Chemistry: An Atoms First Approach
2nd Edition
ISBN: 9781305079243
Author: Steven S. Zumdahl, Susan A. Zumdahl
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Concept explainers
Textbook Question
Chapter 15, Problem 106CP
A mixture contains 1.0 × 10−3 M Cu2+ and 1.0 × 10−3 M Mn2+ and is saturated with 0.10 M H2S. Determine a pH where CuS precipitates but MnS does not precipitate. Ksp for CuS = 8.5 × 10−45 and Ksp for MnS = 2.3 × 10−13.
Expert Solution & Answer
Trending nowThis is a popular solution!
Students have asked these similar questions
What is the molar solubility of nickel(II) sulfide in 0.091 M KCN?
For NiS, Ksp= 3.0 x 10-19
For Ni(CN)4-2 Kf= 1.0 x 1031
If 50.0 g of barium arsenate (Ksp = 1.1 x 10-13) are placed in enough water to generate 500.0 mL of solution, calculate the following:
The molar solubility of the barium arsenate solution.
The molar solubility of the barium ion if 30.0 mL of 0.400 M barium nitrate solution is added to the original solution.
Calculate the molar solubility of lead(II) iodide in water at 25°C. given that Ksp = 7.1 x 10-9Calculate the molar solubility of Mg(OH)2 (Ksp = 1.8 * 10-11 ) in(a) pure water;(b) 0.0862 M MgCl2.(c) 0.0355 M KOH(aq).
Chapter 15 Solutions
Chemistry: An Atoms First Approach
Ch. 15 - To what reaction does the solubility product...Ch. 15 - Prob. 2RQCh. 15 - Prob. 3RQCh. 15 - Prob. 4RQCh. 15 - Prob. 5RQCh. 15 - Prob. 6RQCh. 15 - Prob. 7RQCh. 15 - Prob. 8RQCh. 15 - Prob. 9RQCh. 15 - Prob. 10RQ
Ch. 15 - Prob. 1ALQCh. 15 - Prob. 2ALQCh. 15 - Prob. 3ALQCh. 15 - A friend tells you: The constant Ksp of a salt is...Ch. 15 - Prob. 5ALQCh. 15 - Prob. 6ALQCh. 15 - Prob. 7ALQCh. 15 - For which of the following is the Ksp value of the...Ch. 15 - Ag2S(s) has a larger molar solubility than CuS...Ch. 15 - Prob. 10QCh. 15 - Prob. 11QCh. 15 - When Na3PO4(aq) is added to a solution containing...Ch. 15 - The common ion effect for ionic solids (salts) is...Ch. 15 - Prob. 14QCh. 15 - Prob. 15QCh. 15 - The stepwise formation constants for a complex ion...Ch. 15 - Prob. 17QCh. 15 - Prob. 18QCh. 15 - Write balanced equations for the dissolution...Ch. 15 - Write balanced equations for the dissolution...Ch. 15 - Prob. 21ECh. 15 - Use the following data to calculate the Ksp value...Ch. 15 - Approximately 0.14 g nickel(II) hydroxide,...Ch. 15 - The solubility of the ionic compound M2X3, having...Ch. 15 - Prob. 25ECh. 15 - Prob. 26ECh. 15 - Calculate the solubility of each of the following...Ch. 15 - Prob. 28ECh. 15 - Cream of tartar, a common ingredient in cooking,...Ch. 15 - Prob. 30ECh. 15 - Prob. 31ECh. 15 - Calculate the molar solubility of Cd(OH)2, Ksp =...Ch. 15 - Calculate the molar solubility of Al(OH)3, Ksp = 2...Ch. 15 - Calculate the molar solubility of Co(OH)3, Ksp =...Ch. 15 - Prob. 35ECh. 15 - For each of the following pairs of solids,...Ch. 15 - Calculate the solubility (in moles per liter) of...Ch. 15 - Calculate the solubility of Co(OH)2(s) (Ksp = 2.5 ...Ch. 15 - The Ksp for silver sulfate (Ag2SO4) is 1.2 105....Ch. 15 - Prob. 40ECh. 15 - Prob. 41ECh. 15 - Prob. 42ECh. 15 - Prob. 43ECh. 15 - The solubility of Pb(IO3)(s) in a 0.10-M KIO3...Ch. 15 - Prob. 45ECh. 15 - For which salt in each of the following groups...Ch. 15 - What mass of ZnS (Ksp = 2.5 1022) will dissolve...Ch. 15 - The concentration of Mg2+ in seawater is 0.052 M....Ch. 15 - Will a precipitate form when 100.0 mL of 4.0 104...Ch. 15 - A solution contains 1.0 105 M Ag+ and 2.0 106 M...Ch. 15 - A solution is prepared by mixing 100.0 mL of 1.0 ...Ch. 15 - Prob. 52ECh. 15 - Calculate the final concentrations of K+(aq),...Ch. 15 - Prob. 54ECh. 15 - A 50.0-mL sample of 0.00200 M AgNO3 is added to...Ch. 15 - Prob. 56ECh. 15 - A solution contains 1.0 105 M Na3PO4. What is the...Ch. 15 - The Ksp of Al(OH)3 is 2 1032. At what pH will a...Ch. 15 - A solution is 1 104 M in NaF, Na2S, and Na3PO4....Ch. 15 - A solution contains 0.25 M Ni(NO3)2 and 0.25 M...Ch. 15 - Write equations for the stepwise formation of each...Ch. 15 - Write equations for the stepwise formation of each...Ch. 15 - In the presence of CN, Fe3+ forms the complex ion...Ch. 15 - In the presence of NH3, Cu2+ forms the complex ion...Ch. 15 - Prob. 65ECh. 15 - Prob. 66ECh. 15 - The overall formation constant for HgI42 is 1.0 ...Ch. 15 - Prob. 68ECh. 15 - A solution is formed by mixing 50.0 mL of 10.0 M...Ch. 15 - A solution is prepared by mixing 100.0 mL of 1.0 ...Ch. 15 - a. Calculate the molar solubility of AgI in pure...Ch. 15 - Solutions of sodium thiosulfate are used to...Ch. 15 - Kf for the complex ion Ag(NH3)2+ is 1.7 107. Ksp...Ch. 15 - Prob. 74ECh. 15 - Prob. 75ECh. 15 - The solubility of copper(II) hydroxide in water...Ch. 15 - A solution contains 0.018 mole each of I, Br, and...Ch. 15 - Prob. 78AECh. 15 - Tooth enamel is composed of the mineral...Ch. 15 - Prob. 80AECh. 15 - What mass of Ca(NO3)2 must be added to 1.0 L of a...Ch. 15 - Calculate the mass of manganese hydroxide present...Ch. 15 - Prob. 83AECh. 15 - The active ingredient of Pepto-Bismol is the...Ch. 15 - Prob. 85AECh. 15 - The equilibrium constant for the following...Ch. 15 - Calculate the concentration of Pb2+ in each of the...Ch. 15 - Will a precipitate of Cd(OH)2 form if 1.0 mL of...Ch. 15 - Prob. 89AECh. 15 - Describe how you could separate the ions in each...Ch. 15 - Prob. 91AECh. 15 - Prob. 92AECh. 15 - Prob. 93CWPCh. 15 - Prob. 94CWPCh. 15 - Prob. 95CWPCh. 15 - The solubility of Pb(IO3)2(s) in a 7.2 102-M KIO3...Ch. 15 - A 50.0-mL sample of 0.0413 M AgNO3(aq) is added to...Ch. 15 - Prob. 98CWPCh. 15 - Prob. 99CPCh. 15 - Consider a solution made by mixing 500.0 mL of 4.0...Ch. 15 - a. Calculate the molar solubility of AgBr in pure...Ch. 15 - Prob. 102CPCh. 15 - Prob. 103CPCh. 15 - Calcium oxalate (CaC2O4) is relatively insoluble...Ch. 15 - What is the maximum possible concentration of Ni2+...Ch. 15 - A mixture contains 1.0 103 M Cu2+ and 1.0 103 M...Ch. 15 - Sodium tripolyphosphate (Na5P3O10) is used in many...Ch. 15 - You add an excess of solid MX in 250g water. You...Ch. 15 - a. Calculate the molar solubility of SrF2 in...Ch. 15 - Prob. 110IPCh. 15 - Prob. 111IPCh. 15 - Prob. 112IPCh. 15 - Aluminum ions react with the hydroxide ion to form...
Additional Science Textbook Solutions
Find more solutions based on key concepts
Fully developed conditions are known to exist for water flowing through a 25-nim-diameer tube at 0.01 kg/s and ...
Fundamentals of Heat and Mass Transfer
What is the pH range for acidic solutions? For basic solutions?
