The reason for the appearance of the signal in the latter given compound (2) at a lower wave number of absorption has to be explained. Concept introduction: IR spectral studies: It is a spectroscopic technique which is used to determine the functional groups present in the given compound sample by absorbing frequency in particular range with respect to the group present in the given sample. In the process of oxidation, primary alcohols get converted to aldehydes or acids whereas secondary alcohols get converted to ketones. Hydrogen bonding: The attractive force that holds two polar molecules (containing Hydrogen and highly electronegative atom, such as N, O, or F) is called as hydrogen boding. This is also called as intermolecular hydrogen bonding. The hydrogen bonding takes place within a molecule is called as intramolecular hydrogen bonding.

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Answer 1

Question

Chapter 14, Problem 79CP

(a)

Interpretation Introduction

Interpretation:

The reason for the appearance of the signal in the latter given compound (2) at a lower wave number of absorption has to be explained.

Concept introduction:

IR spectral studies: It is a spectroscopic technique which is used to determine the functional groups present in the given compound sample by absorbing frequency in particular range with respect to the group present in the given sample.

In the process of oxidation, primary alcohols get converted to aldehydes or acids whereas secondary alcohols get converted to ketones.

Hydrogen bonding: The attractive force that holds two polar molecules (containing Hydrogen and highly electronegative atom, such as N, O, or F) is called as hydrogen boding. This is also called as intermolecular hydrogen bonding.

The hydrogen bonding takes place within a molecule is called as intramolecular hydrogen bonding.

(b)

Interpretation Introduction

Interpretation:

The broader signal that can be expected in the given compounds has to be identified and explained.

Concept introduction:

IR spectral studies: It is a spectroscopic technique which is used to determine the functional groups present in the given compound sample by absorbing frequency in particular range with respect to the group present in the given sample.

In the process of oxidation, primary alcohols get converted to aldehydes or acids whereas secondary alcohols get converted to ketones.

Hydrogen bonding: The attractive force that holds two polar molecules (containing Hydrogen and highly electronegative atom, such as N, O, or F) is called as hydrogen boding. This is also called as intermolecular hydrogen bonding.

The hydrogen bonding takes place within a molecule is called as intramolecular hydrogen bonding.

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Answer 2

Question

Chapter 14, Problem 79CP

(a)

Interpretation Introduction

Interpretation:

The reason for the appearance of the signal in the latter given compound (2) at a lower wave number of absorption has to be explained.

Concept introduction:

IR spectral studies: It is a spectroscopic technique which is used to determine the functional groups present in the given compound sample by absorbing frequency in particular range with respect to the group present in the given sample.

In the process of oxidation, primary alcohols get converted to aldehydes or acids whereas secondary alcohols get converted to ketones.

Hydrogen bonding: The attractive force that holds two polar molecules (containing Hydrogen and highly electronegative atom, such as N, O, or F) is called as hydrogen boding. This is also called as intermolecular hydrogen bonding.

The hydrogen bonding takes place within a molecule is called as intramolecular hydrogen bonding.

(b)

Interpretation Introduction

Interpretation:

The broader signal that can be expected in the given compounds has to be identified and explained.

Concept introduction:

IR spectral studies: It is a spectroscopic technique which is used to determine the functional groups present in the given compound sample by absorbing frequency in particular range with respect to the group present in the given sample.

In the process of oxidation, primary alcohols get converted to aldehydes or acids whereas secondary alcohols get converted to ketones.

Hydrogen bonding: The attractive force that holds two polar molecules (containing Hydrogen and highly electronegative atom, such as N, O, or F) is called as hydrogen boding. This is also called as intermolecular hydrogen bonding.

The hydrogen bonding takes place within a molecule is called as intramolecular hydrogen bonding.

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Answer 3

Question

Chapter 14, Problem 79CP

(a)

Interpretation Introduction

Interpretation:

The reason for the appearance of the signal in the latter given compound (2) at a lower wave number of absorption has to be explained.

