EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
3rd Edition
ISBN: 8220102801585
Author: SMITH
Publisher: YUZU
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Chapter 13, Problem 13.104P
Interpretation Introduction

(a)

Interpretation:

Structure of the molecule B should be converted to a condensed structure and IUPAC name of the molecule should be given.

  EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 13, Problem 13.104P , additional homework tip  1

= ( C10H20 )

Concept Introduction:

Alkenes are hydrocarbon molecules that consist a carbon-carbon double bond which has the general formula of CnH2n .Structure of a chemical compound is the arrangement of atoms and bonds in the space.

In alkene nomenclature longest C chain will be considered as the parent/ main C chain. At the end of the alkane suffix -ene is added. Longest chain which includes the carbon-carbon double bond will considered as the main carbon chain. Numbering of the main C chain is starting from the first substituent by giving the lower number to that substituent and as well as the double bond should get the lower number. All the substituents should be numbered and named. Two or more identical substituents should be indicated by using appropriate prefixes as di-. Names of the substituents should be alphabetized. Each substituent should have a position number which is mentioned in the main C chain.

Expert Solution
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Answer to Problem 13.104P

Condensed structure -

  EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 13, Problem 13.104P , additional homework tip  2

IUPAC name −Decene

Explanation of Solution

In alkenes there is a carbon-carbon double bond and different groups are connected to the two carbons. In most of the alkenes; out of four binding positions of carbon-carbon double bond, two of them are binds with two hydrogen atoms and other two binding positions are binds with two different alkyl groups.In this molecule, carbon atoms are represented in black and hydrogen atoms are represented in white color.Structure of a chemical compound is the arrangement of atoms and bonds in the space.

Condensed structure -

  EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 13, Problem 13.104P , additional homework tip  3

In this molecule, main carbon chain which contains the carbon-carbon double bond is a ten membered chain and there are no substituents in this molecule. According to the numbering of the main chain double bond gets the lowest number and it is number 1.Hence, IUPAC name of the molecule is decene.

Interpretation Introduction

(b)

Interpretation:

The resulting product should be identified after reacting C10H20 with H2 in the presence of Pd.

Concept Introduction:

Alkenes are hydrocarbon molecules that consist a carbon-carbon double bond which has the general formula of CnH2n . Alkanes are hydrocarbon molecules which do not have any functional group.

Reaction of alkene with H2 in the presence of Pd will form saturated alkanes and the reaction is called as hydrogenation reaction.

Expert Solution
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Answer to Problem 13.104P

  CH3CH2CH2CH2CH2CH2CH2CH2CH2CH3

Explanation of Solution

Unsaturated ( C10H20 )alkene molecule react with H2 in the presence of Pd and form saturated alkanes. Bond between two H in the H2 , is broken and also a one bond between two carbon-carbon bond is broken, meanwhile new two bonds of CH are formed in the presence of Pd metallic catalyst, which reduce the activation energy of the reaction. Refer to the below reaction;

  CH2=CHCH2CH2CH2CH2CH2CH2CH2CH3                                    H2/PdCH3CH2CH2CH2CH2CH2CH2CH2CH2CH3

Interpretation Introduction

(c)

Interpretation:

The resulting product should be identified after reacting C10H20 with H2O and H2SO4.

Concept Introduction:

Alkenes are hydrocarbon molecules that consist a carbon-carbon double bond which has the general formula of CnH2n . Alcohols are the hydrocarbon molecules which contains OH group in the molecule.

Reaction of alkene with H2O and H2SO4 will form saturated alcohols and the reaction is called as hydration reaction.

Hydration reaction of alkenes follows the Markovnikov's rule.

Expert Solution
Check Mark

Answer to Problem 13.104P

  CH3CHOHCH2CH2CH2CH2CH2CH2CH2CH3

Explanation of Solution

Unsaturated ( C10H20 ) alkene molecule react with H2O and H2SO4 , form alcohols. One bond between a hydrogen atom and an oxygen atom in the H2O , is broken and also a one bond between two carbon-carbon bond is broken, meanwhile new two bonds of COH and CH are formed. Hydrogenation occurs only in the presence of a strong acid such as H2SO4 . Hydration reaction of alkenes follows the Markovnikov's rule. When addition of H2O molecule to an unsymmetrical alkene, H atom binds to the less substituted carbon atom is known as Markovnikov's rule. This molecule also falls into the unsymmetrical alkene category, hence; Markovnikov's rule is applied to this molecule.

Refer to the below reaction;

  CH2=CH(CH2)7CH3H2SO4/H2OCH3CHOH(CH2)7CH3

Interpretation Introduction

(d)

Interpretation:

The resulting polymer should be identified after polymerization of C10H20.

Concept Introduction:

Alkenes are hydrocarbon molecules that contain a carbon-carbon double bond inside a molecule.

Polymers are high molecular weight macromolecules which formed from covalently bonded monomer molecules.

