The structure of the productformed by intramolecular Diels–-Alder reaction of the given compound at room temperature is to be drawn. Concept introduction: > The conjugate addition of alkene to diene is the Diels–-Alder reaction. Diels–-Alder reaction is a cycloaddition occurring through the formation of six-membered cyclic transition state.This is a concerted mechanism in which the single step reaction with no intermediate formation takes place. > Dienophile is the alkene that adds to diene.Diene is an electron-rich system attacksan electron deficient dienophile.The diene and dienophile, when residing in a single molecule, the intramolecular Diels–-Alder reaction is possible. > In order to form the cyclic transition state in Diels–-Alder reaction, the conjugated diene must be able to adopt s-cis conformation. > The s-cis conformation is the conformation of a single bond separated by two double bonds which are in the same plane and pointing in the same direction.The structure is shown below:

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Answer 1

Question

Chapter 11.13, Problem 21P

Interpretation Introduction

Interpretation:

The structure of the productformed by intramolecular Diels–-Alder reaction of the given compound at room temperature is to be drawn.

Concept introduction:
>
The conjugate addition of alkene to diene is the Diels–-Alder reaction. Diels–-Alder reaction is a cycloaddition occurring through the formation of six-membered cyclic transition state.This is a concerted mechanism in which the single step reaction with no intermediate formation takes place.
>
Dienophile is the alkene that adds to diene.Diene is an electron-rich system attacksan electron deficient dienophile.The diene and dienophile, when residing in a single molecule, the intramolecular Diels–-Alder reaction is possible.
>
In order to form the cyclic transition state in Diels–-Alder reaction, the conjugated diene must be able to adopt s-cis conformation.
>
The s-cis conformation is the conformation of a single bond separated by two double bonds which are in the same plane and pointing in the same direction.The structure is shown below:

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Explain the stereochemistry of the product of the Diels-Alder reaction shown below:

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Answer 2

Question

Chapter 11.13, Problem 21P

Interpretation Introduction

Interpretation:

The structure of the productformed by intramolecular Diels–-Alder reaction of the given compound at room temperature is to be drawn.

Concept introduction:
>
The conjugate addition of alkene to diene is the Diels–-Alder reaction. Diels–-Alder reaction is a cycloaddition occurring through the formation of six-membered cyclic transition state.This is a concerted mechanism in which the single step reaction with no intermediate formation takes place.
>
Dienophile is the alkene that adds to diene.Diene is an electron-rich system attacksan electron deficient dienophile.The diene and dienophile, when residing in a single molecule, the intramolecular Diels–-Alder reaction is possible.
>
In order to form the cyclic transition state in Diels–-Alder reaction, the conjugated diene must be able to adopt s-cis conformation.
>
The s-cis conformation is the conformation of a single bond separated by two double bonds which are in the same plane and pointing in the same direction.The structure is shown below:

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Answer 3

Question

Chapter 11.13, Problem 21P

Interpretation Introduction

Interpretation:

The structure of the productformed by intramolecular Diels–-Alder reaction of the given compound at room temperature is to be drawn.

Concept introduction:
>
The conjugate addition of alkene to diene is the Diels–-Alder reaction. Diels–-Alder reaction is a cycloaddition occurring through the formation of six-membered cyclic transition state.This is a concerted mechanism in which the single step reaction with no intermediate formation takes place.
>
Dienophile is the alkene that adds to diene.Diene is an electron-rich system attacksan electron deficient dienophile.The diene and dienophile, when residing in a single molecule, the intramolecular Diels–-Alder reaction is possible.
>
In order to form the cyclic transition state in Diels–-Alder reaction, the conjugated diene must be able to adopt s-cis conformation.
>
The s-cis conformation is the conformation of a single bond separated by two double bonds which are in the same plane and pointing in the same direction.The structure is shown below:

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Answer 4

Question

Chapter 11.13, Problem 21P

Interpretation Introduction

Interpretation:

The structure of the productformed by intramolecular Diels–-Alder reaction of the given compound at room temperature is to be drawn.