Concept introduction:

IR spectral studies: It is a spectroscopic technique which is used to determine the functional groups present in the given compound sample by absorbing frequency in particular range with respect to the group present in the given sample.

In the process of oxidation, primary alcohols get converted to aldehydes or acids whereas secondary alcohols get converted to ketones.

Hydrogen bonding: The attractive force that holds two polar molecules (containing Hydrogen and highly electronegative atom, such as N, O, or F) is called as hydrogen boding. This is also called as intermolecular hydrogen bonding.

The hydrogen bonding takes place within a molecule is called as intramolecular hydrogen bonding.

(b)

Interpretation Introduction

Interpretation:

The broader signal that can be expected in the given compounds has to be identified and explained.

Concept introduction:

IR spectral studies: It is a spectroscopic technique which is used to determine the functional groups present in the given compound sample by absorbing frequency in particular range with respect to the group present in the given sample.

In the process of oxidation, primary alcohols get converted to aldehydes or acids whereas secondary alcohols get converted to ketones.

Hydrogen bonding: The attractive force that holds two polar molecules (containing Hydrogen and highly electronegative atom, such as N, O, or F) is called as hydrogen boding. This is also called as intermolecular hydrogen bonding.

The hydrogen bonding takes place within a molecule is called as intramolecular hydrogen bonding.

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Answer 4

Question

Chapter 14, Problem 79CP

(a)

Interpretation Introduction

Interpretation:

The reason for the appearance of the signal in the latter given compound (2) at a lower wave number of absorption has to be explained.

Concept introduction:

IR spectral studies: It is a spectroscopic technique which is used to determine the functional groups present in the given compound sample by absorbing frequency in particular range with respect to the group present in the given sample.

In the process of oxidation, primary alcohols get converted to aldehydes or acids whereas secondary alcohols get converted to ketones.

Hydrogen bonding: The attractive force that holds two polar molecules (containing Hydrogen and highly electronegative atom, such as N, O, or F) is called as hydrogen boding. This is also called as intermolecular hydrogen bonding.

The hydrogen bonding takes place within a molecule is called as intramolecular hydrogen bonding.

(b)

Interpretation Introduction

Interpretation:

The broader signal that can be expected in the given compounds has to be identified and explained.

Concept introduction:

IR spectral studies: It is a spectroscopic technique which is used to determine the functional groups present in the given compound sample by absorbing frequency in particular range with respect to the group present in the given sample.

In the process of oxidation, primary alcohols get converted to aldehydes or acids whereas secondary alcohols get converted to ketones.

Hydrogen bonding: The attractive force that holds two polar molecules (containing Hydrogen and highly electronegative atom, such as N, O, or F) is called as hydrogen boding. This is also called as intermolecular hydrogen bonding.

The hydrogen bonding takes place within a molecule is called as intramolecular hydrogen bonding.

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Answer 5

Chapter 14, Problem 79CP

(a)

Interpretation Introduction

Interpretation:

The reason for the appearance of the signal in the latter given compound (2) at a lower wave number of absorption has to be explained.

Concept introduction:

IR spectral studies: It is a spectroscopic technique which is used to determine the functional groups present in the given compound sample by absorbing frequency in particular range with respect to the group present in the given sample.

In the process of oxidation, primary alcohols get converted to aldehydes or acids whereas secondary alcohols get converted to ketones.

Hydrogen bonding: The attractive force that holds two polar molecules (containing Hydrogen and highly electronegative atom, such as N, O, or F) is called as hydrogen boding. This is also called as intermolecular hydrogen bonding.

The hydrogen bonding takes place within a molecule is called as intramolecular hydrogen bonding.

(b)

Interpretation Introduction

Interpretation:

The broader signal that can be expected in the given compounds has to be identified and explained.

Concept introduction:

IR spectral studies: It is a spectroscopic technique which is used to determine the functional groups present in the given compound sample by absorbing frequency in particular range with respect to the group present in the given sample.

