Introduction To General, Organic, And Biochemistry
12th Edition
ISBN: 9781337571357
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Question
Chapter 14, Problem 25P
Interpretation Introduction
Interpretation:
The true and false statements should be identified.
Concept Introduction:
An optically active substance has two conditions:
- It should have chiral carbon atom.
- It should not possess plane of symmetry.
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The general formula for alkanes is CnH2n+2.
What is the value of n in 3,7-dimethyldecane?
How many chiral centres does this molecule have?
Select one:
a. n = 10; there is one chiral centre
b. n = 12; there is one chiral centre
c. n = 10; there are two chiral centres
d. n = 12; there are three chiral centres
e. n = 12; there are two chiral centres
The general formula for alkanes is CnH2n+2.
What is the value of n in 3-ethyl-4,7-dimethylnonane?
How many chiral centres does this molecule have?
Select one:
a. n = 9; there are two chiral centres
b. n = 13; there are three chiral centres
c. n = 9; there are three chiral centres
d. n = 13; there is one chiral centre
e. n = 13; there are two chiral centres
Can you help me find the chiral centers?
Chapter 14 Solutions
Introduction To General, Organic, And Biochemistry
Ch. 14.1 - Prob. 14.1QCCh. 14.2 - Problem 15-2 Assign priorities to the groups in...Ch. 14.2 - Problem 15-3 Assign an R or S configuration to the...Ch. 14.3 - Problem 15-4 3-Amino-2-butanol has two...Ch. 14.3 - Prob. 14.5QCCh. 14.3 - Prob. 14.6QCCh. 14 - 15-7 Answer true or false. The cis and trans...Ch. 14 - 15-8 What does the term “chiral” mean? Give an...Ch. 14 - 15-9 What does the term “achiral” mean? Give an...Ch. 14 - 15-10 Define the term “stereoisomer.” Name three...
Ch. 14 - 15-11 In what way are constitutional isomers...Ch. 14 - 15-12 Which of the following objects are chiral...Ch. 14 - Prob. 7PCh. 14 - Prob. 8PCh. 14 - Prob. 9PCh. 14 - Prob. 10PCh. 14 - 15-15 Explain why the carbon of a carbonyl group...Ch. 14 - 15-16 Which of the following compounds contain...Ch. 14 - 15-17 Which of the following compounds contain...Ch. 14 - Prob. 14PCh. 14 - 15-19 Draw the mirror image for each molecule: OH...Ch. 14 - Prob. 16PCh. 14 - 15-21 Answer true or false. For a molecule with...Ch. 14 - Prob. 18PCh. 14 - Prob. 19PCh. 14 - Prob. 20PCh. 14 - Prob. 21PCh. 14 - 15-26 For centuries, Chinese herbal medicine has...Ch. 14 - Prob. 23PCh. 14 - Prob. 24PCh. 14 - Prob. 25PCh. 14 - Prob. 26PCh. 14 - Prob. 27PCh. 14 - Prob. 28PCh. 14 - Prob. 29PCh. 14 - Prob. 30PCh. 14 - 15-35 Following are structural formulas for three...Ch. 14 - Prob. 32PCh. 14 - 15-37 Consider a cyclohexane ring substituted with...Ch. 14 - Prob. 34PCh. 14 - Prob. 35PCh. 14 - Prob. 36PCh. 14 - 15-41 Compound A(C5Hh, is not optically active and...Ch. 14 - Prob. 38PCh. 14 - 15-43 Triamcinolone acetonide, the active...Ch. 14 - 15-44 Consider the structure of the...Ch. 14 - Prob. 41PCh. 14 - 15-46 Consider Lunesta, a nonbenzodiazepine...Ch. 14 - Prob. 43PCh. 14 - Prob. 44P
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Similar questions
- 15-30 (Chemical Connections 15A) What does it mean to say that a drug is chiral? If a drug is chiral, will it be optically active? That is, will it rotate the plane of polarized light?arrow_forward15-44 Consider the structure of the immunosuppressant FK-506, a molecule shown to disrupt calcineurin- mediated signal transduction in T-lymphocytes. What is the molecular formula of this immunosuppressant? How manj' stereocenters are present in FK-506? Determine the maximum number of stereoisomers possible. Identify and label the various functional groups present. Consider the two stereocenters in this structure labeled with asterisks (*). Determine the absolute configuration of each stereocenter. FK-506 has been shown to exhibit moderate solubility in various organic solvents. Is this immunosuppressant expected to be soluble in ethanol (CH3CH2OH)? Consider the carbon atom labeled “1." Describe the geometry and approximate bond angles about this carbon atom. Draw the alternative chair conformations of the cyclohexane ring at the lower right of FK-506 and label the more stable conformation. Are there any aromatic components present in FK-506? Patients taking FK-506 have reported several side effects from this medication, including headaches, nausea or diarrhea, and slight shaking. Would you expect the enantiomer of this drug to result in the same side effects?arrow_forward15-43 Triamcinolone acetonide, the active ingredient in Azmacort Inhalation Aerosol, is a steroid used to treat bronchial asthma. Triamcinolone acetonide Label the eight stereocenters in this molecule. How many stereoisomers are possible for it? (Of these, the stereoisomer with the configura tion shown here is the active ingredient in Azmacort.)arrow_forward
- 15-21 Answer true or false. For a molecule with two stereocenters, 22 = 4 stereoisomers are possible. For a molecule with three stereocenters, 32 = 9 stereoisomers are possible. Enantiomers, like gloves, occur in pairs. 2-Pentanol and 3-pentanol are both chiral and show enantiomerism. 1-Methylcyclohexanol is achiral and does not show enantiomerism. Diastereomers are stereoisomers that are not mirror images.arrow_forward15-10 Define the term “stereoisomer.” Name three types of stereoisomers.arrow_forward15-7 Answer true or false. The cis and trans stereoisomers of 2-butene are achiral. The carbonyl carbon of an aldehyde, ketone, carboxylic acid, or ester cannot be a stereocenter. Stereoisomers have the same connectivity of their atoms. Constitutional isomers have the same connectivity of their atoms. An unmarked cube is achiral. A human foot is chiral. Every object in nature has a mirror image. The most common cause of chirality in organic molecules is the presence of a tetrahedral carbon atom with four different groups bonded to it. If a molecule is not superposable on its mirror image, the molecule is chiral.arrow_forward
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