Concept introduction:
>
The conjugate addition of alkene to diene is the Diels–-Alder reaction. Diels–-Alder reaction is a cycloaddition occurring through the formation of six-membered cyclic transition state.This is a concerted mechanism in which the single step reaction with no intermediate formation takes place.
>
Dienophile is the alkene that adds to diene.Diene is an electron-rich system attacksan electron deficient dienophile.The diene and dienophile, when residing in a single molecule, the intramolecular Diels–-Alder reaction is possible.
>
In order to form the cyclic transition state in Diels–-Alder reaction, the conjugated diene must be able to adopt s-cis conformation.
>
The s-cis conformation is the conformation of a single bond separated by two double bonds which are in the same plane and pointing in the same direction.The structure is shown below:

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Answer 5

Chapter 11.13, Problem 21P

Interpretation Introduction

Interpretation:

The structure of the productformed by intramolecular Diels–-Alder reaction of the given compound at room temperature is to be drawn.

Concept introduction:
>
The conjugate addition of alkene to diene is the Diels–-Alder reaction. Diels–-Alder reaction is a cycloaddition occurring through the formation of six-membered cyclic transition state.This is a concerted mechanism in which the single step reaction with no intermediate formation takes place.
>
Dienophile is the alkene that adds to diene.Diene is an electron-rich system attacksan electron deficient dienophile.The diene and dienophile, when residing in a single molecule, the intramolecular Diels–-Alder reaction is possible.
>
In order to form the cyclic transition state in Diels–-Alder reaction, the conjugated diene must be able to adopt s-cis conformation.
>
The s-cis conformation is the conformation of a single bond separated by two double bonds which are in the same plane and pointing in the same direction.The structure is shown below:

Answer 6

Chapter 11.13, Problem 21P

Interpretation Introduction

Interpretation:

The structure of the productformed by intramolecular Diels–-Alder reaction of the given compound at room temperature is to be drawn.

Concept introduction:
>
The conjugate addition of alkene to diene is the Diels–-Alder reaction. Diels–-Alder reaction is a cycloaddition occurring through the formation of six-membered cyclic transition state.This is a concerted mechanism in which the single step reaction with no intermediate formation takes place.
>
Dienophile is the alkene that adds to diene.Diene is an electron-rich system attacksan electron deficient dienophile.The diene and dienophile, when residing in a single molecule, the intramolecular Diels–-Alder reaction is possible.
>
In order to form the cyclic transition state in Diels–-Alder reaction, the conjugated diene must be able to adopt s-cis conformation.
>
The s-cis conformation is the conformation of a single bond separated by two double bonds which are in the same plane and pointing in the same direction.The structure is shown below:

Answer 7

Chapter 11.13, Problem 21P

Interpretation Introduction

Interpretation:

The structure of the productformed by intramolecular Diels–-Alder reaction of the given compound at room temperature is to be drawn.

Concept introduction:
>
The conjugate addition of alkene to diene is the Diels–-Alder reaction. Diels–-Alder reaction is a cycloaddition occurring through the formation of six-membered cyclic transition state.This is a concerted mechanism in which the single step reaction with no intermediate formation takes place.
>
Dienophile is the alkene that adds to diene.Diene is an electron-rich system attacksan electron deficient dienophile.The diene and dienophile, when residing in a single molecule, the intramolecular Diels–-Alder reaction is possible.
>
In order to form the cyclic transition state in Diels–-Alder reaction, the conjugated diene must be able to adopt s-cis conformation.
>
The s-cis conformation is the conformation of a single bond separated by two double bonds which are in the same plane and pointing in the same direction.The structure is shown below:

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 11.1 - Prob. 1P Ch. 11.1 - Prob. 2P Ch. 11.2 - The two compounds shown differ by a factor of 60...Ch. 11.2 - Prob. 4P Ch. 11.2 - Prob. 5P Ch. 11.2 - Prob. 6P Ch. 11.3 - Prob. 7P Ch. 11.3 - Prob. 8P Ch. 11.3 - Evaluate 2,3,3-trimethyl-1-butene as a candidate...Ch. 11.4 - After heating a solution of allyl tert-butyl...

Solution Summary: The author explains that the structure of the product formed by intramolecular Diels–-Alder reaction at room temperature is rightly drawn.

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