(a) Interpretation: The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated. Concept introduction: Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

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Answer 1

Question

Chapter 16, Problem 16.24P

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(c)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(d)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(e)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

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Bringing together your knowledge of the reaction chemistry of substituted benzenes, suggest a preparative route for conversion of compound A to compound B shown below

Provide a reasonable stepwise mechanism for the following transformation. Show the structure of any intermediates and use the arrow formalism to account for electron flow. Draw the structure of the regioisomer that might form and suggest a reason why it would not be produced.

Bringing together your knowledge of the reaction chemistry of substituted benzenes, suggest a preparative route for conversion of compound A to compound B shown below [Hint: this will take several sequential reaction steps and will involve different reactions

Answer 2

Question

Chapter 16, Problem 16.24P

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(c)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(d)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(e)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

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Answer 3

Question

Chapter 16, Problem 16.24P

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(c)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(d)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(e)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

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Answer 4

Question

Chapter 16, Problem 16.24P

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(c)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(d)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(e)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

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Answer 5

Chapter 16, Problem 16.24P

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(c)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(d)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(e)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Answer 6

Chapter 16, Problem 16.24P

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Answer 7

Chapter 16, Problem 16.24P

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Answer 14

Interpretation Introduction

(e)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Answer 15

Interpretation Introduction

(e)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Answer 16

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Answer 17

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Answer 18

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Answer 19

Ch. 16 - Prob. 16.1P Ch. 16 - Prob. 16.2P Ch. 16 - Prob. 16.3P Ch. 16 - Prob. 16.4P Ch. 16 - Prob. 16.5P Ch. 16 - Prob. 16.6P Ch. 16 - Prob. 16.7P Ch. 16 - Prob. 16.8P Ch. 16 - Prob. 16.9P Ch. 16 - Prob. 16.10P

Solution Summary: The author explains that electrophilic substitution reactions are reactions in which electron loving species get substituted on a benzene ring.

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Chapter 16 Solutions