In the process of oxidation, primary alcohols get converted to aldehydes or acids whereas secondary alcohols get converted to ketones.

Hydrogen bonding: The attractive force that holds two polar molecules (containing Hydrogen and highly electronegative atom, such as N, O, or F) is called as hydrogen boding. This is also called as intermolecular hydrogen bonding.

The hydrogen bonding takes place within a molecule is called as intramolecular hydrogen bonding.

Answer 6

Chapter 14, Problem 79CP

(a)

Interpretation Introduction

Interpretation:

The reason for the appearance of the signal in the latter given compound (2) at a lower wave number of absorption has to be explained.

Concept introduction:

IR spectral studies: It is a spectroscopic technique which is used to determine the functional groups present in the given compound sample by absorbing frequency in particular range with respect to the group present in the given sample.

In the process of oxidation, primary alcohols get converted to aldehydes or acids whereas secondary alcohols get converted to ketones.

Hydrogen bonding: The attractive force that holds two polar molecules (containing Hydrogen and highly electronegative atom, such as N, O, or F) is called as hydrogen boding. This is also called as intermolecular hydrogen bonding.

The hydrogen bonding takes place within a molecule is called as intramolecular hydrogen bonding.

Answer 7

Chapter 14, Problem 79CP

(a)

Interpretation Introduction

Interpretation:

The reason for the appearance of the signal in the latter given compound (2) at a lower wave number of absorption has to be explained.

Concept introduction:

IR spectral studies: It is a spectroscopic technique which is used to determine the functional groups present in the given compound sample by absorbing frequency in particular range with respect to the group present in the given sample.

In the process of oxidation, primary alcohols get converted to aldehydes or acids whereas secondary alcohols get converted to ketones.

Hydrogen bonding: The attractive force that holds two polar molecules (containing Hydrogen and highly electronegative atom, such as N, O, or F) is called as hydrogen boding. This is also called as intermolecular hydrogen bonding.

The hydrogen bonding takes place within a molecule is called as intramolecular hydrogen bonding.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The broader signal that can be expected in the given compounds has to be identified and explained.

Concept introduction:

IR spectral studies: It is a spectroscopic technique which is used to determine the functional groups present in the given compound sample by absorbing frequency in particular range with respect to the group present in the given sample.

In the process of oxidation, primary alcohols get converted to aldehydes or acids whereas secondary alcohols get converted to ketones.

Hydrogen bonding: The attractive force that holds two polar molecules (containing Hydrogen and highly electronegative atom, such as N, O, or F) is called as hydrogen boding. This is also called as intermolecular hydrogen bonding.

The hydrogen bonding takes place within a molecule is called as intramolecular hydrogen bonding.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The broader signal that can be expected in the given compounds has to be identified and explained.

Concept introduction:

IR spectral studies: It is a spectroscopic technique which is used to determine the functional groups present in the given compound sample by absorbing frequency in particular range with respect to the group present in the given sample.

In the process of oxidation, primary alcohols get converted to aldehydes or acids whereas secondary alcohols get converted to ketones.

Hydrogen bonding: The attractive force that holds two polar molecules (containing Hydrogen and highly electronegative atom, such as N, O, or F) is called as hydrogen boding. This is also called as intermolecular hydrogen bonding.

The hydrogen bonding takes place within a molecule is called as intramolecular hydrogen bonding.

Answer 10

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Answer 11

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Answer 13

Ch. 14.3 - Prob. 1CC Ch. 14.3 - Prob. 2CC Ch. 14.3 - Prob. 3CC Ch. 14.3 - Prob. 4CC Ch. 14.4 - Prob. 5CC Ch. 14.4 - Prob. 6CC Ch. 14.4 - Prob. 7CC Ch. 14.5 - Prob. 8CC Ch. 14.5 - Prob. 9CC Ch. 14.5 - Prob. 10CC

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