An Introduction to Physical Science
14th Edition
ISBN: 9781305079137
Author: James Shipman, Jerry D. Wilson, Charles A. Higgins, Omar Torres
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Videos
Textbook Question
Chapter 12.6, Problem 12.9CE
Boron trifluoride, BF3, is an exception to the octet rule. A single bond extends from each fluorine atom to the boron atom, which has a share in only six electrons. The three bonds are polar, yet the molecule itself is nonpolar. What must be the geometry of the molecule and the angle between the bonds?
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
In the methane molecule, CH4, each hydrogen atom is at a corner of a regular tetrahedron with the carbon atom at the center. In coordinates where one of the C-H bonds is in the direction of i + j + k (i-hat + j-hat + k-hat) an adjacent C-H bond is in the direction of i - j - k (i-hat minus j-hat minus k-hat). What is the angle between these two bonds? "
a) 100 degrees
b) 109 degrees
c) 200 degrees
d) 209 degrees
The effective spring constant associated with bonding in the N2 molecule is 2 297 N/m. The nitrogen atoms each have a mass of 2.32 x 10-26 kg, and their nuclei are 0.120 nm apart. Assume the molecule is rigid. The first excited vibrational state of the molecule is above the vibrational ground state by an energy difference ΔE. Calculate the J value of the rotational state that is above the rotational ground state by the same energy difference ΔE.
The internuclear distance (bond length) of carbon monoxide molecule is 1.13 Å. Calculate the energy (in joules and eV) of this molecule in the first excited rotational level. Also calculate the angular velocity of the molecule. Given atomic masses of 12^C = 1.99x10^-26 kg; 16^O = 2.66x10^-26 kg.
Chapter 12 Solutions
An Introduction to Physical Science
Ch. 12.1 - Prob. 1PQCh. 12.1 - Prob. 2PQCh. 12.1 - Prob. 12.1CECh. 12.2 - Prob. 1PQCh. 12.2 - Prob. 2PQCh. 12.2 - Find the formula mass of hydrogen sulfide, H2S,...Ch. 12.2 - Prob. 12.3CECh. 12.3 - Prob. 1PQCh. 12.3 - Prob. 2PQCh. 12.4 - Prob. 1PQ
Ch. 12.4 - Prob. 2PQCh. 12.4 - Prob. 12.4CECh. 12.4 - Prob. 12.5CECh. 12.5 - Prob. 1PQCh. 12.5 - Prob. 2PQCh. 12.5 - Prob. 12.6CECh. 12.6 - Is PCl3 ionic or covalent in bonding? What about...Ch. 12.6 - Prob. 12.8CECh. 12.6 - Boron trifluoride, BF3, is an exception to the...Ch. 12.6 - Prob. 1PQCh. 12.6 - Prob. 2PQCh. 12 - Prob. AMCh. 12 - Prob. BMCh. 12 - Prob. CMCh. 12 - Prob. DMCh. 12 - Prob. EMCh. 12 - Prob. FMCh. 12 - Prob. GMCh. 12 - Prob. HMCh. 12 - Prob. IMCh. 12 - Prob. JMCh. 12 - Prob. KMCh. 12 - Prob. LMCh. 12 - Prob. MMCh. 12 - Prob. NMCh. 12 - Prob. OMCh. 12 - Prob. PMCh. 12 - Prob. QMCh. 12 - Prob. RMCh. 12 - Prob. SMCh. 12 - Prob. 1MCCh. 12 - Prob. 2MCCh. 12 - Prob. 3MCCh. 12 - Prob. 4MCCh. 12 - Prob. 5MCCh. 12 - Prob. 6MCCh. 12 - Prob. 7MCCh. 12 - Prob. 8MCCh. 12 - Prob. 9MCCh. 12 - Prob. 10MCCh. 12 - Sodium reacts with a certain element to form a...Ch. 12 - Prob. 12MCCh. 12 - Prob. 13MCCh. 12 - Carbon is a Group 4A element. How many covalent...Ch. 12 - How many shared pairs of electrons are in an...Ch. 12 - Prob. 16MCCh. 12 - Prob. 17MCCh. 12 - Prob. 18MCCh. 12 - Prob. 1FIBCh. 12 - Prob. 2FIBCh. 12 - Prob. 3FIBCh. 12 - Prob. 4FIBCh. 12 - Prob. 5FIBCh. 12 - Prob. 6FIBCh. 12 - Prob. 7FIBCh. 12 - The formula of an ionic compound of a Group 1A...Ch. 12 - Prob. 9FIBCh. 