ORGANIC CHEMISTRY LSLF W/CONNECT >BI<
ORGANIC CHEMISTRY LSLF W/CONNECT >BI<
5th Edition
ISBN: 9781260293609
Author: SMITH
Publisher: MCG CUSTOM
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Chapter 12, Problem 12.37P

Stearidonic acid (C18H28O2) is an unsaturated fatty acid obtained from oils isolated from hemp and blackcurrant

Chapter 12, Problem 12.37P, 12.37 Stearidonic acid (C18H28O2) is an unsaturated fatty acid obtained from oils isolated from hemp

a. What fatty acid is formed when stearidonic acid is hydrogenated with excess H 2 and a Pd-C catalyst?

b. What fatty acids are formed when stearidonic acid is hydrogenated with one equivalent of H 2 and a Pd-C catalyst?

c. Draw the structure of a possible product formed when stearidonic acid is hydrogenated with one equivalent of H 2 and a Pd-C catalyst, and one double bond is isomerized to a trans isomer.

d. How do the melting points of the following fatty acids compare: stearidonic acid; one of the products formed in part (b); the product drawn in part (c)?

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Stearidonic acid (C18H28O2) is an unsaturated fatty acid obtained fromoils isolated from hemp and blackcurrant a.) What fatty acid is formed when stearidonic acid is hydrogenated withexcess H2 and a Pd catalyst?b.) What fatty acids are formed when stearidonic acid is hydrogenatedwith one equivalent of H2 and a Pd catalyst?c.) Draw the structure of a possible product formed when stearidonic acidis hydrogenated with one equivalent of H2 and a Pd catalyst, and onedouble bond is isomerized to a trans isomer.d.) How do the melting points of the following fatty acids compare:stearidonic acid; one of the products formed in part (b); the productdrawn in part (c)?
Stearidonic acid (C18H28O2) is an unsaturated fatty acid obtained from oils isolated from hemp and blackcurrant (see also Problem 10.11).a.What fatty acid is formed when stearidonic acid is hydrogenated with excess H2 and a Pd catalyst? b.What fatty acids are formed when stearidonic acid is hydrogenated with one equivalent of H2 and a Pd catalyst? c. Draw the structure of a possible product formed when stearidonic acid is hydrogenated with one equivalent of H2 and a Pd catalyst, and one double bond is isomerized to a trans isomer. d.How do the melting points of the following fatty acids compare: stearidonic acid; one of the products formed in part (b); the product drawn in part (c)?
Arachidonic acid is a 20-carbon polyunsaturated essential fatty acid with 4 double bonds at positions omega-6, omega-9, omega-12, and omega-15. Draw the naturally occurring form of this fat.

Chapter 12 Solutions

ORGANIC CHEMISTRY LSLF W/CONNECT >BI<

Ch. 12 - Problem 12.11 (a) Draw the structure of a compound...Ch. 12 - Prob. 12.12PCh. 12 - Prob. 12.13PCh. 12 - Problem 12.14 Draw the products of each...Ch. 12 - Prob. 12.15PCh. 12 - Problem 12.16 Draw all stereoisomers formed when...Ch. 12 - Prob. 12.17PCh. 12 - Problem 12.18 Draw the products formed when both...Ch. 12 - Problem 12.19 Draw the products formed when each...Ch. 12 - Prob. 12.20PCh. 12 - Prob. 12.21PCh. 12 - Problem 12.22 Draw the products formed when each...Ch. 12 - Prob. 12.23PCh. 12 - Problem 12.24 Draw the organic products in each of...Ch. 12 - Prob. 12.25PCh. 12 - Prob. 12.26PCh. 12 - Problem 12.27 Draw the products of each Sharpless...Ch. 12 - Prob. 12.28PCh. 12 - 12.29 Draw the products formed when A is treated...Ch. 12 - Prob. 12.30PCh. 12 - 12.31 Devise a synthesis of the following compound...Ch. 12 - Prob. 12.32PCh. 12 - Prob. 12.33PCh. 12 - Prob. 12.34PCh. 12 - Prob. 12.35PCh. 12 - Prob. 12.36PCh. 12 - 12.37 Stearidonic acid (C18H28O2) is an...Ch. 12 - Draw the organic products formed when cyclopentene...Ch. 12 - Draw the organic products formed when allylic...Ch. 12 - Draw the organic products formed in each reaction....Ch. 12 - Prob. 12.41PCh. 12 - Prob. 12.42PCh. 12 - Prob. 12.43PCh. 12 - What alkene is needed to synthesize each 1,2-diol...Ch. 12 - Prob. 12.45PCh. 12 - 12.46 (a)What product is formed in Step [1] of the...Ch. 12 - Draw the products formed after Steps 1 and 2 in...Ch. 12 - 12.48 Draw the products formed in each oxidative...Ch. 12 - What alkene or alkyne yields each set of products...Ch. 12 - Prob. 12.50PCh. 12 - Prob. 12.51PCh. 12 - Prob. 12.52PCh. 12 - Prob. 12.53PCh. 12 - 12.54 An unknown compound A of molecular formula ...Ch. 12 - 12.55 DHA is a fatty acid derived from fish oil...Ch. 12 - Prob. 12.56PCh. 12 - 12.57 Draw the product of each asymmetric...Ch. 12 - 12.58 Epoxidation of the following allylic alcohol...Ch. 12 - Prob. 12.59PCh. 12 - 12.60 Identify A in the following reaction...Ch. 12 - Prob. 12.61PCh. 12 - 12.62 It is sometimes necessary to isomerize a cis...Ch. 12 - 12.63 Devise a synthesis of each compound from...Ch. 12 - Prob. 12.64PCh. 12 - Prob. 12.65PCh. 12 - 12.66 Devise a synthesis of each compound from the...Ch. 12 - Prob. 12.67PCh. 12 - Prob. 12.68PCh. 12 - 12.69 Devise a synthesis of each compound from as...Ch. 12 - Prob. 12.70PCh. 12 - Prob. 12.71PCh. 12 - 12.72 Draw a stepwise mechanism for the following...Ch. 12 - Prob. 12.73PCh. 12 - Prob. 12.74PCh. 12 - 12.75 Sharpless epoxidation of allylic alcohol X...
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