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CHEM:STRUCTURE&PROPERTIES PKG
15th Edition
ISBN: 9781323184783
Author: Tro
Publisher: PEARSON C
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Chapter 10, Problem 29E
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Chapter 10 Solutions
CHEM:STRUCTURE&PROPERTIES PKG
Ch. 10 - A chemical system produces 155 kJ of heat and does...Ch. 10 - Which sample is most likely to undergo the...Ch. 10 - Prob. 3SAQCh. 10 - A 12.5-g sample of granite initially at 82.0 C is...Ch. 10 - A cylinder with a moving piston expands from an...Ch. 10 - When a 3.80-g sample of liquid octane (C8H18)...Ch. 10 - Hydrogen gas reacts with oxygen to form water....Ch. 10 - Manganese reacts with hydrochloric acid to produce...Ch. 10 - Consider the reactions: A2BH1A3CH2 What is H for...Ch. 10 - Use standard enthalpies of formation to determine...
Ch. 10 - Prob. 11SAQCh. 10 - Prob. 12SAQCh. 10 - Prob. 13SAQCh. 10 - Which set of compounds is arranged in order of...Ch. 10 - Prob. 15SAQCh. 10 - What is thermochemistry? Why is it important?Ch. 10 - What is energy? What is work? List some examples...Ch. 10 - Prob. 3ECh. 10 - What is the law of conservation of energy? How...Ch. 10 - A friend claims to have constructed a machine that...Ch. 10 - What is a state function? List some examples of...Ch. 10 - What is internal energy? Is internal energy a...Ch. 10 - If energy flows out of a chemical system and into...Ch. 10 - If the internal energy of the products of a...Ch. 10 - What is heat? Explain the difference between heat...Ch. 10 - How is the change in internal energy of a system...Ch. 10 - Explain how the sum of heat and work can be a...Ch. 10 - What is heat capacity? Explain the difference...Ch. 10 - Explain how the high specific heat capacity of...Ch. 10 - If two objects, A and B, of different temperature...Ch. 10 - What is pressure-volume work? How is it...Ch. 10 - What is calorimetry? Explain the difference...Ch. 10 - What is the change in enthalpy ( H) for a...Ch. 10 - Explain the difference between an exothermic and...Ch. 10 - From a molecular viewpoint where does the energy...Ch. 10 - From a molecular viewpoint, where does the energy...Ch. 10 - Is the change in enthalpy for a reaction an...Ch. 10 - Explain how the value of H for a reaction changes...Ch. 10 - What is Hess's law? Why is it useful?Ch. 10 - What is a standard state? What is the standard...Ch. 10 - How can bond energies be used to estimate H for a...Ch. 10 - Explain the difference between exothermic and...Ch. 10 - What is the standard enthalpy of formation for a...Ch. 10 - How do you calculate Hrxn from tabulated standard...Ch. 10 - What is lattice energy? How does lattice energy...Ch. 10 - Which statement is true of the internal energy of...Ch. 10 - During an energy exchange, a chemical system...Ch. 10 - Identify each energy exchange as primarily heat or...Ch. 10 - Identify each energy exchange as primarily heat or...Ch. 10 - A system releases 622 kJ of heat and does 105 kJ...Ch. 10 - A system absorbs 196 kJ of heat, and the...Ch. 10 - The gas in a piston (defined as the system) warms...Ch. 10 - The air in an inflated balloon (defined as the...Ch. 10 - A person packs two identical coolers for a picnic,...Ch. 10 - A kilogram of aluminum metal and a kilogram of...Ch. 10 - How much heat is required to warm 1.50 L of water...Ch. 10 - How much heat is required to warm 1.50 kg of sand...Ch. 10 - Suppose that 25 g of each substance is initially...Ch. 10 - An unknown mass of each substance, initially at...Ch. 10 - How much work (in J) is required to expand the...Ch. 10 - The average human lung expands by about 0.50 L...Ch. 10 - The air within a piston equipped with a cylinder...Ch. 10 - A gas is compressed from an initial volume of 5.55...Ch. 10 - When 1 mol of a fuel burns at constant pressure,...Ch. 10 - The change in internal energy for the combustion...Ch. 10 - Is