ORGANIC CHEMISTRY GGC>CUSTOM<-TEXT
ORGANIC CHEMISTRY GGC>CUSTOM<-TEXT
2nd Edition
ISBN: 9781119288510
Author: Klein
Publisher: WILEY
Question
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Chapter 14.11, Problem 23CC

a)

Interpretation Introduction

Interpretation: The products for the given transformations are to be predicted.

Concept Introduction:

Ether analogs of Sulphur called Sulphide or Thioethers. Common names of these compounds are given by fixing the suffix Sulphide instead of Ether.

Preparation of Sulphides from Thiols is given below,

ORGANIC CHEMISTRY GGC>CUSTOM<-TEXT, Chapter 14.11, Problem 23CC , additional homework tip  1

Mechanism:

In the first step, deprotonation of thiol takes place to form thiolate ions.

ORGANIC CHEMISTRY GGC>CUSTOM<-TEXT, Chapter 14.11, Problem 23CC , additional homework tip  2

In the second step, thiolate acts as nucleophile and attacks the alkyl halide.

ORGANIC CHEMISTRY GGC>CUSTOM<-TEXT, Chapter 14.11, Problem 23CC , additional homework tip  3

b)

Interpretation Introduction

Interpretation: The products for the given transformations are to be predicted.

Concept Introduction:

Ether analogs of Sulphur called Sulphide or Thioethers. Common names of these compounds are given by fixing the suffix Sulphide instead of Ether.

Preparation of Sulphides from Thiols is given below,

ORGANIC CHEMISTRY GGC>CUSTOM<-TEXT, Chapter 14.11, Problem 23CC , additional homework tip  4

Mechanism:

In the first step, deprotonation of thiol takes place to form thiolate ions.

ORGANIC CHEMISTRY GGC>CUSTOM<-TEXT, Chapter 14.11, Problem 23CC , additional homework tip  5

In the second step, thiolate acts as nucleophile and attacks the alkyl halide.

ORGANIC CHEMISTRY GGC>CUSTOM<-TEXT, Chapter 14.11, Problem 23CC , additional homework tip  6

c)

Interpretation Introduction

Interpretation: The products for the given transformations are to be predicted.

Concept Introduction:

Ether analogs of Sulphur called Sulphide or Thioethers. Common names of these compounds are given by fixing the suffix Sulphide instead of Ether.

Preparation of Sulphides from Thiols is given below,

ORGANIC CHEMISTRY GGC>CUSTOM<-TEXT, Chapter 14.11, Problem 23CC , additional homework tip  7

Mechanism:

In the first step, deprotonation of thiol takes place to form thiolate ions.

ORGANIC CHEMISTRY GGC>CUSTOM<-TEXT, Chapter 14.11, Problem 23CC , additional homework tip  8

In the second step, thiolate acts as nucleophile and attacks the alkyl halide.

ORGANIC CHEMISTRY GGC>CUSTOM<-TEXT, Chapter 14.11, Problem 23CC , additional homework tip  9

d)

Interpretation Introduction

Interpretation: The products for the given transformations are to be predicted.

Concept Introduction:

Ether analogs of Sulphur called Sulphide or Thioethers. Common names of these compounds are given by fixing the suffix Sulphide instead of Ether.

Preparation of Sulphides from Thiols is given below,

ORGANIC CHEMISTRY GGC>CUSTOM<-TEXT, Chapter 14.11, Problem 23CC , additional homework tip  10

Mechanism:

In the first step, deprotonation of thiol takes place to form thiolate ions.

ORGANIC CHEMISTRY GGC>CUSTOM<-TEXT, Chapter 14.11, Problem 23CC , additional homework tip  11

In the second step, thiolate acts as nucleophile and attacks the alkyl halide.

ORGANIC CHEMISTRY GGC>CUSTOM<-TEXT, Chapter 14.11, Problem 23CC , additional homework tip  12

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Chapter 14 Solutions

ORGANIC CHEMISTRY GGC>CUSTOM<-TEXT

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