(a) Interpretation: The three-dimensional representation for the enantiomers of each compound should be drawn. Concept Introduction: Enantiomers are the stereoisomers that are non-superimposable mirror images. In the three-dimensional representation of the compound, substituents are attached with dash and wedge bonds here, dash bonds (dashed lines) represent the group is attached from below the plane and wedge bond (solid lines) represent the group is attached from top of the plane.

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Answer 1

Question

Chapter 14.1, Problem 14.1QC

Interpretation Introduction

(a)

Interpretation:

The three-dimensional representation for the enantiomers of each compound should be drawn.

Concept Introduction:

Enantiomers are the stereoisomers that are non-superimposable mirror images. In the three-dimensional representation of the compound, substituents are attached with dash and wedge bonds here, dash bonds (dashed lines) represent the group is attached from below the plane and wedge bond (solid lines) represent the group is attached from top of the plane.

Interpretation Introduction

(b)

Interpretation:

The three-dimensional representation for the enantiomers of each compound should be drawn.

Concept Introduction:

Enantiomers are the stereoisomers that are non-superimposable mirror images. In the three-dimensional representation of the compound, substituents are attached with dash and wedge bonds here, dash bonds (dashed lines) represent the group is attached from below the plane and wedge bond (solid lines) represent the group is attached from top of the plane.

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Problem 1: It is desired to prepare polyester with the number average molecular weight, Mn- 5000 g/mol by reacting of 1 mol butane-1,4 diol (HO-CH2-CH2-CH2-CH2-OH) with 1 mol of adipic acid (HOOC-CH2-CH2-CH2-CH2-COOH). (a) Write chemical equation illustrating synthesis of the polyester. (b) Calculate the value of the monomer conversion at which the reaction should be stopped to obtain this polymer, assuming perfect stoichiometric balance. What would be polydispersity index for the polymer obtained? (c) Assuming that 0.5 mol % of the diol is lost to polymerization by a side reaction (dehydratation to a non-reactive substance), what would be the value of Mn if the reaction was carried out to the same extent as in part (b). (d) For the polymerization process value of polymerization rate constant is 1.5*102 L/(mol*s) at 100° C. How long would it take to prepare the polyester with the number average molecular weight, M, 5,000 g/mol at 100 ° C? There is no diol loss for this part of…

Answer 2

Question

Chapter 14.1, Problem 14.1QC

Interpretation Introduction

(a)

Interpretation:

The three-dimensional representation for the enantiomers of each compound should be drawn.

Concept Introduction:

Enantiomers are the stereoisomers that are non-superimposable mirror images. In the three-dimensional representation of the compound, substituents are attached with dash and wedge bonds here, dash bonds (dashed lines) represent the group is attached from below the plane and wedge bond (solid lines) represent the group is attached from top of the plane.

Interpretation Introduction

(b)

Interpretation:

The three-dimensional representation for the enantiomers of each compound should be drawn.

Concept Introduction:

Enantiomers are the stereoisomers that are non-superimposable mirror images. In the three-dimensional representation of the compound, substituents are attached with dash and wedge bonds here, dash bonds (dashed lines) represent the group is attached from below the plane and wedge bond (solid lines) represent the group is attached from top of the plane.

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Answer 3

Question

Chapter 14.1, Problem 14.1QC

Interpretation Introduction

(a)

Interpretation:

The three-dimensional representation for the enantiomers of each compound should be drawn.

Concept Introduction:

Enantiomers are the stereoisomers that are non-superimposable mirror images. In the three-dimensional representation of the compound, substituents are attached with dash and wedge bonds here, dash bonds (dashed lines) represent the group is attached from below the plane and wedge bond (solid lines) represent the group is attached from top of the plane.

Interpretation Introduction

(b)

Interpretation:

The three-dimensional representation for the enantiomers of each compound should be drawn.

Concept Introduction:

Enantiomers are the stereoisomers that are non-superimposable mirror images. In the three-dimensional representation of the compound, substituents are attached with dash and wedge bonds here, dash bonds (dashed lines) represent the group is attached from below the plane and wedge bond (solid lines) represent the group is attached from top of the plane.

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Answer 4

Question

Chapter 14.1, Problem 14.1QC

Interpretation Introduction

(a)

Interpretation:

The three-dimensional representation for the enantiomers of each compound should be drawn.

