Modified Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: An Introduction to General, Organic, and Biological Chemistry (13th Edition)
13th Edition
ISBN: 9780134562254
Author: Karen C Timberlake
Publisher: PEARSON
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Textbook Question
Chapter 13.2, Problem 13.19PP
Identify the chiral carbon in each of the following compounds:
a. citronellol; one enantiomer has the odor of geranium
b. alanine,an amino acid
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Construct the two enantiomeric forms/structure of the following monosaccharides and designate
the handedness of each using D, L system:
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b. Psicose
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Crocin, which occurs naturally in crocus and gardenia owers, is primarily responsible for the color of saffron. (a) What lipid and monosaccharides are formed by the hydrolysis of crocin? (b) Classify the lipid as a monoterpenoid, diperpenoid, etc., and locate the isoprene units.
Raffinose, with the structure below, is a trisaccharide commonly found in peas, beans, and some other vegetables. Identify all anomeric carbons.
Chapter 13 Solutions
Modified Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: An Introduction to General, Organic, and Biological Chemistry (13th Edition)
Ch. 13.1 - Prob. 13.1PPCh. 13.1 - Prob. 13.2PPCh. 13.1 - Prob. 13.3PPCh. 13.1 - Prob. 13.4PPCh. 13.1 - Prob. 13.5PPCh. 13.1 - Prob. 13.6PPCh. 13.1 - Prob. 13.7PPCh. 13.1 - Prob. 13.8PPCh. 13.1 - Prob. 13.9PPCh. 13.1 - Prob. 13.10PP
Ch. 13.2 - Prob. 13.11PPCh. 13.2 - Prob. 13.12PPCh. 13.2 - Prob. 13.13PPCh. 13.2 - Prob. 13.14PPCh. 13.2 - Prob. 13.15PPCh. 13.2 - Prob. 13.16PPCh. 13.2 - Identify each of the following as D or L: a. b. c.Ch. 13.2 - Identify each of the following as D or L: a. b. c.Ch. 13.2 - Identify the chiral carbon in each of the...Ch. 13.2 - Prob. 13.20PPCh. 13.3 - Prob. 13.21PPCh. 13.3 - Prob. 13.22PPCh. 13.3 - Prob. 13.23PPCh. 13.3 - Prob. 13.24PPCh. 13.3 - Prob. 13.25PPCh. 13.3 - Prob. 13.26PPCh. 13.3 - Prob. 13.27PPCh. 13.3 - Prob. 13.28PPCh. 13.3 - Prob. 13.29PPCh. 13.3 - Prob. 13.30PPCh. 13.4 - What are the kind and number of atoms in the ring...Ch. 13.4 - What are the kind and number of atoms in the ring...Ch. 13.4 - Prob. 13.33PPCh. 13.4 - Prob. 13.34PPCh. 13.4 - Prob. 13.35PPCh. 13.4 - Identify each of the following as the a or ß...Ch. 13.5 - Prob. 13.37PPCh. 13.5 - Prob. 13.38PPCh. 13.5 - Prob. 13.39PPCh. 13.5 - Prob. 13.40PPCh. 13.6 - Prob. 13.41PPCh. 13.6 - Prob. 13.42PPCh. 13.6 - Prob. 13.43PPCh. 13.6 - Prob. 13.44PPCh. 13.6 - Prob. 13.45PPCh. 13.6 - Prob. 13.46PPCh. 13.7 - Describe the similarities and differences in the...Ch. 13.7 - Prob. 13.48PPCh. 13.7 - Prob. 13.49PPCh. 13.7 - Prob. 13.50PPCh. 13.7 - Prob. 13.51PPCh. 13.7 - Prob. 13.52PPCh. 13.7 - Prob. 13.53PPCh. 13.7 - Prob. 13.54PPCh. 13 - Prob. 13.55UTCCh. 13 - Prob. 13.56UTCCh. 13 - Prob. 13.57UTCCh. 13 - Prob. 13.58UTCCh. 13 - Prob. 13.59UTCCh. 13 - Prob. 13.60UTCCh. 13 - Prob. 13.61APPCh. 13 - Prob. 13.62APPCh. 13 - Prob. 13.63APPCh. 13 - Prob. 13.64APPCh. 13 - Prob. 13.65APPCh. 13 - Prob. 13.66APPCh. 13 - Prob. 13.67APPCh. 13 - Prob. 13.68APPCh. 13 - Prob. 13.69APPCh. 13 - Prob. 13.70APPCh. 13 - Prob. 13.71APPCh. 13 - Prob. 13.72APPCh. 13 - Prob. 13.73APPCh. 13 - Prob. 13.74APPCh. 13 - Prob. 13.75CPCh. 13 - Prob. 13.76CPCh. 13 - 13.77 Gentiobiose is found in saffron. (13.4,...Ch. 13 - Prob. 13.78CP
