EBK GENERAL CHEMISTRY: THE ESSENTIAL CO
EBK GENERAL CHEMISTRY: THE ESSENTIAL CO
7th Edition
ISBN: 9780100257047
Author: Chang
Publisher: YUZU
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Chapter 11, Problem 11.63QP

a)

Interpretation Introduction

Interpretation:

The structure of the alkane cyclopentane has to be predicted.

Concept introduction:

IUPAC Nomenclature of cycloalkanes:

  • The longest continuous ring of carbon atoms is identified. The prefix is added with ‘cyclo’.
  • The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
  • While numbering the longest chain, the substituent should get least possible number.
  • Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

b)

Interpretation Introduction

Interpretation:

The structure of cis-2-butene has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkenes:

  • The longest continuous chain of carbon atoms is identified.
  • The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
  • While numbering the longest chain, the substituent should get least possible number.
  • Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Geometric isomers of Alkenes:

Cis-isomer: When two particular atoms (identical group of atoms) are adjacent (on same side) to each other, the alkene is known as cis-isomer.

EBK GENERAL CHEMISTRY: THE ESSENTIAL CO, Chapter 11, Problem 11.63QP , additional homework tip  1

Trans-isomer: When two particular atoms (identical group of atoms) are opposite from each other, the alkene is known as trans-isomer.

c)

Interpretation Introduction

Interpretation:

The structure of 2-hexanol has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkanes:

  • The longest continuous chain of carbon atoms is identified.
  • The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
  • While numbering the longest chain, the substituent should get least possible number.
  • Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

d)

Interpretation Introduction

Interpretation:

The structure of 1,4-dibromobenzene has to be predicted.

Concept introduction:

IUPAC Nomenclature of Aromatic compounds:

  • The parent compound of aromatic compound is Benzene.
  • The substituent groups attached to the parent is identified. A substituent group contains group of atoms attached to the carbon atom of the aromatic ring.
  • While numbering the parent, the location of the second group relative to the first substituent uses prefixes like o-ortho (1,2-), m-meta (1,3-), and p-para (1,4) in disubstituted aromatic ring.

EBK GENERAL CHEMISTRY: THE ESSENTIAL CO, Chapter 11, Problem 11.63QP , additional homework tip  2

e)

Interpretation Introduction

Interpretation:

The structure of 2-butyne has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkynes:

  • The longest continuous chain of carbon atoms is identified. The suffix is added replaced with ‘yne’.
  • The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
  • While numbering the longest chain, the substituent should get least possible number.
  • Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

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Chapter 11 Solutions

EBK GENERAL CHEMISTRY: THE ESSENTIAL CO

Ch. 11 - Prob. 11.2QPCh. 11 - Prob. 11.3QPCh. 11 - 11.4 What are structural isomers? Ch. 11 - Prob. 11.5QPCh. 11 - 11.6 Draw skeletal structures of the boat and...Ch. 11 - 11.7 Alkenes exhibit geometric isomerism because...Ch. 11 - 11.8 Why is it that alkanes and alkynes, unlike...Ch. 11 - Prob. 11.9QPCh. 11 - 11.10 Describe reactions that are characteristic...Ch. 11 - Prob. 11.11QPCh. 11 - Prob. 11.12QPCh. 11 - Prob. 11.13QPCh. 11 - Prob. 11.14QPCh. 11 - Prob. 11.15QPCh. 11 - Prob. 11.16QPCh. 11 - Prob. 11.17QPCh. 11 - 11.18 Draw Newman projections of four different...Ch. 11 - 11.19 Draw the structures of cis-2-butene and...Ch. 11 - 11.20 Would you expect cyclobutadiene to be a...Ch. 11 - Prob. 11.21QPCh. 11 - Prob. 11.22QPCh. 11 - 11.23 Sulfuric acid (H2SO4) adds to the double...Ch. 11 - Prob. 11.24QPCh. 11 - Prob. 11.25QPCh. 11 - Prob. 11.26QPCh. 11 - Prob. 11.27QPCh. 11 - Prob. 11.28QPCh. 11 - Prob. 11.29QPCh. 11 - 11.30 Benzene and cyclohexane both contain...Ch. 11 - Prob. 11.31QPCh. 11 - Prob. 11.32QPCh. 11 - Prob. 11.33QPCh. 11 - Prob. 11.34QPCh. 11 - Prob. 11.35QPCh. 11 - Prob. 11.36QPCh. 11 - Prob. 11.37QPCh. 11 - Prob. 11.38QPCh. 11 - Prob. 11.39QPCh. 11 - Prob. 11.40QPCh. 11 - Prob. 11.41QPCh. 11 - Prob. 11.42QPCh. 11 - Prob. 11.43QPCh. 11 - Prob. 11.44QPCh. 11 - Prob. 11.45QPCh. 11 - Prob. 11.46QPCh. 11 - Prob. 11.47QPCh. 11 - Prob. 11.48QPCh. 11 - Prob. 11.49QPCh. 11 - Prob. 11.50QPCh. 11 - Prob. 11.51QPCh. 11 - Prob. 11.52QPCh. 11 - Prob. 11.53QPCh. 11 - Prob. 11.54QPCh. 11 - Prob. 11.55QPCh. 11 - Prob. 11.56QPCh. 11 - Prob. 11.57QPCh. 11 - Prob. 11.58QPCh. 11 - Prob. 11.59QPCh. 11 - Prob. 11.60QPCh. 11 - Prob. 11.61QPCh. 11 - Prob. 11.62QPCh. 11 - Prob. 11.63QPCh. 11 - Prob. 11.64QPCh. 11 - Prob. 11.65QPCh. 11 - Prob. 11.66QPCh. 11 - Prob. 11.67QPCh. 11 - Prob. 11.68QPCh. 11 - Prob. 11.69QPCh. 11 - Prob. 11.70QPCh. 11 - Prob. 11.71QPCh. 11 - Prob. 11.72QPCh. 11 - 11.73 Octane number is assigned to gasoline to...Ch. 11 - Prob. 11.74SPCh. 11 - Prob. 11.75SPCh. 11 - Prob. 11.76SPCh. 11 - Prob. 11.77SPCh. 11 - Prob. 11.78SP
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