How water molecules reorganize into a cage-like structure around the hydrophobic compounds. Introduction: Water molecules in the ice are arranged in such a way that forms a cage-like structure due to the formation of intermolecular hydrogen bond in between the oxygen and hydrogen atom of two different water molecules.

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Answer 1

Question

Chapter 11, Problem 1Q

Summary Introduction

To explain: How water molecules reorganize into a cage-like structure around the hydrophobic compounds.

Introduction: Water molecules in the ice are arranged in such a way that forms a cage-like structure due to the formation of intermolecular hydrogen bond in between the oxygen and hydrogen atom of two different water molecules.

Expert Solution

Explanation of Solution

Refer to the Fig 11-9, “A hydrophobic molecules tend to avoid water”, in the text book. It shows the reorganization of water molecules into a cage-like structure around the hydrophobic compound. Hydrophobic molecules are water insoluble molecules that cannot form favorable interaction with the water molecules.

The hydrogen bonds between the water molecules are continuously broken and formed by the action of thermal motion. When a water molecule comes near to the hydrophobic molecules, its motion is restricted because hydrogen bonds cannot be formed in the direction of hydrophobic molecules. As a result, they force adjacent water molecules to reorganize into a cage-like structure around them.

Summary Introduction

To compare: The cage-like structure of water with ice.

Introduction: Water molecules in the ice are arranged in such a way that forms a cage-like structure due to the formation of intermolecular hydrogen bond in between the oxygen and hydrogen atom of two different water molecules.

Expert Solution

Explanation of Solution

The hexagonal ice gives an open cage-like structure because each oxygen atom in the ice is surrounded by four hydrogen atoms by covalent bond and hydrogen bond. The cage-like structure is less organized, more transient, and considerably less network than a small crystal of ice.

Summary Introduction

To explain: Why the cage-like structure would be energetically unfavorable.

Introduction: Water molecules in the ice are arranged in such a way that forms a cage-like structure due to the formation of intermolecular hydrogen bond in between the oxygen and hydrogen atom of two different water molecules.

Expert Solution

Explanation of Solution

The cage-like structure is a highly ordered structure. During its formation, free energy is required and the cost of the free energy is decreased when the hydrophobic molecules are aggregated to form a cluster. The entropy of the system decreases; hence, the “cage-like” structure would be energetically unfavorable.

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Answer 2

Question

Chapter 11, Problem 1Q

Summary Introduction

To explain: How water molecules reorganize into a cage-like structure around the hydrophobic compounds.

Introduction: Water molecules in the ice are arranged in such a way that forms a cage-like structure due to the formation of intermolecular hydrogen bond in between the oxygen and hydrogen atom of two different water molecules.

Expert Solution

Explanation of Solution

Refer to the Fig 11-9, “A hydrophobic molecules tend to avoid water”, in the text book. It shows the reorganization of water molecules into a cage-like structure around the hydrophobic compound. Hydrophobic molecules are water insoluble molecules that cannot form favorable interaction with the water molecules.

The hydrogen bonds between the water molecules are continuously broken and formed by the action of thermal motion. When a water molecule comes near to the hydrophobic molecules, its motion is restricted because hydrogen bonds cannot be formed in the direction of hydrophobic molecules. As a result, they force adjacent water molecules to reorganize into a cage-like structure around them.

Summary Introduction

To compare: The cage-like structure of water with ice.

Introduction: Water molecules in the ice are arranged in such a way that forms a cage-like structure due to the formation of intermolecular hydrogen bond in between the oxygen and hydrogen atom of two different water molecules.

Expert Solution

Explanation of Solution

The hexagonal ice gives an open cage-like structure because each oxygen atom in the ice is surrounded by four hydrogen atoms by covalent bond and hydrogen bond. The cage-like structure is less organized, more transient, and considerably less network than a small crystal of ice.

Summary Introduction

To explain: Why the cage-like structure would be energetically unfavorable.

Introduction: Water molecules in the ice are arranged in such a way that forms a cage-like structure due to the formation of intermolecular hydrogen bond in between the oxygen and hydrogen atom of two different water molecules.

Expert Solution

Explanation of Solution

The cage-like structure is a highly ordered structure. During its formation, free energy is required and the cost of the free energy is decreased when the hydrophobic molecules are aggregated to form a cluster. The entropy of the system decreases; hence, the “cage-like” structure would be energetically unfavorable.

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Answer 3

Question

Chapter 11, Problem 1Q

Summary Introduction

To explain: How water molecules reorganize into a cage-like structure around the hydrophobic compounds.

Introduction: Water molecules in the ice are arranged in such a way that forms a cage-like structure due to the formation of intermolecular hydrogen bond in between the oxygen and hydrogen atom of two different water molecules.

Expert Solution

Explanation of Solution

Refer to the Fig 11-9, “A hydrophobic molecules tend to avoid water”, in the text book. It shows the reorganization of water molecules into a cage-like structure around the hydrophobic compound. Hydrophobic molecules are water insoluble molecules that cannot form favorable interaction with the water molecules.