each process exothermic or endothermic?...Ch. 10 - Is each process exothermic or endothermic?...Ch. 10 - Consider the thermochemical equation for the...Ch. 10 - What mass of natural gas (CH4) must bum to emit...Ch. 10 - Nitromethane (CH3NO2) burns in air to produce...Ch. 10 - Titanium reacts with iodine to form titanium (III)...Ch. 10 - The propane fuel (C3H8) used in gas barbeques bums...Ch. 10 - Charcoal is primarily carbon. Determine the mass...Ch. 10 - We submerge a silver block, initially at 58.5 °C...Ch. 10 - We submerge a 32.5-g iron rod, initially at 22.7...Ch. 10 - We submerge a 31.1-g wafer of pure gold initially...Ch. 10 - We submerge a 2.85-g lead weight, initially at...Ch. 10 - Two substances, A and B, initially at different...Ch. 10 - A 2.74-g sample of a substance suspected of being...Ch. 10 - Exactly 1.5 g of a fuel burns under conditions of...Ch. 10 - In order to obtain the largest possible amount of...Ch. 10 - When 0.514 g of biphenyl (C12H10) undergoes...Ch. 10 - Mothballs are composed primarily of the...Ch. 10 - Zinc metal reacts with hydrochloric acid according...Ch. 10 - Instant cold packs used to ice athletic injuries...Ch. 10 - For each generic reaction, determine the value of...Ch. 10 - Consider the generic reaction: A+2BC+3DH=155kJ...Ch. 10 - Calculate Hrxn for the reaction:...Ch. 10 - Calculate Hrxn for the reaction:...Ch. 10 - Calculate Hrxn for the reaction:...Ch. 10 - Calculate Hrxn for the reaction:...Ch. 10 - Hydrogenation reactions are used to add hydrogen...Ch. 10 - Ethanol is a possible fuel. Use average bond...Ch. 10 - Hydrogen, a potential future fuel, can be produced...Ch. 10 - Hydroxyl radicals react with and eliminate many...Ch. 10 - Write an equation for the formation of each...Ch. 10 - Prob. 82ECh. 10 - S3. Hydrazine (N2H4) is a fuel used by some...Ch. 10 - Prob. 84ECh. 10 - Prob. 85ECh. 10 - Prob. 86ECh. 10 - Prob. 87ECh. 10 - Prob. 88ECh. 10 - Top fuel dragsters and funny cars burn...Ch. 10 - Prob. 90ECh. 10 - Prob. 91ECh. 10 - Rubidium iodide has a lattice energy of-617...Ch. 10 - Prob. 93ECh. 10 - Prob. 94ECh. 10 - Use the Born-Haber cycle and data from Appendix...Ch. 10 - Prob. 96ECh. 10 - The kinetic energy of a rolling billiard ball is...Ch. 10 - A100-W light bulb is placed in a cylinder equipped...Ch. 10 - Evaporating sweat cools the body because...Ch. 10 - LP gas burns according to the exothermic reaction:...Ch. 10 - Use standard enthalpies of formation to calculate...Ch. 10 - Dry ice is solid carbon dioxide. Instead of...Ch. 10 - A 25.5-g aluminum block is warmed to 65.4 °C and...Ch. 10 - We mix 50.0 mL of ethanol (density = 0.789 g/mL)...Ch. 10 - Prob. 105ECh. 10 - Prob. 106ECh. 10 - One tablespoon of peanut butter has a mass of 16...Ch. 10 - Prob. 108ECh. 10 - Prob. 109ECh. 10 - When we burn 10.00 g of phosphorus in O2 (g) to...Ch. 10 - The H for the oxidation of S in the gas phase to...Ch. 10 - The Hfo of TiI3(s) is -328 kJ/mol; and the Ho for...Ch. 10 - A copper cube measuring 1.55 cm on edge and an...Ch. 10 - A pure gold ring and pure silver ring have a total...Ch. 10 - The reaction of Fe2O3(s) with Al(s) to form...Ch. 10 - Prob. 116ECh. 10 - Prob. 117ECh. 10 - Prob. 118ECh. 10 - Prob. 119ECh. 10 - Calculate the heat of atomization (see previous...Ch. 10 - Prob. 121ECh. 10 - Prob. 122ECh. 10 - Prob. 123ECh. 10 - Prob. 124ECh. 10 - Prob. 125ECh. 10 - Find H, E, q, and w for the freezing of water at...Ch. 10 - The heat of vaporization of water at 373 K is 40.7...Ch. 10 - Prob. 128ECh. 10 - Prob. 129ECh. 10 - Prob. 130ECh. 10 - Prob. 131ECh. 10 - Prob. 132ECh. 10 - Prob. 133ECh. 10 - Which expression describes the heat emitted in a...Ch. 10 - Prob. 135ECh. 10 - Prob. 136ECh. 10 - Prob. 137ECh. 10 - Prob. 138ECh. 10 - Prob. 139ECh. 10 - Which statement is true of a reaction in which V...Ch. 10 - Which statement is true of an endothermic...Ch. 10 - When a firecracker explodes, energy is obviously...