12 - Prob. 10FIBCh. 12 - Prob. 11FIBCh. 12 - Prob. 12FIBCh. 12 - Prob. 1SACh. 12 - Prob. 2SACh. 12 - Prob. 3SACh. 12 - Prob. 4SACh. 12 - Prob. 5SACh. 12 - Prob. 6SACh. 12 - Prob. 7SACh. 12 - Prob. 8SACh. 12 - Prob. 9SACh. 12 - Prob. 10SACh. 12 - Prob. 11SACh. 12 - Prob. 12SACh. 12 - Prob. 13SACh. 12 - Prob. 14SACh. 12 - Prob. 15SACh. 12 - Prob. 16SACh. 12 - Prob. 17SACh. 12 - Prob. 18SACh. 12 - Prob. 19SACh. 12 - Prob. 20SACh. 12 - Prob. 21SACh. 12 - Prob. 22SACh. 12 - Prob. 23SACh. 12 - Prob. 24SACh. 12 - Prob. 25SACh. 12 - A covalent bond in which the electron pair is...Ch. 12 - Could a molecule composed of two atoms joined by a...Ch. 12 - Explain how a polyatomic ion such as carbonate...Ch. 12 - Prob. 29SACh. 12 - Prob. 30SACh. 12 - Prob. 31SACh. 12 - State the short general principle of solubility,...Ch. 12 - Prob. 33SACh. 12 - Prob. 1VCCh. 12 - You decide to have hot dogs for dinner. In the...Ch. 12 - Why cant we destroy bothersome pollutants by just...Ch. 12 - Prob. 3AYKCh. 12 - When you use a bottle of vinegar-and-oil salad...Ch. 12 - Prob. 5AYKCh. 12 - Prob. 6AYKCh. 12 - Prob. 1ECh. 12 - An antacid tablet weighing 0.942 g contained...Ch. 12 - Calculate (to the nearest 0.1 u) the formula mass...Ch. 12 - Calculate (to the nearest 0.1 u) the formula mass...Ch. 12 - Find the percentage by mass of Cl in MgCl2 if it...Ch. 12 - Prob. 6ECh. 12 - Prob. 7ECh. 12 - Prob. 8ECh. 12 - Prob. 9ECh. 12 - Prob. 10ECh. 12 - Prob. 11ECh. 12 - Prob. 12ECh. 12 - Prob. 13ECh. 12 - Prob. 14ECh. 12 - Prob. 15ECh. 12 - Write the Lewis symbols and structures that show...Ch. 12 - Prob. 17ECh. 12 - Prob. 18ECh. 12 - Prob. 19ECh. 12 - Prob. 20ECh. 12 - Referring only to a periodic table, give the...Ch. 12 - Referring only to a periodic table, give the...Ch. 12 - Prob. 23ECh. 12 - Draw the Lewis structure for formaldehyde, H2CO, a...Ch. 12 - Prob. 25ECh. 12 - Prob. 26ECh. 12 - Prob. 27ECh. 12 - Prob. 28ECh. 12 - Use arrows to show the polarity of each bond in...Ch. 12 - Use arrows to show the polarity of each bond in...Ch. 12 - Prob. 31ECh. 12 - Prob. 32E
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, physics and related others by exploring similar questions and additional content below.Similar questions
- Suppose that the wavenumber of the J = 1 ← 0 rotational transition of 1H81Br considered as a rigid rotor was measured to be 18.20 cm-1, what is (a) the moment of inertia of the molecule? _____________kg-m2 (b) the bond length? ________________Angstroms (Given the isotopic masses:(m(79Br) = 78.9183 amu, m(81Br) = 80.9163 amuarrow_forwardIn the methane molecule, CH4, each hydrogen atom is at the corner of a regular tetrahedron with the carbon atom at the center. If one of the C-H is in the direction ofarrow_forwardThe CO molecule undergoes a rotational transition from the ℓ = 1 level to the ℓ = 2 level. Using Table 11.1, calculate the values of the reduced mass and the bond length of the molecule. Compare your results with those of Example 11.1.arrow_forward
