Chemistry: The Molecular Nature of Matter and Change - Standalone book
Chemistry: The Molecular Nature of Matter and Change - Standalone book
7th Edition
ISBN: 9780073511177
Author: Martin Silberberg Dr., Patricia Amateis Professor
Publisher: McGraw-Hill Education
Question
Book Icon
Chapter 12, Problem 12.147P

(a)

Interpretation Introduction

Interpretation:

The solvent that has stronger interactions with the polymer is to be identified.

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other.

Viscosity is the quantity that determines the resistance of the liquid to flow. Both liquids and gases can flow but gases have high viscosity than liquids. Viscosity is directly related to the intermolecular forces and therefore increases with increase in the intermolecular forces.

The formula to calculate the intrinsic viscosity is as follows:

[η]sovent=(K)(Ma) (1)

Here,

[η]sovent is the intrinsic viscosity of a solvent.

K and a are constants specific to the polymer and solvent.

M is the molar mass of the polymer.

(b)

Interpretation Introduction

The intrinsic viscosity of benzene is to be calculated. Also, the use of intrinsic viscosity in a given solvent to determine the molar mass of any sample of that polymer is to be determined.

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other.

Viscosity is the quantity that determines the resistance of the liquid to flow. Both liquids and gases can flow but gases have high viscosity than liquids. Viscosity is directly related to the intermolecular forces and therefore increases with increase in the intermolecular forces.

The formula to calculate the intrinsic viscosity is as follows:

[η]sovent=(K)(Ma) (1)

Here,

[η]sovent is the intrinsic viscosity of a solvent.

K and a are constants specific to the polymer and solvent.

M is the molar mass of the polymer.

(c)

Interpretation Introduction

The intrinsic viscosity values of a polyisobutylene sample and polystyrene sample are to be compared. Also, the solvent-polymer interactions of both the samples are to be determined.

Concept introduction:

Viscosity is the quantity that determines the resistance of the liquid to flow. Both liquids and gases can flow but gases have high viscosity than liquids. Viscosity is directly related to the intermolecular forces and therefore increases with increase in the intermolecular forces.

The formula to calculate the intrinsic viscosity is as follows:

[η]sovent=(K)(Ma) (1)

Here,

[η]sovent is the intrinsic viscosity of a solvent.

K and a are constants specific to the polymer and solvent.

M is the molar mass of the polymer.