The hydrogen bonds between the water molecules are continuously broken and formed by the action of thermal motion. When a water molecule comes near to the hydrophobic molecules, its motion is restricted because hydrogen bonds cannot be formed in the direction of hydrophobic molecules. As a result, they force adjacent water molecules to reorganize into a cage-like structure around them.

Summary Introduction

To compare: The cage-like structure of water with ice.

Introduction: Water molecules in the ice are arranged in such a way that forms a cage-like structure due to the formation of intermolecular hydrogen bond in between the oxygen and hydrogen atom of two different water molecules.

Expert Solution

Explanation of Solution

The hexagonal ice gives an open cage-like structure because each oxygen atom in the ice is surrounded by four hydrogen atoms by covalent bond and hydrogen bond. The cage-like structure is less organized, more transient, and considerably less network than a small crystal of ice.

Summary Introduction

To explain: Why the cage-like structure would be energetically unfavorable.

Introduction: Water molecules in the ice are arranged in such a way that forms a cage-like structure due to the formation of intermolecular hydrogen bond in between the oxygen and hydrogen atom of two different water molecules.

Expert Solution

Explanation of Solution

The cage-like structure is a highly ordered structure. During its formation, free energy is required and the cost of the free energy is decreased when the hydrophobic molecules are aggregated to form a cluster. The entropy of the system decreases; hence, the “cage-like” structure would be energetically unfavorable.

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Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Answer 4

Question

Chapter 11, Problem 1Q

Summary Introduction

To explain: How water molecules reorganize into a cage-like structure around the hydrophobic compounds.

Introduction: Water molecules in the ice are arranged in such a way that forms a cage-like structure due to the formation of intermolecular hydrogen bond in between the oxygen and hydrogen atom of two different water molecules.

Expert Solution

Explanation of Solution

Refer to the Fig 11-9, “A hydrophobic molecules tend to avoid water”, in the text book. It shows the reorganization of water molecules into a cage-like structure around the hydrophobic compound. Hydrophobic molecules are water insoluble molecules that cannot form favorable interaction with the water molecules.

The hydrogen bonds between the water molecules are continuously broken and formed by the action of thermal motion. When a water molecule comes near to the hydrophobic molecules, its motion is restricted because hydrogen bonds cannot be formed in the direction of hydrophobic molecules. As a result, they force adjacent water molecules to reorganize into a cage-like structure around them.

Summary Introduction

To compare: The cage-like structure of water with ice.

Introduction: Water molecules in the ice are arranged in such a way that forms a cage-like structure due to the formation of intermolecular hydrogen bond in between the oxygen and hydrogen atom of two different water molecules.

Expert Solution

Explanation of Solution

The hexagonal ice gives an open cage-like structure because each oxygen atom in the ice is surrounded by four hydrogen atoms by covalent bond and hydrogen bond. The cage-like structure is less organized, more transient, and considerably less network than a small crystal of ice.

Summary Introduction

To explain: Why the cage-like structure would be energetically unfavorable.

Introduction: Water molecules in the ice are arranged in such a way that forms a cage-like structure due to the formation of intermolecular hydrogen bond in between the oxygen and hydrogen atom of two different water molecules.

Expert Solution

Explanation of Solution

The cage-like structure is a highly ordered structure. During its formation, free energy is required and the cost of the free energy is decreased when the hydrophobic molecules are aggregated to form a cluster. The entropy of the system decreases; hence, the “cage-like” structure would be energetically unfavorable.

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Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Answer 5

Chapter 11, Problem 1Q

Summary Introduction

To explain: How water molecules reorganize into a cage-like structure around the hydrophobic compounds.

Introduction: Water molecules in the ice are arranged in such a way that forms a cage-like structure due to the formation of intermolecular hydrogen bond in between the oxygen and hydrogen atom of two different water molecules.

Expert Solution

Explanation of Solution

Refer to the Fig 11-9, “A hydrophobic molecules tend to avoid water”, in the text book. It shows the reorganization of water molecules into a cage-like structure around the hydrophobic compound. Hydrophobic molecules are water insoluble molecules that cannot form favorable interaction with the water molecules.

The hydrogen bonds between the water molecules are continuously broken and formed by the action of thermal motion. When a water molecule comes near to the hydrophobic molecules, its motion is restricted because hydrogen bonds cannot be formed in the direction of hydrophobic molecules. As a result, they force adjacent water molecules to reorganize into a cage-like structure around them.

Summary Introduction

To compare: The cage-like structure of water with ice.

Introduction: Water molecules in the ice are arranged in such a way that forms a cage-like structure due to the formation of intermolecular hydrogen bond in between the oxygen and hydrogen atom of two different water molecules.

Expert Solution

Explanation of Solution

The hexagonal ice gives an open cage-like structure because each oxygen atom in the ice is surrounded by four hydrogen atoms by covalent bond and hydrogen bond. The cage-like structure is less organized, more transient, and considerably less network than a small crystal of ice.