- Consider the HCl molecule, which consists of a hydrogen atom of mass 1 u bound to a chlorine atom of mass 35 u. The equilibrium separation between the atoms is 0.128 nm, and it requires 0.15 eV of work to increase or decrease this separation by 0.01 nm. (a) Calculate the four lowest rotational energies (in eV) that are possible, assuming the molecule rotates rigidly. (b) Find the molecules spring constant and its classical frequency of vibration. (Hint: Recall that U=12Kx2.) (c) Find the two lowest vibrational energies and the classical amplitude of oscillation corresponding to each of these energies. (d) Determine the longest wavelength radiation that the molecule can emit in a pure rotational transition and in a pure vibrational transition.arrow_forwardThe rotational temperature of the Oxygen molecule is 2.08 K. Estimate the molecular rotational partition function of Oxygen at 300K. a. 72.1 b.288.4 c.-144.2 d.none of the above e.144.2arrow_forwardTo determine the equilibrium separation of the atoms in the HCl molecule, you measure the rotational spectrum of HCl. You find that the spectrum contains these wavelengths (among others): 60.4 mm, 69.0 mm, 80.4 mm, 96.4 mm, and 120.4 mm. (a) Use your measured wavelengths to find the moment of inertia of the HCl molecule about an axis through the center of mass and perpendicular to the line joining the two nuclei. (b) The value of l changes by +-1 in rotational transitions. What value of l for the upper level of the transition gives rise to each of these wavelengths? (c) Use your result of part (a) to calculate the equilibrium separation of the atoms in the HCl molecule. The mass of a chlorine atom is 5.81 * 10-26 kg, and the mass of a hydrogen atom is 1.67 * 10-27 kg. (d) What is the longest-wavelength line in the rotational spectrum of HCl?arrow_forward
- Let's consider the three atoms composing the molecule now have different masses and coordinate, while the axis of rotation is still z axis that is perpendicular to the xy plane. The first atom has a mass of 142.54 kg, with x coordinate at 3 m and y coordinate at 6 m. The second atom has a mass of 82.55 kg, with x coordinate at 1 m and y coordinate at 6 m. The third atom has a mass of 8 kg, with x coordinate at 5 m and y coordinate at 9 m. What is the moment of inertia in unit of kg m2 with respect to the x axis?arrow_forwardDetermine the strength of the electric field needed to induce a dipole moment of 1.2 mD in a molecule with a polarizability of 2.31 x 10-40 J-1 C2 m2. Express your answer in units of MV/m with two decimals.arrow_forwardA = 1.05i + 1j + 1.08kB = 0.98i + -0.81j + -0.92k What is the angle (in degrees) between the bonds based on this new data?arrow_forward
- Hydrogen molecule has force constant 570 Nm 1. A hydrogen molecule is given a total vibration of 2.00 x 10- 19 J. Calculate 1) the maximum bond elongation and 2) maximum force at this energy.arrow_forwardAccording to a new spectroscopy analysis, the adjacent bond vectors was found to be A = 1.07i + 0.83j + 0.81k B = 1.03i + -0.99j + -0.85k What is the angle (in degrees) between the bonds based on this new data?arrow_forwardindicate the following lattice points (211) , (111) and (1 0 1) in an orthorhombic lattice structure with sides a= 5cm,, b =6cm and C =7cmYour answerarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Modern PhysicsPhysicsISBN:9781111794378Author:Raymond A. Serway, Clement J. Moses, Curt A. MoyerPublisher:Cengage Learning
Modern Physics
Physics
ISBN:9781111794378
Author:Raymond A. Serway, Clement J. Moses, Curt A. Moyer
Publisher:Cengage Learning
The Laws of Thermodynamics, Entropy, and Gibbs Free Energy; Author: Professor Dave Explains;https://www.youtube.com/watch?v=8N1BxHgsoOw;License: Standard YouTube License, CC-BY