Organic Chemistry; Modified MasteringChemistry with Pearson eText -- ValuePack Access Card; Study Guide and Student Solutions Manual for Organic Chemistry, Books a la Carte Edition (7th Edition)
7th Edition
ISBN: 9780134240152
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Textbook Question
Chapter 10, Problem 44P
Indicate which species in each pair gives a higher substitution-product-to-elimination-product ratio when it reacts with isopropyl bromide:
- a. ethoxide ion or tert-butoxide ion
- b. –OCN or –SCN
- c. Cl– or Br–
- d. CH3S‑ or CH3O–
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Indicate which species in each pair gives a higher substitution-product-to-elimination-product ratio when it reacts with isopropyl bromide:
a. ethoxide ion or tert-butoxide ion
b. -OCN or -SCN
c. Cl- or Br-
d. CH3S- or CH3O-
17. What is the missing reagent in the reaction below?
aq. HCI
A. CH2(COOE1)2, NaOEt
C. CH2(COOE1)2, HOAC
B. CH3CO2Et, NaOEt
D. CH3CO,Et, HOAC
18. In several reactions of carhonyl compounds that we have studied, the reaction proceeds by c
What is the major organic product obtained from the following reaction?
A.
B.
EN
NH₂
H
NH
H
1. LIAIH4
2. H3O+
C.
D.
OH
NH₂
EN
Chapter 10 Solutions
Organic Chemistry; Modified MasteringChemistry with Pearson eText -- ValuePack Access Card; Study Guide and Student Solutions Manual for Organic Chemistry, Books a la Carte Edition (7th Edition)
Ch. 10.2 - Prob. 1PCh. 10.2 - Prob. 2PCh. 10.2 - Prob. 3PCh. 10.2 - Prob. 4PCh. 10.3 - Four alkenes are formed from the E1 reaction of...Ch. 10.3 - If 2-fluoropentane could undergo an E1 reaction,...Ch. 10.3 - Prob. 7PCh. 10.3 - Propose a mechanism for the following reaction:Ch. 10.4 - Prob. 9PCh. 10.4 - What products will be obtained from the El...
Ch. 10.4 - Prob. 11PCh. 10.5 - Prob. 12PCh. 10.6 - Prob. 14PCh. 10.7 - Why do cis-1-bromo-2-ethylcyclohexane and...Ch. 10.7 - Which isomer reacts more rapidly in an E2...Ch. 10.7 - Prob. 18PCh. 10.8 - Prob. 19PCh. 10.8 - Prob. 20PCh. 10.9 - Prob. 21PCh. 10.9 - Explain why only a substitution product and no...Ch. 10.9 - Prob. 23PCh. 10.9 - Prob. 24PCh. 10.9 - Prob. 25PCh. 10.9 - a. Explain why 1-bromo-2,2-dimethylpropane has...Ch. 10.10 - A small amount of another organic product is...Ch. 10.10 - What is the best way to prepare the following...Ch. 10.10 - Prob. 29PCh. 10.10 - Prob. 30PCh. 10.10 - Why is a cumulated diene not formed in the...Ch. 10.10 - What product is obtained when the following...Ch. 10.11 - Prob. 33PCh. 10.11 - Prob. 34PCh. 10 - Draw the major product obtained when each of the...Ch. 10 - Prob. 36PCh. 10 - a. Indicate how each of the following factors...Ch. 10 - Prob. 38PCh. 10 - A chemist wanted to synthesize the...Ch. 10 - Prob. 40PCh. 10 - Prob. 41PCh. 10 - Prob. 42PCh. 10 - Starting with an alkyl halide, how could the...Ch. 10 - Indicate which species in each pair gives a higher...Ch. 10 - Prob. 45PCh. 10 - For each of the following alkyl halides, indicate...Ch. 10 - Prob. 47PCh. 10 - When 2-bromo-2,3-dimethylbutane reacts with a...Ch. 10 - Prob. 49PCh. 10 - When the following compound undergoes solvolysis...Ch. 10 - cis-1-Bromo-4-tert-butylcyclohexane and...Ch. 10 - Draw the substitution and elimination products.Ch. 10 - Prob. 53PCh. 10 - Prob. 54PCh. 10 - Which of the following hexachlorocyclohexanes is...Ch. 10 - Explain why the rate of the reaction of...Ch. 10 - Prob. 57PCh. 10 - Two elimination products are obtained from the...Ch. 10 - Draw the structures or the product of the obtained...Ch. 10 - How could you prepare the following compounds from...Ch. 10 - cis-4-Bromocyclohexanol and...Ch. 10 - Prob. 62PCh. 10 - Prob. 63P
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- 12. Which reagents/conditions would lead to the transformation depicted below in high yield? a. NaOMe, MeOH b. MeOH, H₂O* c. NaOEt, EtOH 13. In the structure of 2-fluoropropanoic acid shown, the oxidation number on C1 is the oxidation number on C2 is a. +1, +2, -3 b. -3, +1, +3 d. NaOH, H₂O e. two of these , and the oxidation number on C3 is, c. 0, 0, 0 d. +3,0,-3 e. +2,0, -2 ??? OH 14. What will be the outcome of the following reaction sequence? B. 1. NaOEt, EtOH 2. PCC 3. isopropylMgBr 4. H₂0¹ ??? a. 2-ethyl-3-isopropyl-2,3-dimethyloxirane b. 2,3,4-trimethyl-3,4-epoxyhexane c. 1,2,3,4-tetramethyl-2,3-epoxypentane d. Both a and b are suitable. e. All of the above are correct. OH 15. What is a suitable IUPAC name for the structure shown at the right? OH D. F H OH LOH CH3 3 OHarrow_forwardChoose the most correct set of reagents for the following reactions. 1.? OMe 2. ? a. 1. MsCI, pyridine; 2. NaOH, H2O2, H2O b. 1. HCI, pyridine NaOCH3, CH;OH c. 1. Pl3, pyridine; 2. NaOCH3, CH;OH d. 1. TSCI, pyridine; 2. NaOCH3, CH3OH e. 1. CH30", pyridine; 2. H* f. 1. PBr3, pyridine; 2. H*arrow_forwardFrom the table of reagents shown below, show how you synthesize the product from the given reactant. OCH₂CH3 OH a. NBS, (PhCO₂)2 b. Br2, FeBr3 c. Br₂, H+ d. OH e. NaOH(s), A f. HNO3, H₂SO4 g. H₂ CrO4 Reagents available h. CH3 CI, AICI, o. CuCN i. CH3 CH₂ Br p. H₂O+, A j. CH₂O, A q. CH3 CH₂ COCI, AICI, k. CH3COCI, AICI3 r. H₂NNH₂, OH, A 1. Mg, Et₂ O s. H₂, Pd/C m. CO₂ (s) then H3O+ t. H₂PO₂ n. HONO 0°C u. Cl₂, FeCl3 (Enter the letter(s) of the reagent(s) needed in the box, in the order that they must be used. No more than two steps are required to perform the synthesis. Note that a retrosynthetic arrow is used, and therefore the reactant is shown on the right.) Answer:arrow_forward
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