(a)
Interpretation:
The
Concept introduction:
Dienes are the compounds that contain carbon-carbon double bonds. The term conjugated dienes is used when the double bonds are present alternatively in a hydrocarbon chain. The mathematical function that describes the wave like behavior of the electron in a molecule is expressed by molecular orbital. The physical and chemical properties are found with the help of molecular orbital.
Answer to Problem 15.1P
The bonding molecular orbitals are
The anti-bonding molecular orbitals are
The molecular orbitals of conjugated
Explanation of Solution
In
The three bonding molecular orbitals are
The three anti bonding molecular orbitals are
The sketch showing the molecular orbital of conjugated
Figure 1
The three bonding molecular orbitals are
The three anti bonding molecular orbitals are
The sketch showing the molecular orbital of conjugated
(b)
Interpretation:
The total number of nodes in the
Concept introduction:
The term conjugated dienes is used when the double bonds are present alternatively in a hydrocarbon chain. The mathematical function that describes the wave like behavior of an electron in a molecule is expressed by molecular orbital. The molecular orbital contains nodes and lobes. Nodes are the regions in the molecular orbital of conjugated system in which the adjoining orbital lobes undergoes a phase change.
Answer to Problem 15.1P
The total number of nodes that the molecular orbital (MOs) of conjugated
Explanation of Solution
There is no change of phase occurs in lobes in the
There is one change of phase occurs in lobes in the
There is two change of phase occurs in lobes in the
There are four change of phase occurs in lobes in the
There are five change of phase occurs in lobes in the
There are six change of phase occurs in lobes in the
The number of nodes that molecular orbital (MOs) of conjugated
Molecular Orbital | Number of Nodes |
Zero | |
One | |
Two | |
Three | |
Four | |
Five |
The number of nodes that molecular orbital (MOs) of conjugated
(c)
Interpretation:
The position of the nodes in
Concept introduction:
The term conjugated dienes is used when the double bonds are present alternatively in a hydrocarbon chain. The mathematical function that describes the wave like behavior of the electron in a molecule is expressed by molecular orbital. The molecular orbital contains nodes and lobes. Nodes are the regions in the molecular orbital of conjugated system in which the adjoining orbital lobes undergoes a phase change.
Answer to Problem 15.1P
The position of the nodes in
Explanation of Solution
There is no change of phase occurs in lobes in the
.
The sketch of
Figure 2
There is one change of phase occurs in lobes in the
The sketch of
Figure 3
There are 6 change of phase occurs in lobes in the
The
The sketch of
Figure 4
The position of the nodes in
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Chapter 15 Solutions
Loose-leaf Version For Organic Chemistry
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