Solution Manual for Quantitative Chemical Analysis
Solution Manual for Quantitative Chemical Analysis
9th Edition
ISBN: 9781464175633
Author: Daniel Harris
Publisher: Palgrave Macmillan Higher Ed
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Chapter 14.6, Problem 11TY
Interpretation Introduction

Interpretation:

The formation coefficient Kf has to be calculated when the cell voltage is 0.300V .

Concept Introduction:

Cell Voltage:

Cell voltage is the difference between cathode potential and anode potential.

Ecell=E+-E-

Nernst equation:

In electrochemistry, the standard reduction potentials are related with the temperature and gas constant and standard electrode potentials and concentrations.

Ecell=E0cell-RTnFlog[cathode]n[anode]n

Formation coefficient:

The general form of a problem where the problem has the relation between concentrations of the reactants and products,

Kf=[HgY2-][Hg2+][Y4-]=[HgY2-][Hg2+]αY4-[EDTA]

Where,

K = formation constant

[Y4-]Y4-[EDTA]

[EDTA] = formal concentration which is not bound to the metal= 0.0150M

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Chapter 14 Solutions

Solution Manual for Quantitative Chemical Analysis

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