Concept Introduction:

Enantiomers are the stereoisomers that are non-superimposable mirror images. In the three-dimensional representation of the compound, substituents are attached with dash and wedge bonds here, dash bonds (dashed lines) represent the group is attached from below the plane and wedge bond (solid lines) represent the group is attached from top of the plane.

Interpretation Introduction

(b)

Interpretation:

The three-dimensional representation for the enantiomers of each compound should be drawn.

Concept Introduction:

Enantiomers are the stereoisomers that are non-superimposable mirror images. In the three-dimensional representation of the compound, substituents are attached with dash and wedge bonds here, dash bonds (dashed lines) represent the group is attached from below the plane and wedge bond (solid lines) represent the group is attached from top of the plane.

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Answer 5

Chapter 14.1, Problem 14.1QC

Interpretation Introduction

(a)

Interpretation:

The three-dimensional representation for the enantiomers of each compound should be drawn.

Concept Introduction:

Enantiomers are the stereoisomers that are non-superimposable mirror images. In the three-dimensional representation of the compound, substituents are attached with dash and wedge bonds here, dash bonds (dashed lines) represent the group is attached from below the plane and wedge bond (solid lines) represent the group is attached from top of the plane.

Interpretation Introduction

(b)

Interpretation:

The three-dimensional representation for the enantiomers of each compound should be drawn.

Concept Introduction:

Enantiomers are the stereoisomers that are non-superimposable mirror images. In the three-dimensional representation of the compound, substituents are attached with dash and wedge bonds here, dash bonds (dashed lines) represent the group is attached from below the plane and wedge bond (solid lines) represent the group is attached from top of the plane.

Answer 6

Chapter 14.1, Problem 14.1QC

Interpretation Introduction

(a)

Interpretation:

The three-dimensional representation for the enantiomers of each compound should be drawn.

Concept Introduction:

Enantiomers are the stereoisomers that are non-superimposable mirror images. In the three-dimensional representation of the compound, substituents are attached with dash and wedge bonds here, dash bonds (dashed lines) represent the group is attached from below the plane and wedge bond (solid lines) represent the group is attached from top of the plane.

Answer 7

Chapter 14.1, Problem 14.1QC

Interpretation Introduction

(a)

Interpretation:

The three-dimensional representation for the enantiomers of each compound should be drawn.

Concept Introduction:

Enantiomers are the stereoisomers that are non-superimposable mirror images. In the three-dimensional representation of the compound, substituents are attached with dash and wedge bonds here, dash bonds (dashed lines) represent the group is attached from below the plane and wedge bond (solid lines) represent the group is attached from top of the plane.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The three-dimensional representation for the enantiomers of each compound should be drawn.

Concept Introduction:

Enantiomers are the stereoisomers that are non-superimposable mirror images. In the three-dimensional representation of the compound, substituents are attached with dash and wedge bonds here, dash bonds (dashed lines) represent the group is attached from below the plane and wedge bond (solid lines) represent the group is attached from top of the plane.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The three-dimensional representation for the enantiomers of each compound should be drawn.

Concept Introduction:

Enantiomers are the stereoisomers that are non-superimposable mirror images. In the three-dimensional representation of the compound, substituents are attached with dash and wedge bonds here, dash bonds (dashed lines) represent the group is attached from below the plane and wedge bond (solid lines) represent the group is attached from top of the plane.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 14.1 - Prob. 14.1QC Ch. 14.2 - Problem 15-2 Assign priorities to the groups in...Ch. 14.2 - Problem 15-3 Assign an R or S configuration to the...Ch. 14.3 - Problem 15-4 3-Amino-2-butanol has two...Ch. 14.3 - Prob. 14.5QC Ch. 14.3 - Prob. 14.6QC Ch. 14 - 15-7 Answer true or false. The cis and trans...Ch. 14 - 15-8 What does the term “chiral” mean? Give an...Ch. 14 - 15-9 What does the term “achiral” mean? Give an...Ch. 14 - 15-10 Define the term “stereoisomer.” Name three...

Solution Summary: The author explains that the three-dimensional representation for the enantiomers of each compound should be drawn.

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Chapter 14 Solutions