THERMODYNAMICS LLF W/ CONNECT ACCESS
9th Edition
ISBN: 9781264446889
Author: CENGEL
Publisher: MCG
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Textbook Question
Chapter 12.6, Problem 7P
Conside the function z(x, y), its partial derivatives (∂z/∂x)y and (∂z/∂y)x, and the total derivative dz/dx.
- (a) How do the magnitudes (∂x)y and dx compare?
- (b) How do the magnitudes (∂z)y and dz compare?
- (c) Is there any relation among dz, (∂z)x, and (∂z)y?
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For the situation shown in the figure below the
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(b) H= (R+ r) + (D + r)
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(c) H=(R+r)+ VD -R
(d) H= (R+r)+ 2D(R+r)- D
The following thermodynamic potential functions H (enthalpy), A (Helmholtz function), G (Gibbs function) and U (internal energy) are connected by a system known as Maxwell's relations. Explain what is meant by Maxwell relations. If you know that dU = – P dV + T dS (P is pressure, V is volume, S is entropy and T is temperature), use the Legendre differential transformation to prove that dA = – P dV – S dT. In your own words, explain the role and importance of functions A and U.
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(a) An ideal gas expands adiabatically from a volume of 2.5 x 10-3 m³ to 3.0 x 10-3 m³. If the initial pressure and temperature were 5.0 x 10 Pa and 295 K, respectively, what are the final pressure (in Pa) and temperature (in K) of the gas? Use y =
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(b) In an isothermal process, an ideal gas expands from a volume of 2.5 x 10-3 m³ to 3.0 x 10-3 m³. If the initial pressure and temperature were 5.0 x 10° Pa and 295 K, respectively, what are the final pressure (in Pa) and temperature (in K) of the gas?
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Chapter 12 Solutions
THERMODYNAMICS LLF W/ CONNECT ACCESS
Ch. 12.6 - What is the difference between partial...Ch. 12.6 - Consider the function z(x, y). Plot a differential...Ch. 12.6 - Consider a function z(x, y) and its partial...Ch. 12.6 - Prob. 4PCh. 12.6 - Prob. 5PCh. 12.6 - Consider a function f(x) and its derivative df/dx....Ch. 12.6 - Conside the function z(x, y), its partial...Ch. 12.6 - Consider air at 350 K and 0.75 m3/kg. Using Eq....Ch. 12.6 - Consider air at 350 K and 0.75 m3/kg. Using Eq....Ch. 12.6 - Nitrogen gas at 800 R and 50 psia behaves as an...
Ch. 12.6 - Consider an ideal gas at 400 K and 100 kPa. As a...Ch. 12.6 - Using the equation of state P(v a) = RT, verify...Ch. 12.6 - Prove for an ideal gas that (a) the P = constant...Ch. 12.6 - Verify the validity of the last Maxwell relation...Ch. 12.6 - Verify the validity of the last Maxwell relation...Ch. 12.6 - Show how you would evaluate T, v, u, a, and g from...Ch. 12.6 - Prob. 18PCh. 12.6 - Prob. 19PCh. 12.6 - Prob. 20PCh. 12.6 - Prove that (PT)=kk1(PT)v.Ch. 12.6 - Prob. 22PCh. 12.6 - Prob. 23PCh. 12.6 - Using the Clapeyron equation, estimate the...Ch. 12.6 - Prob. 26PCh. 12.6 - Determine the hfg of refrigerant-134a at 10F on...Ch. 12.6 - Prob. 28PCh. 12.6 - Prob. 29PCh. 12.6 - Two grams of a saturated liquid are converted to a...Ch. 12.6 - Prob. 31PCh. 12.6 - Prob. 32PCh. 12.6 - Prob. 33PCh. 12.6 - Prob. 34PCh. 12.6 - Prob. 35PCh. 12.6 - Prob. 36PCh. 12.6 - Determine the change in the internal energy of...Ch. 12.6 - Prob. 38PCh. 12.6 - Determine the change in the entropy of helium, in...Ch. 12.6 - Prob. 40PCh. 12.6 - Estimate the specific heat difference cp cv for...Ch. 12.6 - Derive expressions for (a) u, (b) h, and (c) s for...Ch. 12.6 - Derive an expression for the specific heat...Ch. 12.6 - Derive an expression for the specific heat...Ch. 12.6 - Derive an expression for the isothermal...Ch. 12.6 - Prob. 46PCh. 12.6 - Show that cpcv=T(PT)V(VT)P.Ch. 12.6 - Show that the enthalpy of an ideal gas is a...Ch. 12.6 - Prob. 49PCh. 12.6 - Show that = ( P/ T)v.Ch. 12.6 - Prob. 51PCh. 12.6 - Prob. 52PCh. 12.6 - Prob. 53PCh. 12.6 - Prob. 54PCh. 12.6 - Prob. 55PCh. 12.6 - Does the Joule-Thomson coefficient of a substance...Ch. 12.6 - The pressure of a fluid always decreases during an...Ch. 12.6 - Will the temperature of helium change if it is...Ch. 12.6 - Estimate the Joule-Thomson coefficient of...Ch. 12.6 - Estimate the Joule-Thomson coefficient of...Ch. 12.6 - Prob. 61PCh. 12.6 - Steam is throttled slightly from 1 MPa and 300C....Ch. 12.6 - What is the most general equation of state for...Ch. 12.6 - Prob. 64PCh. 12.6 - Consider a gas whose equation of state is P(v a)...Ch. 12.6 - Prob. 66PCh. 12.6 - What is the enthalpy departure?Ch. 12.6 - On the generalized enthalpy departure chart, the...Ch. 12.6 - Why is the generalized enthalpy departure chart...Ch. 12.6 - What is the error involved in the (a) enthalpy and...Ch. 12.6 - Prob. 71PCh. 12.6 - Saturated water vapor at 300C is expanded while...Ch. 12.6 - Determine the enthalpy change and the entropy...Ch. 12.6 - Prob. 74PCh. 12.6 - Prob. 75PCh. 12.6 - Prob. 77PCh. 12.6 - Propane is compressed isothermally by a...Ch. 12.6 - Prob. 81PCh. 12.6 - Prob. 82RPCh. 12.6 - Starting with the relation dh = T ds + vdP, show...Ch. 12.6 - Using the cyclic relation and the first Maxwell...Ch. 12.6 - For ideal gases, the development of the...Ch. 12.6 - Show that cv=T(vT)s(PT)vandcp=T(PT)s(vT)PCh. 12.6 - Temperature and pressure may be defined as...Ch. 12.6 - For a homogeneous (single-phase) simple pure...Ch. 12.6 - For a homogeneous (single-phase) simple pure...Ch. 12.6 - Prob. 90RPCh. 12.6 - Prob. 91RPCh. 12.6 - Estimate the cpof nitrogen at 300 kPa and 400 K,...Ch. 12.6 - Prob. 93RPCh. 12.6 - Prob. 94RPCh. 12.6 - Prob. 95RPCh. 12.6 - Methane is to be adiabatically and reversibly...Ch. 12.6 - Prob. 97RPCh. 12.6 - Prob. 98RPCh. 12.6 - Prob. 99RPCh. 12.6 - An adiabatic 0.2-m3 storage tank that is initially...Ch. 12.6 - Prob. 102FEPCh. 12.6 - Consider the liquidvapor saturation curve of a...Ch. 12.6 - For a gas whose equation of state is P(v b) = RT,...Ch. 12.6 - Prob. 105FEPCh. 12.6 - Prob. 106FEP
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