Explanation The reaction steps involved in the formation of hydrogen iodide are as follows. The fast step is reversible and represented as follows: I 2 ⇌ k − 1 k 1 2 I The rate of formation of the intermediate I can be expressed as follows: dI d t = 2 k 1 [ I 2 ] (1) The rate of deformation of I can be expressed as follows: − dI d t = k − 1 [ I ] 2 (2) The second step is also fast and represented as follows: I+H 2 ⇌ k − 2 k 2 H 2 I The rate of formation of H 2 I can be calculated as follows: d [ H 2 I ] d t = k 2 [ I ] [ H 2 ] (3) The rate of deformation of H 2 I can be calculated as follows: − d [ H 2 I ] d t = k − 2 [ H 2 I ] (4) The slow step is the rate-determining step and represented as follows: H 2 I+I → k 3 2HI The rate of formation of HI can be expressed as follows: 1 2 d [ HI ] d t = k 3 [ I ] [ H 2 ] (5) Steady-state approximation (SSA) is defined as the rate of formation is equal to the rate of deformation for any compound. Apply steady-state approximation and equate right-hand expression of equations (1) and (2) as follows: k − 1 [ I ] 2 = 2 k 1 [ I 2 ] or [ I ] = 2 k 1 k − 1 [ I 2 ] Apply steady-state approximation and equate right-hand expression of equations (3) and (4) as follows: k 2 [ I ] [ H 2 ] = k − 2 [ H 2 I ] or [ H 2 I ] = k 2 k − 2 [ I ] [ H 2 ] Substitute

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Question

Chapter 14, Problem 108E

Interpretation Introduction

To determine: The rate law for the formation of hydrogen iodide.

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Chapter 14, Problem 107E

Chapter 14, Problem 109E

Chapter 14 Solutions

CHEMISTRY:A MOLECULAR APPROACH (LL) W/

Ch. 14 - Prob. 1SAQ Ch. 14 - Q2. Dinitrogen monoxide decomposes into nitrogen...Ch. 14 - Q3. This plot shows the rate of the decomposition...Ch. 14 - Q4. For the reaction 2 A + B → C, the initial rate...Ch. 14 - Prob. 5SAQ Ch. 14 - Prob. 6SAQ Ch. 14 - Prob. 7SAQ Ch. 14 - Prob. 8SAQ Ch. 14 - Q9. The rate constant of a reaction is measured at...Ch. 14 - Prob. 10SAQ

