Elements Of Physical Chemistry
Elements Of Physical Chemistry
7th Edition
ISBN: 9780198727873
Author: ATKINS, P. W. (peter William), De Paula, Julio
Publisher: Oxford University Press
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Chapter 11, Problem 11E.2E
Interpretation Introduction

Interpretation:

Ratio of the fluorescence quantum yields in the presence and absence of the quencher has to be determined.

Concept Introduction:

Fluorescence rate constant of a molecule depends on its fluorescence quantum yield and fluorescence lifetime observed by the molecule. It can be given as,

  Fluorescence rate constant, kf = ΦF,0τ0where, ΦF,0 = Fluorescence quantum yieldτ0 = Observed fluorescence lifetime

Quenching is the total number of processes that is able to decrease the phosphorescence or fluorescence of a molecule. Reactions, electron transfer and energy transfer are examples of the processes that quench the phosphorescence or fluorescence of a molecule.

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Chapter 11 Solutions

Elements Of Physical Chemistry

Ch. 11 - Prob. 11C.3STCh. 11 - Prob. 11C.4STCh. 11 - Prob. 11C.5STCh. 11 - Prob. 11C.6STCh. 11 - Prob. 11C.7STCh. 11 - Prob. 11D.1STCh. 11 - Prob. 11D.2STCh. 11 - Prob. 11D.3STCh. 11 - Prob. 11E.1STCh. 11 - Prob. 11E.2STCh. 11 - Prob. 11E.3STCh. 11 - Prob. 11E.4STCh. 11 - Prob. 11A.1ECh. 11 - Prob. 11A.2ECh. 11 - Prob. 11A.3ECh. 11 - Prob. 11A.4ECh. 11 - Prob. 11A.5ECh. 11 - Prob. 11A.6ECh. 11 - Prob. 11A.7ECh. 11 - Prob. 11A.8ECh. 11 - Prob. 11B.1ECh. 11 - Prob. 11B.2ECh. 11 - Prob. 11B.3ECh. 11 - Prob. 11B.4ECh. 11 - Prob. 11B.5ECh. 11 - Prob. 11B.6ECh. 11 - Prob. 11B.7ECh. 11 - Prob. 11B.8ECh. 11 - Prob. 11B.9ECh. 11 - Prob. 11B.10ECh. 11 - Prob. 11B.11ECh. 11 - Prob. 11B.12ECh. 11 - Prob. 11B.13ECh. 11 - Prob. 11B.14ECh. 11 - Prob. 11B.15ECh. 11 - Prob. 11B.16ECh. 11 - Prob. 11C.1ECh. 11 - Prob. 11C.2ECh. 11 - Prob. 11C.3ECh. 11 - Prob. 11C.4ECh. 11 - Prob. 11C.5ECh. 11 - Prob. 11C.6ECh. 11 - Prob. 11C.7ECh. 11 - Prob. 11C.8ECh. 11 - Prob. 11C.9ECh. 11 - Prob. 11D.1ECh. 11 - Prob. 11D.2ECh. 11 - Prob. 11D.3ECh. 11 - Prob. 11D.4ECh. 11 - Prob. 11D.5ECh. 11 - Prob. 11D.6ECh. 11 - Prob. 11E.1ECh. 11 - Prob. 11E.2ECh. 11 - Prob. 11E.3ECh. 11 - Prob. 11.1DQCh. 11 - Prob. 11.2DQCh. 11 - Prob. 11.3DQCh. 11 - Prob. 11.4DQCh. 11 - Prob. 11.5DQCh. 11 - Prob. 11.6DQCh. 11 - Prob. 11.7DQCh. 11 - Prob. 11.8DQCh. 11 - Prob. 11.9DQCh. 11 - Prob. 11.10DQCh. 11 - Prob. 11.11DQCh. 11 - Prob. 11.12DQCh. 11 - Prob. 11.13DQCh. 11 - Prob. 11.1PCh. 11 - Prob. 11.2PCh. 11 - Prob. 11.4PCh. 11 - Prob. 11.5PCh. 11 - Prob. 11.6PCh. 11 - Prob. 11.7PCh. 11 - Prob. 11.8PCh. 11 - Prob. 11.9PCh. 11 - Prob. 11.11PCh. 11 - Prob. 11.12PCh. 11 - Prob. 11.13PCh. 11 - Prob. 11.14PCh. 11 - Prob. 11.15PCh. 11 - Prob. 11.1PRCh. 11 - Prob. 11.2PRCh. 11 - Prob. 11.3PRCh. 11 - Prob. 11.5PR
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