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The zinc-silver oxide battery, although expensive, is used to power satellite systems because of its light weight. Unbalanced half-reactions that occur in this battery are
Which equation represents the oxidation half-reaction? Which represents the reduction half-reaction? Add electrons to the appropriate side of each equation to account for the chance in oxidation number.
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- 1. If you wish to convert 0.0100 mol of Au3+ (aq) ions into Au(s) in a “gold-plating” process, how long must you electrolyze a solution if the current passing through the circuit is 2.00 amps? 483 seconds 4.83 104 seconds 965 seconds 1450 secondsarrow_forwardDraw a diagram of each cell. Label the anode, the cathode, the species in each half-cell solution, the direction of electron movement in an external circuit, and thedirection of movement of ions within the cell. (a) Cu(s) | Cu2+(aq) || Fe2+(aq) |Fe(s) (b) Pt(s) | H2O2(aq), H+(aq) || Fe2+(aq), Fe3+(aq) | Pt(s)arrow_forwardConsider the following cell running under standard conditions: Fe(s)Fe2+(aq)Al3+(aq)Al(s) a Is this a voltaic cell? b Which species is being reduced during the chemical reaction? c Which species is the oxidizing agent? d What happens to the concentration of Fe3+(aq) as the reaction proceeds? e How does the mass of Al(s) change as the reaction proceeds?arrow_forward
- An electrolytic cell is set up with Cd(s) in Cd(NO3)2(aq) and Zn(s) in Zn(NO3)2(aq). Initially both electrodesweigh 5.00 g. After running the cell for several hours theelectrode in the left compartment weighs 4.75 g. (a) Which electrode is in the left compartment? (b) Does the mass of the electrode in the right compartmentincrease, decrease, or stay the same? If the masschanges, what is the new mass? (c) Does the volume of the electrode in the right compartment increase, decrease, or stay the same? If the volumechanges, what is the new volume? (The density of Cd is8.65 g/cm3.)arrow_forwardFor the reaction Cu2+(aq) + Zn(s) → Cu(s) + Zn2+ (aq), why can’t you generate electric current by placing a piece of copper metal and a piece of zinc metal in a solution containing CuCl2(aq) and ZnCl2(aq)?arrow_forwardA voltaic cell is constructed in which one half-cell consists of a silver wire in an aqueous solution of AgNO3.The other half cell consists of an inert platinum wire in an aqueous solution containing Fe2+(aq) and Fe3+(aq). (a) Calculate the cell potential, assuming standard conditions. (b) Write the net ionic equation for the reaction occurring in the cell. (c) Which electrode is the anode and which is the cathode? (d) If [Ag+] is 0.10 M, and [Fe2+] and [Fe3+] are both 1.0 M, what is the cell potential? Is the net cell reaction still that used in part (a)? If not, what is the net reaction under the new conditions?arrow_forward
- What is the standard cell potential you would obtain from a cell at 25C using an electrode in which Hg22+(aq) is in contact with mercury metal and an electrode in which an aluminum strip dips into a solution of Al3+(aq)?arrow_forwardThe voltaic cell is represented as Zn(s)Zn2+(1.0M)Cu2+(1.0M)Cu(s) Which of the following statements is not true of this cell? a The mass of the zinc electrode, Zn(s), decreases as the cell runs. b The copper electrode is the anode. c Electrons flow through the external circuit from the zinc electrode to the copper electrode. d Reduction occurs at the copper electrode as the cell runs. e The concentration of Cu2+ decreases as the cell runs.arrow_forwardUse Table 17.1 to arrange the following oxidizing agents in order of increasing strength: Mn2+ S Co3+ Cl2 K+arrow_forward
- Consider these half-reactions: (a) Which is the weakest oxidizing agent? (b) Which is the strongest oxidizing agent? (c) Which is the strongest reducing agent? (d) Which is the weakest reducing agent? (e) Will Sn(s) reduce Ag+(aq) to Ag(s)? (f) Will Hg() reduce Sn2+(aq) to Sn(s)? (g) Name the ions that can be reduced by Sn(s). (h) Which metals can be oxidized by Ag+(aq)?arrow_forwardA voltaic cell is constructed using the reaction of chromium metal and iron(II) ions. 2 Cr(s) + 3 Fe2+(aq) 2 Cr3+(aq) + 3 Fe(s) Complete the following sentences: Electrons in the external circuit flow from the ________ electrode to the ______ electrode. Negative ions move in the salt bridge from the ________ half-cell to the ______ half-cell. The half-reaction at the anode is _______ and that at the cathode is ________.arrow_forwardSome metals, such as thallium, can be oxidized to more than one oxidation state. Obtain the balanced net ionic equations for the following oxidation reduction reactions, in which nitric acid is reduced to nitric oxide, NO. a Oxidation of thallium metal to thallium(I) ion by nitric acid. b Oxidation of thallium(I) ion to thallium(III) ion by nitric acid. c Oxidation of thallium metal to thallium(III) by nitric acid. [Consider adding the a and b equations.]arrow_forward
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