FUND.OF GEN CHEM CHAP 1-13 W/ACCESS
16th Edition
ISBN: 9781323406038
Author: McMurry
Publisher: PEARSON C
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 15.7, Problem 15.15P
(a)
Interpretation Introduction
Interpretation:
Given the reaction (a) was formed by hemiacetals (or) hemiketals and transformation process should be identified.
Concept Introduction:
Acetal formation: The small amount of acid catalysts is added to the reaction of an alcohol with an
Hemiacetal: A compound with both an alcohol like (-OH) group and ether like (-OR) group bond to the carbon atom was at one time the aldehyde carbonyl carbon.
Hemiketals: A compound with both an alcohol (-OH) groups and an ether (-OR) groups are bonded to the carbon atom that was at one time the ketone carbonyl carbon.
(b)
Interpretation Introduction
Interpretation:
Given the reaction (a) was formed by hemiacetals (or) hemiketals and transformation process should be identified.
Concept Introduction:
Acetal formation: The small amount of acid catalysts is added to the reaction of an alcohol with an aldehyde or ketone, the hemi-space initially formed is converted into an acetal or a ketal substitution reaction.
Hemiketals: A compound with both an alcohol (-OH) groups and an ether (-OR) groups are bonded to the carbon atom that was at one time the ketone carbonyl carbon.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Under standard conditions, will the following reaction proceed spontaneously as written?
What would be the characteristics of a transition-state analog for the chymotrypsin reaction?
Give full reaction for the synthesis of Diclofenac sodium ?
Chapter 15 Solutions
FUND.OF GEN CHEM CHAP 1-13 W/ACCESS
Ch. 15.1 - Prob. 15.1PCh. 15.1 - Prob. 15.2PCh. 15.2 - Draw structures corresponding to the following...Ch. 15.2 - Prob. 15.1CIAPCh. 15.2 - Prob. 15.2CIAPCh. 15.2 - Prob. 15.4PCh. 15.2 - Draw the line structures and provide common names...Ch. 15.2 - Prob. 15.6KCPCh. 15.3 - For each compound shown next (ad), indicate...Ch. 15.3 - Prob. 15.8KCP
Ch. 15.4 - Prob. 15.9KCPCh. 15.5 - Indicate whether the following compounds will give...Ch. 15.6 - Draw line structures of the following compounds...Ch. 15.6 - Prob. 15.12PCh. 15.7 - Prob. 15.13PCh. 15.7 - Prob. 15.14PCh. 15.7 - Prob. 15.15PCh. 15.7 - Draw the structure of each acetal or ketal final...Ch. 15.7 - Prob. 15.17PCh. 15.7 - Prob. 15.18PCh. 15.7 - Prob. 15.19PCh. 15.7 - Prob. 15.1MRPCh. 15.7 - Prob. 15.2MRPCh. 15.7 - Prob. 15.3MRPCh. 15.7 - Prob. 15.3CIAPCh. 15.7 - (a) What are mirotubules? (b) Why would drugs that...Ch. 15.7 - Tetrodotoxin, found in the puffer fish, has been...Ch. 15 - Prob. 15.20UKCCh. 15 - Prob. 15.21UKCCh. 15 - Prob. 15.22UKCCh. 15 - Prob. 15.23UKCCh. 15 - Prob. 15.24UKCCh. 15 - Prob. 15.25UKCCh. 15 - ALDEHYDESAND KETONES (SECTIONS 15.1 AND 15.2)...Ch. 15 - Draw a structure for a compound that meets each of...Ch. 15 - Prob. 15.28APCh. 15 - Prob. 15.29APCh. 15 - Draw structures corresponding to the following...Ch. 15 - Draw structures corresponding to the following...Ch. 15 - Prob. 15.32APCh. 15 - Prob. 15.33APCh. 15 - The following names are incorrect. What is wrong...Ch. 15 - Prob. 15.35APCh. 15 - Prob. 15.36APCh. 15 - Prob. 15.37APCh. 15 - Prob. 15.38APCh. 15 - Prob. 15.39APCh. 15 - Prob. 15.40APCh. 15 - Draw the structures of the aldehydes that might be...Ch. 15 - Write the structures of the hemiacetal or...Ch. 15 - Write the structures of the hemiacetal or...Ch. 15 - Prob. 15.44APCh. 15 - Prob. 15.45APCh. 15 - Prob. 15.46APCh. 15 - Prob. 15.47APCh. 15 - Prob. 15.48APCh. 15 - Prob. 15.49APCh. 15 - Prob. 15.50CPCh. 15 - Prob. 15.51CPCh. 15 - Prob. 15.52CPCh. 15 - Prob. 15.53CPCh. 15 - Prob. 15.54CPCh. 15 - Name the following compounds: (a) (b) (c) (be sure...Ch. 15 - Draw the structural formulas of the following...Ch. 15 - Prob. 15.57CPCh. 15 - Complete the following equations (refer to Summary...Ch. 15 - Prob. 15.59CPCh. 15 - How could you differentiate between 3-hexanol and...Ch. 15 - The liquids 1-butanol and butanal have similar...Ch. 15 - Prob. 15.62CPCh. 15 - Prob. 15.63GPCh. 15 - Prob. 15.64GPCh. 15 - Using the ketone structural form of fructose...Ch. 15 - Prob. 15.66GP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, biochemistry and related others by exploring similar questions and additional content below.Similar questions
- Will the synthesis of 9,10-dihydroanthracene-9,10-α,β-succinic anhydride via Diels-Alder reaction occur faster under photochemical conditions? Explain.arrow_forwardwhat is the Km and Vmax for the reaction?arrow_forwardExplain the process of polyacrylamide reaction, and what are the two reagents are crucial for this reaction?arrow_forward
- With the help of the half reactions given in Table 1, formulate the redox equation for the oxidation of succinate and reduction of ubiquinone.arrow_forwardDraw the structure of two different aldohexoses that yield the followingaldaric acid when oxidized with HNO3. Use Figure to name eachaldohexosearrow_forwardGiven the following choices,a. what is the structure of the product of the reaction catalysed by ACAT?b. structure of the product produced from the reaction catalysed by phospolipase A2?c. general structure of TAGd. structure of glycerolarrow_forward
- Describe the structuraldifferences betweenthe oxidized form andthe reduced form ofnicotinamidearrow_forwardThe hydrolysis of a phenylalanine-containing peptide is catalyzed by a-chymotrypsin with the following results. Calculate KM and Vmax for the reaction. What is the equation of the line?arrow_forwardAssume that the reaction Arabinose +Pi <> Arabinose-6-P has a delta G of +13.0 kJ/mol and the reaction XTP <> XDP + Pi has a delta G of -25.7 kJ/mol. Calculate the delta G for the combined reaction Arabinose + XTP <> Arabinose-6-P + ADP, in kJ/mol to four significant figures.arrow_forward
- What is the ratio of [isocitrate] to [citrate] under cellular conditions at 37°C?arrow_forwardGive full reaction for the synthesis of Cetirizine ?arrow_forwardAlginic acid, isolated from seaweed and used as athickening agent for ice cream and other foods, is apolymer of d-mannuronic acid with b(1,4) glycosidiclinkages.a. Draw the structure of alginic acid.b. Why does this substance act as a thickening agent?arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
