCl4 b. NCl3 c. SeCl2 d. ICl a. NO2, NO3, N2O4 (N2O4 exists as O2NNO2.) b. OCN, SCN, N3 (Carbon is the central atom in OCN and SCN.)arrow_forwardBest Lewis Formula and Molecular Geometry A student writes the Lewis electron-dot formula for the carbonate anion, CO32, as a Does this Lewis formula obey the octet rule? Explain. What are the formal charges on the atoms? Try describing the bonding for this formula in valence bond terms. Do you have any difficulty doing this? b Does this Lewis formula give a reasonable description of the electron structure, or is there a better one? If there is a better Lewis formula, write it down and explain why it is better. c The same student writes the following resonance description for CO2: Is there something wrong with this description? (What would you predict as the geometries of these formulas?) d Is one or the other formula a better description? Could a value for the dipole moment help you decide? e Can you write a Lewis formula that gives an even better description of CO2? Explain your answer.arrow_forward
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