Interpretation:
The preparation of
Concept introduction:
When
Hydroboration-oxidation of
The regioselectivity is opposite to that of Markovnikov's rule.
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ORGANIC CHEMISTRY,VOL.1 >CUSTOM<
- prepare a flow sheet for the preparation of benzoic acid from a) bromobenzene and magnesium and b) phenylmagnesium bromide and carbon dioxide. using your knowledge of the physical properties of the solvents, reactants, and products, show how the products can be purified, indicate which layer should contain the product in the liquid/liquid extraction steps.arrow_forwardDescribe two synthetic routes for the preparation of p-methoxyaniline from benzene.arrow_forwardStarting with benzene, give a sequence of laboratory reactions which could be used to prepare p-isopropylaniline. If separation of ortho, meta, or para-isomers is required, give evidence that it is feasible.arrow_forward
- Suggest a synthesis for the molecule below starting from benzene, alcohols of four carbons or fewer and any inorganic reagentsarrow_forwardShow how to convert carboxylic acids to other functional groups, and devisemultistep syntheses using carboxylic acids as starting materials and intermediates.Explain how acid chlorides are used as activated derivatives of carboxylic acidsarrow_forwardSuggest a reasonable synthetic strategy for synthesizing 3,5-dichlorobenzyl amine from benzaldehyde.arrow_forward
- 1. You have been given a mixture of toluene,aniline and benzoic acid dissolved in chloroform.explain in detail with the aid of a flow diagram and reaction schemes,how you would separate the mixture into pure componentsarrow_forwardOutline the steps invloved in the synthesis of 3-chloro-4-fluroacetophenone from 4-aminoacetophenone. provide the bond line structure for the major organic product obtained in each step of the proposed synthesis.arrow_forwardObtain 3-chloro-4-nitrophenol by starting from benzene and by diazotization using suitable reagents.arrow_forward
- Provide a step by step mechanism for the conversion of cuclohexanol in hot concentrated phosphoric acidarrow_forwardAn organic was subjected to sodium fusion and the resulting Lassaigne’s extract boiled with FeSO4 and acidified with concentrated H2SO4, yielding a Prussian blue color. Give an example of a compound fits this description?arrow_forwardYou could extract caffeine from neutral organics by treatment with aqueous HCl (acid). Write the structure of the conjugate acid of caffeine (after treatment with HCl) and explain why it would dissolve in the aqueous layer.arrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning