Concept explainers
(a)
Interpretation: The product(s) formed by the reaction of given
Concept introduction: The reaction of hydrogen halide with alkene results in the formation of
Answer to Problem 15.23P
The product formed by the reaction of given alkene with
The product formed by the reaction of given alkene with
Explanation of Solution
Electrophilic addition reaction follows Markovnikov rule. According to Markovnikov rule, the positive part of halogen acid attached to that carbon atom in
The given alkene is shown below.
Figure 1
The steps followed by electrophilic addition reaction are stated below:
• First protonation of the alkene take place to generate the carbocation.
• The halide ion will attack on the carbocation to give the final product.
The product formed by the reaction of given alkene with
Figure 2
The product formed by the reaction of given alkene with
The addition of
The addition of
The product formed by the reaction of given alkene with
Figure 3
The product formed by the reaction of given alkene with
The product(s) formed by the reaction of given alkene with
(b)
Interpretation: The product(s) formed by the reaction of given alkene with
Concept introduction: The reaction of hydrogen halide with alkene results in the formation of alkyl halide. This type of reaction is an electrophilic addition of hydrogen halide. Electrophilic addition reactions are those in which breaking of pi bond take place to form new sigma bond.
Answer to Problem 15.23P
The product formed by the reaction of given alkene with
The product formed by the reaction of given alkene with
Explanation of Solution
Electrophilic addition reaction follows Markovnikov rule. According to Markovnikov rule, the positive part of halogen acid attached to that carbon atom in
The given alkene is shown below.
Figure 4
The steps followed by electrophilic addition reaction are stated below:
• First protonation of the alkene take place to generate the carbocation.
• The halide ion will attack on the carbocation to give the final product.
The product formed by the reaction of given alkene with
Figure 5
The product formed by the reaction of given alkene with
The addition of
The addition of
The product formed by the reaction of given alkene with
Figure 6
The product formed by the reaction of given alkene with
The product(s) formed by the reaction of given alkene with
(c)
Interpretation: The product(s) formed by the reaction of given alkene with
Concept introduction: The reaction of hydrogen halide with alkene results in the formation of alkyl halide. This type of reaction is an electrophilic addition of hydrogen halide. Electrophilic addition reactions are those in which breaking of pi bond take place to form new sigma bond.
Answer to Problem 15.23P
The product formed by the reaction of given alkene with
The product formed by the reaction of given alkene with
Explanation of Solution
Electrophilic addition reaction follows Markovnikov rule. According to Markovnikov rule, the positive part of halogen acid attached to that carbon atom in
The given alkene is shown below.
Figure 7
The steps followed by electrophilic addition reaction are stated below:
• First protonation of the alkene take place to generate the carbocation.
• The halide ion will attack on the carbocation to give the final product.
The product formed by the reaction of given alkene with
Figure 8
The reaction of given alkene with
The addition of
The addition of
The product formed by the reaction of given alkene with
Figure 9
The reaction of given alkene with
The product(s) formed by the reaction of given alkene with
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Chapter 15 Solutions
ORGANIC CHEMISTRY SOLUTIONS MANUAL
- Draw a stepwise mechanism for the following reduction.arrow_forwardDraw a stepwise mechanism for the following reaction that forms ether D. D can be converted to the antidepressant fluoxetine (trade name Prozac) in a single step.arrow_forwardDraw a stepwise mechanism for the attached reaction, which involves two Friedel–Crafts reactions. B was an intermediate in the synthesis of the antidepressant sertralinearrow_forward
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- Ethers are oxidized with O2 to form hydroperoxides that decompose violently when heated. Draw a stepwise mechanism for this reaction.arrow_forwardDraw the organic product of each reaction (d).arrow_forward(a) Give an acceptable name for compound A. (b) Draw the organic products formed when A is treated with each reagent: [1] H3O+; [2] −OH, H2O; [3] CH3CH2CH2MgBr (excess), then H2O; [4] LiAlH4, then H2O.arrow_forward
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