Introduction to Chemistry
Write the electron configurations far each of the following elements: (a) Sc. (b) Ti. (c) Cr. (d) Fe. (e) Ru
Chemistry by OpenStax (2015-05-04)
22.102 Write the structures of the cis and tram isomers, if any, for the following compounds:
Chemistry: The Molecular Nature of Matter
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- A solution contains 0.25 M Ni(NO3)2 and 0.25 M Cu(NO3)2. Can the metal ions be separated by slowly adding Na2CO3? Assume that for successful separation 99% of the metal ion must be precipitated before the other metal ion begins to precipitate, and assume no volume change on addition of Na2CO3.arrow_forwardSolid sodium fluoride is slowly added to an aqueous solution that contains 0.0100-M Pb2+ and 0.0100-M Ca2+. (a) Determine which precipitates first, calcium fluoride or lead(II) fluoride. (b) Calculate the percentage of Ca2+ or Pb2+ that has precipitated just prior to the precipitation of the compound that precipitates second.arrow_forwardConsider 0.0010-M solutions of these sparingly soluble solutes in equilibrium with their ions. Predict the effect on each equilibrium if a saturated solution of sodium iodide were added. Explain your prediction in each case. AgI(s) ⇌ Ag+(aq) + I−(aq) PbI2(s) ⇌ Pb2+(aq) + 2 I−(aq)arrow_forward
- A 3.20-L solution of 1.25 103 M Pb(NO3)2 is mixed with a 0.80-L solution of 5.0 101 M NaCl. Calculate Q for the dissolution of PbCl2. No precipitate has formed. Is the solution supersaturated, saturated, or unsaturated?arrow_forwardWhat mass of Ca(NO3)2 must be added to 1.0 L of a 1.0-M HF solution to begin precipitation of CaF2(s)? For CaF2, Ksp = 4.0 1011 and Ka for HF = 7.2 104. Assume no volume change on addition of Ca(NO3)2(s).arrow_forward(a) Determine whether AgCl precipitates from a solution containing 1.0 105-M Ag+ and 1.0 105-M Cl. Ksp AgCl = 1.8 1010. (b) An AgCl precipitate forms from a solution that contains 1.0 105-M Ag+. Calculate the minimum Cl concentration required for precipitation to occur.arrow_forward
- Consider the dissolution of slightly soluble salt, PbCl2 (Ksp = 1.70 x 10-5): PbCl2(s) ⇌ Pb2+(aq) + 2Cl-(aq) Calculate the molar solubility of PbCl2 in:a. Pure Water b. 0.10 M Pb(NO3)2 Express the answer in four decimal placesarrow_forwarda. What is the molar solubility of silver sulfate (Ag2SO4) in water if the solubility product constant is 1.20 x 10-6? b. What is the lowest [Ag+] needed to start precipitating Ag2SO4 in a solution of 0.170 M sodium sulfate (Na2SO4)?arrow_forwardCalculate the molar solubility of barium fluoride, BaF2 (Ksp = 1.0 x 10-6 at 25 oC) in: Pure water at 25 oC A solution that already had 0.15 M NaF at 25oC.arrow_forward
- You are trying to separate calcium ions (Ca2+) from lead ions (Pb2+), both present in a mixture and each at a concentration of 0.010 M. You will accomplish this by titrating (adding slowly) sodium sulfate (Na2SO4). (Ksp for CaSO4 = 4.9 x 10-5; Ksp for PbSO4 = 1.3 x 10-8 at 25 °C.). Which will be the first salt to precipitate? What will the concentration of the first ion to precipitate (Ca2+ or Pb2+) be when the second salt begins to precipitate?arrow_forwardA solution is prepared by mixing 50.0 mL of 0.50 M CaCl2 with 50.0 mL of 0.50 M CoCl2. When NaOH is slowly added to the mixture, which precipitates first? Ksp[Ca(OH)2] = 6.5 × 10–6, Ksp[Co(OH)2] = 2.5 × 10–16arrow_forwardCadmium cations Cd^2+ form a soluble metal complex ion [Cd(NH3)4]^2+ upon the addition of ammonia. The molar solubility of CdS in 2.0 M NH3 is: Ksp (CdS)=3.6 x 10^-29 Kf [Cd(NH3)4]^2+ =4.0 x 10^6 The correct answer is 4.8 x 10 ^-11 M. I just need help with how to solve this problem.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage LearningChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
- General Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage LearningChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Precipitation Reactions: Crash Course Chemistry #9; Author: Crash Course;https://www.youtube.com/watch?v=IIu16dy3ThI;License: Standard YouTube License, CC-BY