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- Use Hesss law to calculate the enthalpy change for the formation of CS2() from C(s) and S(s) [C(s) + 2 S(s) CS2()] from the following enthalpy values. C(s)+O2(g)CO2(g)rH1=393.5kJ/mol-rxnS(s)+O2(g)SO2(g)rH2=296.8kJ/mol-rxnCS2(l)+3O2(g)CO2(g)+2SO2(g)rH3=1103.9kJ/mol-rxnarrow_forwardWhen 2.50 g of methane burns in oxygen, 125 kJ of heat is produced. What is the enthalpy of combustion per mole of methane under these conditions?arrow_forwardUsing the data in Appendix G, calculate the standard enthalpy change for each of the following reactions: (a) Si(s)+2F2(g)SiF4(g) (b) 2C(s)+2H2(g)+O2(g)CH3CO2H(l) (c) CH4(g)+N2(g)HCN(g)+NH3(g) ; (d) CS2(g)+3Cl2(g)CCl4(g)+S2Cl2(g)arrow_forward
- What mass of acetylene, C2H2(g), must be burned to produce 3420 kJ of heat, given that its enthalpy of combustion is 1301 kJ/mol? Compare this with the answer to Exercise 5.91 and determine which substance produces more heat per gram.arrow_forward9.73 Without looking up any numerical data or doing calculations, predict whether the enthalpy change for each of the following reactions should he positive, negative, or zero. (a) H2O(l)H2O(s) (b) N2(g)2N(g) (c) CH4(g)+2O2(g)CO2(g)+2H2O(l) (d) CO2(s)CO2(g)arrow_forwardIs the following reaction the appropriate one to use in determining the enthalpy of formation of methane, CH4(g)? Why or why not? C(g)+4H(g)CH4(g)arrow_forward
- Which of the enthalpies of combustion in Table 5.2 the table are also standard enthalpies of formation?arrow_forward9.41 Under what conditions does the enthalpy change equal the heat of a process?arrow_forwardThe enthalpy change for the following reaction is 393.5 kJ. C(s,graphite)+O2(g)CO2(g) (a) Is energy released from or absorbed by the system in this reaction? (b) What quantities of reactants and products are assumed? (c) Predict the enthalpy change observed when 3.00 g carbon burns in an excess of oxygen.arrow_forward
- The thermochemical equation for the burning of methane, the main component of natural gas, is CH4(g)+2O2(g)CO2(g)+2H2O(l)H=890kJ (a) Is this reaction endothermic or exothermic? (b) What quantities of reactants and products are assumed if H = 890 kJ? (c) What is the enthalpy change when 1.00 g methane burns in an excess of oxygen?arrow_forwardOne step in the manufacturing of sulfuric acid is the conversion of SO2(g) to SO3(g). The thermochemical equation for this process is SO2(g)+12O2(g)SO3(g)H=98.9kJ The second step combines the SO3 with H2O to make H2SO4. (a) Calculate the enthalpy change that accompanies the reaction to make 1.00 kg SO3(g). (b) Is heat absorbed or released in this process?arrow_forwardWhat mass of carbon monoxide must be burned to produce 175 kJ of heat under standard state conditions?arrow_forward
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