Expert Solution
Check Mark

Answer to Problem 13.104P

  EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 13, Problem 13.104P , additional homework tip  4

Explanation of Solution

Polymers are high molecular weight macromolecules which formed from covalently bonded monomer molecules. When forming polymers from alkene monomers, the weak bond which is in the carbon-carbon double bond is broken and new strong bond will form to connect the monomer molecules together. Hence; weak bond of the carbon-carbon double bond of CH2=CH(CH2)7CH3 will break and new strong bond will form to create polydecane. 'n' number of monomers will together make polydecane polymer with 'n' number of decenemonomers. Refer to the below diagram;

  EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 13, Problem 13.104P , additional homework tip  5

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Chapter 13 Solutions

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM

Ch. 13.3 - Prob. 13.11PCh. 13.3 - Prob. 13.12PCh. 13.3 - Prob. 13.13PCh. 13.4 - Prob. 13.14PCh. 13.6 - Prob. 13.15PCh. 13.6 - Prob. 13.16PCh. 13.6 - Prob. 13.17PCh. 13.6 - Prob. 13.18PCh. 13.6 - Prob. 13.19PCh. 13.7 - Prob. 13.20PCh. 13.8 - Prob. 13.21PCh. 13.8 - Prob. 13.22PCh. 13.10 - Give the IUPAC name of each compound. Ch. 13.10 - Prob. 13.24PCh. 13.11 - Prob. 13.25PCh. 13.12 - Prob. 13.26PCh. 13.13 - Prob. 13.27PCh. 13.13 - Prob. 13.28PCh. 13 - Anethole, the major constituent of anise oil, is...Ch. 13 - Prob. 13.30PCh. 13 - What is the molecular formula for a hydrocarbon...Ch. 13 - Prob. 13.32PCh. 13 - Prob. 13.33PCh. 13 - Prob. 13.34PCh. 13 - Prob. 13.35PCh. 13 - Prob. 13.36PCh. 13 - Give the IUPAC name for each molecule depicted in...Ch. 13 - Give the IUPAC name for each molecule depicted in...Ch. 13 - Give the IUPAC name for each compound. a....Ch. 13 - Give the IUPAC name for each compound. d....Ch. 13 - Prob. 13.41PCh. 13 - Prob. 13.42PCh. 13 - Give the structure corresponding to each IUPAC...Ch. 13 - Prob. 13.44PCh. 13 - Each of the following IUPAC names is incorrect....Ch. 13 - Each of the following IUPAC names is incorrect....Ch. 13 - Prob. 13.47PCh. 13 - Prob. 13.48PCh. 13 - Prob. 13.49PCh. 13 - Label the carbon-carbon double bond as cis or...Ch. 13 - Prob. 13.51PCh. 13 - Prob. 13.52PCh. 13 - Prob. 13.53PCh. 13 - Prob. 13.54PCh. 13 - Prob. 13.55PCh. 13 - Prob. 13.56PCh. 13 - Prob. 13.57PCh. 13 - Prob. 13.58PCh. 13 - Prob. 13.59PCh. 13 - Prob. 13.60PCh. 13 - What alkyd halide is formed when each alkene is...Ch. 13 - Prob. 13.62PCh. 13 - Prob. 13.63PCh. 13 - Prob. 13.64PCh. 13 - What alkene is needed as a starting material to...Ch. 13 - Prob. 13.66PCh. 13 - Prob. 13.67PCh. 13 - Prob. 13.68PCh. 13 - Prob. 13.69PCh. 13 - Prob. 13.70PCh. 13 - Prob. 13.71PCh. 13 - Prob. 13.72PCh. 13 - Prob. 13.73PCh. 13 - Prob. 13.74PCh. 13 - Prob. 13.75PCh. 13 - Prob. 13.76PCh. 13 - Prob. 13.77PCh. 13 - Prob. 13.78PCh. 13 - Prob. 13.79PCh. 13 - Prob. 13.80PCh. 13 - Prob. 13.81PCh. 13 - Are o-bromochlorobenzene and m-bromochlorobenzene...Ch. 13 - Give the structure corresponding to each IUPAC...Ch. 13 - Give the structure corresponding to each IUPAC...Ch. 13 - Prob. 13.85PCh. 13 - Prob. 13.86PCh. 13 - Prob. 13.87PCh. 13 - Prob. 13.88PCh. 13 - Prob. 13.89PCh. 13 - Prob. 13.90PCh. 13 - Prob. 13.91PCh. 13 - Prob. 13.92PCh. 13 - Prob. 13.93PCh. 13 - Eleostearic acid is an unsaturated fatty acid...Ch. 13 - Prob. 13.95PCh. 13 - Prob. 13.96PCh. 13 - Prob. 13.97PCh. 13 - Prob. 13.98PCh. 13 - Prob. 13.99PCh. 13 - Prob. 13.100PCh. 13 - Prob. 13.101PCh. 13 - Prob. 13.102PCh. 13 - Answer the following questions about compound A,...Ch. 13 - Prob. 13.104PCh. 13 - Prob. 13.105PCh. 13 - Prob. 13.106PCh. 13 - Prob. 13.107CPCh. 13 - Prob. 13.108CP
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