Chapter 14, Problem 14.43P

Interpretation Introduction

Interpretation:

The molar bond enthalpy of $\text{O}=\text{O}$ double bond in ${\text{O}}_2$ molecule has to be determined.

Concept Introduction:

Thermodynamics is a study of energy transfers that can be done by either heat or work. The energy transferred through work involves force. When work is positive then system gains energy while when work is negative then system loses energy. Heat is not a state function and therefore change in enthalpy of reaction $\left(\Delta H{°}_{\text{rxn}}\right)$ has been introduced. The expression to calculate $\Delta H{°}_{\text{rxn}}$ is as follows:

  $\Delta H_{\text{rxn}}=H_{\text{prod}}-H_{\text{react}}$

The useful property of $\Delta H{°}_{\text{rxn}}$ is that it is an additive property.

The enthalpy of reaction can also be calculated by use of molar bond enthalpies. The standard enthalpy of reaction is given as follows:

  $\Delta H{°}_{\text{rxn}}=H_{\text{bond}}\left[\text{reactants}\right]–H_{\text{bond}}\left[\text{products}\right]$