Ch. 14 - Prob. 11SAQ Ch. 14 - Q12. Which statement is true regarding the...Ch. 14 - Prob. 13SAQ Ch. 14 - Q14. Use collision theory to determine which...Ch. 14 - Q15. Carbon monoxide and chlorine gas react to...Ch. 14 - Prob. 1E Ch. 14 - Prob. 2E Ch. 14 - Prob. 3E Ch. 14 - 4. Why is the reaction rate for reactants defined...Ch. 14 - Prob. 5E Ch. 14 - Prob. 6E Ch. 14 - Prob. 7E Ch. 14 - 8. For a reaction with multiple reactants, how is...Ch. 14 - 9. Explain the difference between the rate law for...Ch. 14 - 10. Write integrated rate laws for zero-order,...Ch. 14 - Prob. 11E Ch. 14 - 12. How do reaction rates typically depend on...Ch. 14 - Prob. 13E Ch. 14 - 14. What is an Arrhenius plot? Explain the...Ch. 14 - Prob. 15E Ch. 14 - Prob. 16E Ch. 14 - 17. In a reaction mechanism, what is an elementary...Ch. 14 - 18. What are the two requirements for a proposed...Ch. 14 - 19. What is an intermediate within a reaction...Ch. 14 - Prob. 20E Ch. 14 - 21. Explain the difference between homogeneous...Ch. 14 - Prob. 22E Ch. 14 - Prob. 23E Ch. 14 - Prob. 24E Ch. 14 - 25. Consider the reaction: 2 HBr(g) → H2(g) +...Ch. 14 - 26. Consider the reaction: 2 N2O(g) → 2 N2(g) +...Ch. 14 - 27. For the reaction 2 A(g) + B(g) → 3 C(g), a....Ch. 14 - 28. For the reaction A(g) + B(g) → 2 C(g), a....Ch. 14 - 29. Consider the reaction: Cl2(g) + 3 F2(g) → 2...Ch. 14 - Prob. 30E Ch. 14 - Prob. 31E Ch. 14 - Prob. 32E Ch. 14 - Prob. 33E Ch. 14 - 34. Consider the reaction: 2 H2O2(aq) → 2 H2O(l) +...Ch. 14 - Prob. 35E Ch. 14 - Prob. 36E Ch. 14 - Prob. 37E Ch. 14 - 38. This reaction is first order in N2O5: N2O5(g)...Ch. 14 - Prob. 39E Ch. 14 - Prob. 40E Ch. 14 - Prob. 41E Ch. 14 - 42. Consider the data showing the initial rate of...Ch. 14 - Prob. 43E Ch. 14 - Prob. 44E Ch. 14 - 45. The tabulated data were collected for this...Ch. 14 - 46. The tabulated data were collected for this...Ch. 14 - 47. Indicate the order of reaction consistent with...Ch. 14 - 48. Indicate the order of reaction consistent with...Ch. 14 - 49. The tabulated data show the concentration of...Ch. 14 - Prob. 50E Ch. 14 - 51. The tabulated data show the concentration of...Ch. 14 - 52. The reaction A → products was monitored as a...Ch. 14 - Prob. 53E Ch. 14 - Prob. 54E Ch. 14 - Prob. 55E Ch. 14 - Prob. 56E Ch. 14 - 57. The half-life for the radioactive decay of...Ch. 14 - 58. The half-life for the radioactive decay of...Ch. 14 - Prob. 59E Ch. 14 - Prob. 60E Ch. 14 - Prob. 61E Ch. 14 - Prob. 62E Ch. 14 - Prob. 63E Ch. 14 - Prob. 64E Ch. 14 - 65. The data shown here were collected for the...Ch. 14 - Prob. 66E Ch. 14 - 67. The tabulated data were collected for the...Ch. 14 - 68. The tabulated data show the rate constant of a...Ch. 14 - 69. A reaction has a rate constant of 0.0117/s at...Ch. 14 - 70. A reaction has a rate constant of 0.000122/s...Ch. 14 - Prob. 71E Ch. 14 - Prob. 72E Ch. 14 - Prob. 73E Ch. 14 - Prob. 74E Ch. 14 - Prob. 75E Ch. 14 - Prob. 76E Ch. 14 - Prob. 77E Ch. 14 - Prob. 78E Ch. 14 - 79. Many heterogeneous catalysts are deposited on...Ch. 14 - 80. Suppose that the reaction A → products is...Ch. 14 - 81. Suppose that a catalyst lowers the activation...Ch. 14 - Prob. 82E Ch. 14 - Prob. 83E Ch. 14 - Prob. 84E Ch. 14 - Prob. 85E Ch. 14 - Prob. 86E Ch. 14 - Prob. 87E Ch. 14 - Prob. 88E Ch. 14 - Prob. 89E Ch. 14 - Prob. 90E Ch. 14 - 91. Iodine atoms combine to form I2 in liquid...Ch. 14 - 92. The hydrolysis of sucrose (C12H22O11) into...Ch. 14 - Prob. 93E Ch. 14 - Prob. 94E Ch. 14 - Prob. 95E Ch. 14 - Prob. 96E Ch. 14 - 97. The desorption (leaving of the surface) of a...Ch. 14 - Prob. 98E Ch. 14 - 99. The kinetics of this reaction were studied as...Ch. 14 - Prob. 100E Ch. 14 - Prob. 101E Ch. 14 - 102. Consider the two reactions: a. Why is the...Ch. 14 - 103. Anthropologists can estimate the age of a...Ch. 14 - 104. Geologists can estimate the age of rocks by...Ch. 14 - Prob. 105E Ch. 14 - 106. Consider the reaction: 2 NH3(aq) + OCl–(aq) →...Ch. 14 - Prob. 107E Ch. 14 - Prob. 108E Ch. 14 - Prob. 109E Ch. 14 - Prob. 110E Ch. 14 - Prob. 111E Ch. 14 - Prob. 112E Ch. 14 - 113. In this chapter we have seen a number of...Ch. 14 - Prob. 114E Ch. 14 - 115. The previous exercise shows how the...Ch. 14 - Prob. 116E Ch. 14 - Prob. 117E Ch. 14 - Prob. 118E Ch. 14 - Prob. 119E Ch. 14 - Prob. 120E Ch. 14 - Prob. 121E Ch. 14 - Prob. 122E Ch. 14 - Prob. 123QGW Ch. 14 - 124. A certain compound, A, reacts to form...Ch. 14 - 125. The color of food is an important component...

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