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- The following trisaccharide derivative is important to human health.What ever the A ring is called, it is linked to the B ring as ?-O-(A Ringyl)-B ringly-C ring?arrow_forwardCellobiose, a disaccharide obtained by the hydrolysis of cellulose, is composed of two glucose units joined together in a 1->4-ß-glycoside bond. What is the structure of cellobiose?arrow_forwarda) Draw Haworth projections of both - and -anomers of D-fructose. Indicate which carbon is the anomeric carbon.b) Sucrose is a disaccharide made up of a molecule of D-fructose and D-glucose. Draw the structure of sucrose clearly indicating the linkage between the two monosaccharides and its biological significance.c) Tollen’s reagent is a very mild oxidizing agent which normally oxidize aldehydes but not ketones. However, both glucose and fructose give positive results with Tollen’s reagent and are classified as reducing sugars. Explain how fructose can also give positive results with Tollen’s reagent (illustrate using structures).arrow_forward
- Crocin, which occurs naturally in crocus and gardenia flowers, is primarily responsible for the color of saffron. (a) What lipid and monosaccharides are formed by the hydrolysis of crocin? (b) Classify the lipid as a monoterpenoid, diperpenoid, etc., and locate the isoprene units.arrow_forwardusing the picture as a reference do the following: a.) draw the Haworth projection of β-D-Mannose b.) draw the disaccharide formed from two β-D-Mannose molecules with a β-1 → 4 glycosidic bondarrow_forward>Lactose is a disaccharide of glucose and galactose. Draw the structure of lactose.arrow_forward
- The anticoagulant heparin is a polysaccharide that contains alternating residues of -D- glucuronic acid-6- sulfate and N-sulfo-D-glucosamine-6sulfate connected by (1 B 4)- glycosidic linkages. Draw a part of heparin that shows one each of the two residues.arrow_forwardA. Assign each chiral center as R or S B. draw a diastereomer of ephedrine.arrow_forward(A) Identify the glycosidic bond in the following disaccharide (B) Decide whether the compound is a non reducing or reducing sugar (C) Polysaccharide units are usually bonded together with alpha or beta 1,6 or 1,4 linkages. What linkage is used in the disaccharide shown below?arrow_forward
- 2 Draw the structure of a disaccharide made up of two D-glucose units. The glycosidic bond is α-1,6-glycosidic bond.arrow_forwardSpongothymidine is an N-glycoside isolated from Tectitethya crypta, a shallow-water Caribbean sponge. Identify the base and monosaccharide that compose spongothymidine, and draw the structure of the monosaccharide using a Fischer projection formula.arrow_forwardConsider the tetrasaccharide stachyose drawn below. Stachyose is found in white jasmine, soybeans, and lentils. Because humans cannot digest it, its consumption causes flatulence.a. Label all glycoside bonds.b. Classify each glycosidic linkage as αα or ββ and use numbers to designate its location between two rings (e.g., 1→→4-ββ)-c. What products are formed when stachyose is hydrolyzed with H33O++?d. Is stachyose a reducing sugar?e. What product is formed when stachyose is treated with excess CH33I, Ag22O?f. What products are formed when the product in (e) is treated with H33O++?arrow_forward
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