Blurred answer

Chapter 12 Solutions

Chemistry: The Molecular Nature of Matter and Change - Standalone book

Ch. 12.6 - For each of the following crystalline solids,...Ch. 12.6 - Prob. 12.6BFPCh. 12.6 - Prob. 12.7AFPCh. 12.6 - Iron crystallizes in a body-centered cubic...Ch. 12.6 - Prob. 12.8AFPCh. 12.6 - Prob. 12.8BFPCh. 12.6 - Prob. B12.1PCh. 12.6 - Prob. B12.2PCh. 12 - Prob. 12.1PCh. 12 - Prob. 12.2PCh. 12 - Prob. 12.3PCh. 12 - Prob. 12.4PCh. 12 - Prob. 12.5PCh. 12 - Prob. 12.6PCh. 12 - Prob. 12.7PCh. 12 - Name the phase change in each of these events: (a)...Ch. 12 - Prob. 12.9PCh. 12 - Many heat-sensitive and oxygen-sensitive solids,...Ch. 12 - Prob. 12.11PCh. 12 - Prob. 12.12PCh. 12 - Prob. 12.13PCh. 12 - Prob. 12.14PCh. 12 - Prob. 12.15PCh. 12 - Prob. 12.16PCh. 12 - Prob. 12.17PCh. 12 - Prob. 12.18PCh. 12 - From the data below, calculate the total heat (in...Ch. 12 - Prob. 12.20PCh. 12 - Prob. 12.21PCh. 12 - Prob. 12.22PCh. 12 - Prob. 12.23PCh. 12 - Prob. 12.24PCh. 12 - Prob. 12.25PCh. 12 - Prob. 12.26PCh. 12 - Prob. 12.27PCh. 12 - Prob. 12.28PCh. 12 - Prob. 12.29PCh. 12 - Prob. 12.30PCh. 12 - Use Figure 12.10 to answer the following: Carbon...Ch. 12 - Prob. 12.32PCh. 12 - Prob. 12.33PCh. 12 - Prob. 12.34PCh. 12 - Prob. 12.35PCh. 12 - Prob. 12.36PCh. 12 - Distinguish between polarizability and polarity....Ch. 12 - Prob. 12.38PCh. 12 - Prob. 12.39PCh. 12 - Prob. 12.40PCh. 12 - Prob. 12.41PCh. 12 - Prob. 12.42PCh. 12 - Prob. 12.43PCh. 12 - Prob. 12.44PCh. 12 - Prob. 12.45PCh. 12 - Prob. 12.46PCh. 12 - Prob. 12.47PCh. 12 - Prob. 12.48PCh. 12 - Prob. 12.49PCh. 12 - Which liquid in each pair has the lower vapor...Ch. 12 - Which substance has the lower boiling point?...Ch. 12 - Which substance has the higher boiling point?...Ch. 12 - Prob. 12.53PCh. 12 - Prob. 12.54PCh. 12 - Prob. 12.55PCh. 12 - Prob. 12.56PCh. 12 - Why does the antifreeze ingredient ethylene glycol...Ch. 12 - Prob. 12.58PCh. 12 - Prob. 12.59PCh. 12 - Why does an aqueous solution of ethanol (CH3CH2OH)...Ch. 12 - Prob. 12.61PCh. 12 - Prob. 12.62PCh. 12 - Prob. 12.63PCh. 12 - Prob. 12.64PCh. 12 - Prob. 12.65PCh. 12 - Prob. 12.66PCh. 12 - Prob. 12.67PCh. 12 - Prob. 12.68PCh. 12 - Prob. 12.69PCh. 12 - Prob. 12.70PCh. 12 - Prob. 12.71PCh. 12 - Prob. 12.72PCh. 12 - Prob. 12.73PCh. 12 - Prob. 12.74PCh. 12 - Prob. 12.75PCh. 12 - Prob. 12.76PCh. 12 - Prob. 12.77PCh. 12 - Prob. 12.78PCh. 12 - Prob. 12.79PCh. 12 - Prob. 12.80PCh. 12 - Prob. 12.81PCh. 12 - Prob. 12.82PCh. 12 - Prob. 12.83PCh. 12 - Prob. 12.84PCh. 12 - Besides the type of unit cell, what information is...Ch. 12 - What type of unit cell does each metal use in its...Ch. 12 - What is the number of atoms per unit cell for each...Ch. 12 - Calcium crystallizes in a cubic closest packed...Ch. 12 - Chromium adopts the body-centered cubic unit cell...Ch. 12 - Prob. 12.90PCh. 12 - Prob. 12.91PCh. 12 - Prob. 12.92PCh. 12 - Prob. 12.93PCh. 12 - Prob. 12.94PCh. 12 - Prob. 12.95PCh. 12 - Prob. 12.96PCh. 12 - Prob. 12.97PCh. 12 - Prob. 12.98PCh. 12 - Prob. 12.99PCh. 12 - Prob. 12.100PCh. 12 - Prob. 12.101PCh. 12 - Prob. 12.102PCh. 12 - Prob. 12.103PCh. 12 - Polonium, the Period 6 member of Group 6A(16), is...Ch. 12 - Prob. 12.105PCh. 12 - Prob. 12.106PCh. 12 - Prob. 12.107PCh. 12 - Prob. 12.108PCh. 12 - Prob. 12.109PCh. 12 - Prob. 12.110PCh. 12 - Prob. 12.111PCh. 12 - Prob. 12.112PCh. 12 - Prob. 12.113PCh. 12 - Prob. 12.114PCh. 12 - Prob. 12.115PCh. 12 - Prob. 12.116PCh. 12 - Prob. 12.117PCh. 12 - Prob. 12.118PCh. 12 - Prob. 12.119PCh. 12 - Prob. 12.120PCh. 12 - Prob. 12.121PCh. 12 - Prob. 12.122PCh. 12 - Prob. 12.123PCh. 12 - Prob. 12.124PCh. 12 - Prob. 12.125PCh. 12 - Prob. 12.126PCh. 12 - Bismuth is used to calibrate instruments employed...Ch. 12 - Prob. 12.128PCh. 12 - Prob. 12.129PCh. 12 - Prob. 12.130PCh. 12 - Prob. 12.131PCh. 12 - Prob. 12.132PCh. 12 - Prob. 12.133PCh. 12 - Prob. 12.134PCh. 12 - Prob. 12.135PCh. 12 - Prob. 12.136PCh. 12 - Prob. 12.137PCh. 12 - Prob. 12.138PCh. 12 - Prob. 12.139PCh. 12 - Prob. 12.140PCh. 12 - Prob. 12.141PCh. 12 - Prob. 12.142PCh. 12 - Prob. 12.143PCh. 12 - Prob. 12.144PCh. 12 - Prob. 12.145PCh. 12 - The crystal structure of sodium is based on the...Ch. 12 - Prob. 12.147PCh. 12 - One way of purifying gaseous H2 is to pass it...
Knowledge Booster
Background pattern image
Recommended textbooks for you
Text book image
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Text book image
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Text book image
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Text book image
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Text book image
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Text book image
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY