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- A 21.4-mL volume of hydrochloric acid reacts completely with a solid sample of MgCO3. The reaction is 2HCl(aq)+MgCO3(s)CO2(g)+H2O(l)+MgCl2(aq) The volume of CO2 formed is 159 mL at 23C and 731 mmHg. What is the molarity of the HCl solution?arrow_forwardAn organic compound contains C, H, N, and O. Combustion of 0.1023 g of the compound in excess oxygen yielded 0.2766 g CO2 and 0.0991 g H2O. A sample of 0.4831 g of the compound was analyzed for nitrogen by the Dumas method (see Exercise 129). At STP, 27.6 mL of dry N2 was obtained. In a third experiment, the density of the compound as a gas was found to be 4.02 g/L at 127C and 256 torr. What are the empirical and molecular formulas of the compound?arrow_forwardMany nitrate salts can be decomposed by heating. For example, blue, anhydrous copper(II) nitrate produces the gases nitrogen dioxide and oxygen when heated. In the laboratory, you find that a sample of this salt produced a 0.195-g mixture of gaseous NO2 and O2 with a total pressure of 725 mm Hg at 35 C in a 125-mL flask (and black, solid CuO was left as a residue). What is the average molar mass of the gas mixture? What are the mole fractions of NO2 and O2 in the mixture? What amount of each gas b in the mixture? Do these amounts reflect the relative amounts of NO2 and O2 expected based on the balanced equation? Is it possible that the fact that some NO2 molecules combine to give N2O4 plays a role? Heating copper(II) nitrate produces nitrogen dioxide and oxygen gas and leaves a residue of copper(ll) oxide.arrow_forward
- Potassium peroxide is used to absorb the CO2 produced by the people in a space vehicle. 2K2O2(s)+2CO2(g)2K2CO3(s)+O2(g)If a person at rest exhales 3.0 L of air per minute and CO2 is 3.4% (by volume) of exhaled air, how many grams of K2O2 are needed per person for a five-day trip. Assume a temperature of 250 and 728 mm Hg pressure.arrow_forward93 The complete combustion of octane can be used as a model for the burning of gasoline: 2C8H18+25O216CO2+18H2O Assuming that this equation provides a reasonable model of the actual combustion process, what volume of air at 1.0 atm and 25°C must be taken into an engine to burn 1 gallon of gasoline? (The partial pressure of oxygen in air is 0.21 atm and the density of liquid octane is 0.70 g/mL.)arrow_forward47 HCl(g) reacts with ammonia gas, NH3(g), to form solid ammonium chloride. If a sample of ammonia occupying 250 mL at 21 C and a pressure of 140 torr is allowed to react with excess HCl, what mass of NH4Cl will form?arrow_forward
- 54 One way to generate oxygen is to heat potassium chlorate, KClO3. (The other product is potassium chloride.) If 386 mL of oxygen at 41 C and 97.8 kPa is generated by this reaction, what is the minimum mass of KClO3used?arrow_forwardA person exhales about 5.8 102 L of carbon dioxide per day (at STP). The carbon dioxide exhaled by an astronaut is absorbed from the air of a space capsule by reaction with lithium hydroxide, LiOH. 2LiOH(s)+CO2(g)Li2CO3(s)+H2O(l) How many grams of lithium hydroxide are required per astronaut per day?arrow_forwardA mixture contained zinc sulfide, ZnS, and lead sulfide, PbS. A sample of the mixture weighing 6.12 g was reacted with an excess of hydrochloric acid. The reactions are ZnS(s)+2HCL(aq)ZnCl2(aq)+H2S(g)PbS(s)+2HCL(aq)PbCl2(aq)+H2S(g) If the sample reacted completely and produced 1.049 L of hydrogen sulfide, H2S, at 23C and 762 mmHg, what were the percentages of ZnS and PbS in the mixture?arrow_forward
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