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Concept explainers
(a)
Interpretation: The most stable radical that can result from cleavage of
Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as
(b)
Interpretation: The most stable radical that can result from cleavage of
Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as
(c)
Interpretation: The most stable radical that can result from cleavage of
Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as
(d)
Interpretation: The most stable radical that can result from cleavage of
Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as
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Chapter 13 Solutions
ORGANIC CHEMISTRY-ACCESS
- 1. Which among these can make a molecule nucleophilic? a.double bondsb.positive chargec. incomplete octet 2. Which among these can make a molecule electrophilic? a.Triple bondsb.positive chargec. radicalsarrow_forwardExamine the reactant and product for each reaction. Label each transformation as an addition, elimination, or substitution. Br А. Br ОН elimination addition С. substitution D. B.arrow_forwardChoose the correct product for each reaction. A. B. C. D. PPh3 H PPh3 || I ။arrow_forward
- Which of the following is not stable? a. ?H b. Li c. ®B d. 14N Aarrow_forward5. Consider the reaction below and answer the following questions + OH + H₂O a. Draw in ALL missing lone pair electrons as well as electron movement arrows on the reactant side Identify the nucleophile and electrophile on the reactant side b. c. Identify which side of the equilibrium will dominate. d. Draw resonance structures for the organic compound on the product side CHEM 241-Group05. Ormord d ****arrow_forwardComplete the fourth resonance structure to determine which bond is shortest? Which compound will react fourth fastest with B-eBr ? d. e. F 14. Complete the fourth resonance structure to determine which bond is shortest? 15. Which compound will react fourth fastest with Br₂/FeBr3? a. b. d. -OH b darrow_forward
- Which B carbon in the molecule below would be used to form the Zaitsev product? Br a. A b.B C. C d. D e. E O f. F ajarrow_forwardH₂C CH₂ 2 c CH₂ 1. Reaction A is a radical process. The part of the mechanism that is represented above is called [blank1] would immediately follow [blank2] A. a. nucleophilic attack; hydrogen abstraction b. homolytic attack; hydrogen abstraction c. hydrogen abstraction; homolytic cleavage d. nucleophilic attack; homolytic cleavage 2. Radical mechanisms begins by which of the following events: a) homolytic cleavage b) heterolytic cleavage c) extreme heating or exposure to light irradiation. d) nucleophilic attack 3. Rank the following radicals from most stable to least stable: CH H₂C A CH₂ a) D > C>A>B b) B>D>A>C c) D> B>A>C d) C>A>B>D H₂C B CH₂ H₂C" CH₂ C CH3 H₂C CH D CH₂arrow_forwardConsider this step in a radical reaction: Br Br: ?arrow_forward
- a. 5. Draw the product(s) of each addition reaction b. d. دھ HBr H2SO4, H₂O Bra, H2O a. 9-BBN b. H2O2, NaOHarrow_forward1. Products A and B combine to make up over 90% of the product mixture. H-CI CI В D ČI A a. For each of the structure A-D, attach an H atom to the carbon that in fact added an H b. Classify each of the four structures as either a 1,2 or 1,4 addition product c. Draw the resonance structures for the cation that leads to both product A+B, and also draw the resonance structure for the cation that leads to both product C+D. d. Draw the mechanism for the formation of products A and B above.arrow_forwardA 16. Provide a structure for compounds A, B, and C. C? Br9 Br ,H 1. XS LDA 1. NaH H20 В. 2. H30* А. 2. С. Br TFOH, CF3CH2OH Br 出ぐだ B.arrow_forward
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