EBK ORGANIC CHEMISTRY
EBK ORGANIC CHEMISTRY
6th Edition
ISBN: 9781260475685
Author: SMITH
Publisher: MCGRAW-HILL HIGHER EDUCATION
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Chapter 13.3, Problem 5P
Interpretation Introduction

Interpretation: The structures of A and B is to be determined.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from CH sigma bond of the alkane.

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Compounds A and B are isomers having molecular formula C5H12. Heating A with Cl2 gives a single product of monohalogenation, whereas heating B under the same conditions forms three constitutional isomers. What are thestructures of A and B?
5) Compound A reacted with Mg in ether to give B. Compound B is with Ethyl bromide to give Ethyl cyclohexane. What are the structures of A and B?
Compound L undergoes dehydrohalogenation to form hydrogen bromide and 1-methylcyclohexene. What is dehydrohalogenation? State the condition required for dehydrohalogenation. Draw the structural formula of compound L and name L.
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