Summary Introduction

To explain: Why the cage-like structure would be energetically unfavorable.

Introduction: Water molecules in the ice are arranged in such a way that forms a cage-like structure due to the formation of intermolecular hydrogen bond in between the oxygen and hydrogen atom of two different water molecules.

Expert Solution

Explanation of Solution

The cage-like structure is a highly ordered structure. During its formation, free energy is required and the cost of the free energy is decreased when the hydrophobic molecules are aggregated to form a cluster. The entropy of the system decreases; hence, the “cage-like” structure would be energetically unfavorable.

Answer 6

Chapter 11, Problem 1Q

Summary Introduction

To explain: How water molecules reorganize into a cage-like structure around the hydrophobic compounds.

Introduction: Water molecules in the ice are arranged in such a way that forms a cage-like structure due to the formation of intermolecular hydrogen bond in between the oxygen and hydrogen atom of two different water molecules.

Expert Solution

Explanation of Solution

Refer to the Fig 11-9, “A hydrophobic molecules tend to avoid water”, in the text book. It shows the reorganization of water molecules into a cage-like structure around the hydrophobic compound. Hydrophobic molecules are water insoluble molecules that cannot form favorable interaction with the water molecules.

The hydrogen bonds between the water molecules are continuously broken and formed by the action of thermal motion. When a water molecule comes near to the hydrophobic molecules, its motion is restricted because hydrogen bonds cannot be formed in the direction of hydrophobic molecules. As a result, they force adjacent water molecules to reorganize into a cage-like structure around them.

Answer 7

Chapter 11, Problem 1Q

Summary Introduction

To explain: How water molecules reorganize into a cage-like structure around the hydrophobic compounds.

Introduction: Water molecules in the ice are arranged in such a way that forms a cage-like structure due to the formation of intermolecular hydrogen bond in between the oxygen and hydrogen atom of two different water molecules.

Answer 8

Expert Solution

Explanation of Solution

Refer to the Fig 11-9, “A hydrophobic molecules tend to avoid water”, in the text book. It shows the reorganization of water molecules into a cage-like structure around the hydrophobic compound. Hydrophobic molecules are water insoluble molecules that cannot form favorable interaction with the water molecules.

The hydrogen bonds between the water molecules are continuously broken and formed by the action of thermal motion. When a water molecule comes near to the hydrophobic molecules, its motion is restricted because hydrogen bonds cannot be formed in the direction of hydrophobic molecules. As a result, they force adjacent water molecules to reorganize into a cage-like structure around them.

Answer 9

Expert Solution

Answer 10

Expert Solution

Answer 11

Expert Solution

Answer 12

Summary Introduction

To compare: The cage-like structure of water with ice.

Introduction: Water molecules in the ice are arranged in such a way that forms a cage-like structure due to the formation of intermolecular hydrogen bond in between the oxygen and hydrogen atom of two different water molecules.

Expert Solution

Explanation of Solution

The hexagonal ice gives an open cage-like structure because each oxygen atom in the ice is surrounded by four hydrogen atoms by covalent bond and hydrogen bond. The cage-like structure is less organized, more transient, and considerably less network than a small crystal of ice.

Answer 13

Summary Introduction

To compare: The cage-like structure of water with ice.

Introduction: Water molecules in the ice are arranged in such a way that forms a cage-like structure due to the formation of intermolecular hydrogen bond in between the oxygen and hydrogen atom of two different water molecules.

Answer 14

Expert Solution

Explanation of Solution

The hexagonal ice gives an open cage-like structure because each oxygen atom in the ice is surrounded by four hydrogen atoms by covalent bond and hydrogen bond. The cage-like structure is less organized, more transient, and considerably less network than a small crystal of ice.

Answer 15

Expert Solution

Answer 16

Expert Solution

Answer 17

Expert Solution

Answer 18

Summary Introduction

To explain: Why the cage-like structure would be energetically unfavorable.

Introduction: Water molecules in the ice are arranged in such a way that forms a cage-like structure due to the formation of intermolecular hydrogen bond in between the oxygen and hydrogen atom of two different water molecules.

Expert Solution

Explanation of Solution

The cage-like structure is a highly ordered structure. During its formation, free energy is required and the cost of the free energy is decreased when the hydrophobic molecules are aggregated to form a cluster. The entropy of the system decreases; hence, the “cage-like” structure would be energetically unfavorable.

Answer 19

Summary Introduction

To explain: Why the cage-like structure would be energetically unfavorable.

Introduction: Water molecules in the ice are arranged in such a way that forms a cage-like structure due to the formation of intermolecular hydrogen bond in between the oxygen and hydrogen atom of two different water molecules.

Answer 20

Expert Solution

Explanation of Solution

The cage-like structure is a highly ordered structure. During its formation, free energy is required and the cost of the free energy is decreased when the hydrophobic molecules are aggregated to form a cluster. The entropy of the system decreases; hence, the “cage-like” structure would be energetically unfavorable.