The structure and formation of ß-anomer from a-anomer should be determined. Concept introduction: Anomers are the glycosides or cyclic monosaccharides that are epimers. These are different from each other in the configuration of C-1 (aldoses) or at C-2 if (ketoses).

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Question

Chapter 11, Problem 17P

Interpretation Introduction

Interpretation:

The structure and formation of ß-anomer from a-anomer should be determined.

Concept introduction:

Anomers are the glycosides or cyclic monosaccharides that are epimers. These are different from each other in the configuration of C-1 (aldoses) or at C-2 if (ketoses).

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Draw the structure. Saccharide X occurs in the roots of several species of plants. Deduce the structure of saccharide x from the following data: 1. Acidic hydrolysis of 1 mol of stachyose yields 2 mol of D-galactose, 1 mol of D-glucose, and 1 mol of D-fructose. 2. Stachyose is a nonreducing sugar. 3. Treating stachyose with an a-galactosidase produces a mixture containing D-galactose, sucrose, and a nonreducing trisaccharide called raffinose. 4. Acidic hydrolysis of raffinose gives D-glucose, D-fructose, and D-galactose. Treating raffinose with an a-galactosidase yields D-galactose and sucrose. Treating raffinose with invertase (an enzyme that hydrolyzes sucrose) yields fructose and melibiose 5. Methylation of saccharide x followed by hydrolysis yields 2,3,4,6-tetra-O-methyl-D-galactose, 2,3,4-tri-0-methyl-D-galactose, 2,3,4-tri-O-methyl-D-glucose, and 1,3,4,6-tetra-O-methyl-D-fructose.

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Answer 2

Question

Chapter 11, Problem 17P

Interpretation Introduction

Interpretation:

The structure and formation of ß-anomer from a-anomer should be determined.

Concept introduction:

Anomers are the glycosides or cyclic monosaccharides that are epimers. These are different from each other in the configuration of C-1 (aldoses) or at C-2 if (ketoses).

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Answer 3

Question

Chapter 11, Problem 17P

Interpretation Introduction

Interpretation:

The structure and formation of ß-anomer from a-anomer should be determined.

Concept introduction:

Anomers are the glycosides or cyclic monosaccharides that are epimers. These are different from each other in the configuration of C-1 (aldoses) or at C-2 if (ketoses).

Expert Solution & Answer

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Answer 4

Question

Chapter 11, Problem 17P

Interpretation Introduction

Interpretation:

The structure and formation of ß-anomer from a-anomer should be determined.

Concept introduction:

Anomers are the glycosides or cyclic monosaccharides that are epimers. These are different from each other in the configuration of C-1 (aldoses) or at C-2 if (ketoses).

Expert Solution & Answer

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Answer 5

Chapter 11, Problem 17P

Interpretation Introduction

Interpretation:

The structure and formation of ß-anomer from a-anomer should be determined.

Concept introduction:

Anomers are the glycosides or cyclic monosaccharides that are epimers. These are different from each other in the configuration of C-1 (aldoses) or at C-2 if (ketoses).

Answer 6

Chapter 11, Problem 17P

Interpretation Introduction

Interpretation:

The structure and formation of ß-anomer from a-anomer should be determined.

Concept introduction:

Anomers are the glycosides or cyclic monosaccharides that are epimers. These are different from each other in the configuration of C-1 (aldoses) or at C-2 if (ketoses).

Answer 7

Chapter 11, Problem 17P

Interpretation Introduction

Interpretation:

The structure and formation of ß-anomer from a-anomer should be determined.

Concept introduction:

Anomers are the glycosides or cyclic monosaccharides that are epimers. These are different from each other in the configuration of C-1 (aldoses) or at C-2 if (ketoses).

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 11 - Prob. 1P Ch. 11 - Prob. 2P Ch. 11 - Prob. 3P Ch. 11 - Prob. 4P Ch. 11 - Prob. 5P Ch. 11 - Prob. 6P Ch. 11 - Prob. 7P Ch. 11 - Prob. 8P Ch. 11 - Prob. 9P Ch. 11 - Prob. 10P

The structure and formation of ß-anomer from a-anomer should be determined. Concept introduction: Anomers are the glycosides or cyclic monosaccharides that are epimers. These are different from each other in the configuration of C-1 (aldoses) or at C-2 if (ketoses).

Solution Summary: The author explains the structure and formation of ß-anomer from a-Anomers. Anomers are glycosides or cyclic monosaccharides that are epimers.

Interpretation:

The structure and formation of ß-anomer from a-anomer should be determined.

Concept introduction:

Anomers are the glycosides or cyclic monosaccharides that are epimers. These are different from each other in the configuration of C-1 (aldoses) or at C-2 if (ketoses).

Want to see the full answer?

Chapter 11 Solutions

The structure and formation of ß-anomer from a-anomer should be determined. Concept introduction: Anomers are the glycosides or cyclic monosaccharides that are epimers. These are different from each other in the configuration of C-1 (aldoses) or at C-2 if (ketoses).

Solution Summary: The author explains the structure and formation of ß-anomer from a-Anomers. Anomers are glycosides or cyclic monosaccharides that are epimers.

Interpretation: The structure and formation of ß-anomer from a-anomer should be determined. Concept introduction: Anomers are the glycosides or cyclic monosaccharides that are epimers. These are different from each other in the configuration of C-1 (aldoses) or at C-2 if (ketoses).

Want to see the full answer?

Chapter 11 Solutions

Interpretation:

The structure and formation of ß-anomer from a-anomer should be determined.

Concept introduction:

Anomers are the glycosides or cyclic monosaccharides that are epimers. These are different from each other in the configuration of C-1 (aldoses) or at C-2 if (ketoses).