Atkins' Physical Chemistry
Atkins' Physical Chemistry
11th Edition
ISBN: 9780198769866
Author: ATKINS, P. W. (peter William), De Paula, Julio, Keeler, JAMES
Publisher: Oxford University Press
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The exchange current density for a system is 3 mA·cm-2. Calculate a) the current density when the overvoltage is 1.6 mV and the temperature is 25°C. b) the value of β of the anodic process if the Tafel slope is 0.6 V at the same temperature. Data: R = 8.314 JK-1mol-1, and F = 96485 C mol-1.
Graphic scheme of the transition of alpha-D-Glucopyranose and beta-D-Glucopyranose from Fischer projection to Haworth projection and to a chair conformation.
MeOH OH H2SO4 (cat.) reflux OMe You are running this reaction, and your lab mate forgets to TLC their esterification reaction and decides that after 2 hours of refluxing the reaction must be done. They concentrate the reaction mixture and take a 1H NMR. In addition to the peaks for the desired product the spectrum includes a peak at 11.90 ppm. The student then re-dissolves their product mixture in DCM and washes the solution with a saturated aqueous NaHCO3 solution. They then dry the organic layer, concentrate the sample on the rotary evaporator to remove the DCM and take a new 1H NMR. The spectrum is now pure methyl ester with no additional peaks. What did the peak at 11.90 ppm indicate to your lab mate and why did washing with NaHCO3 cause it to disappear?

Chapter 16 Solutions

Atkins' Physical Chemistry

Chapter 16, Problem 16A.3BEChapter 16, Problem 16A.4AEChapter 16, Problem 16A.4BEChapter 16, Problem 16A.5AEChapter 16, Problem 16A.5BEChapter 16, Problem 16A.6AEChapter 16, Problem 16A.6BEChapter 16, Problem 16A.7AEChapter 16, Problem 16A.7BEChapter 16, Problem 16A.8AEChapter 16, Problem 16A.8BEChapter 16, Problem 16A.9AEChapter 16, Problem 16A.9BEChapter 16, Problem 16A.10AEChapter 16, Problem 16A.10BEChapter 16, Problem 16A.11AEChapter 16, Problem 16A.11BEChapter 16, Problem 16A.12AEChapter 16, Problem 16A.12BEChapter 16, Problem 16A.1PChapter 16, Problem 16A.5PChapter 16, Problem 16A.6PChapter 16, Problem 16B.1DQChapter 16, Problem 16B.2DQChapter 16, Problem 16B.1AEChapter 16, Problem 16B.1BEChapter 16, Problem 16B.2AEChapter 16, Problem 16B.2BEChapter 16, Problem 16B.3AEChapter 16, Problem 16B.3BEChapter 16, Problem 16B.4AEChapter 16, Problem 16B.4BEChapter 16, Problem 16B.5AEChapter 16, Problem 16B.5BEChapter 16, Problem 16B.6AEChapter 16, Problem 16B.6BEChapter 16, Problem 16B.1PChapter 16, Problem 16B.3PChapter 16, Problem 16B.4PChapter 16, Problem 16B.5PChapter 16, Problem 16B.6PChapter 16, Problem 16B.8PChapter 16, Problem 16B.9PChapter 16, Problem 16C.1DQChapter 16, Problem 16C.2DQChapter 16, Problem 16C.1AEChapter 16, Problem 16C.1BEChapter 16, Problem 16C.2AEChapter 16, Problem 16C.2BEChapter 16, Problem 16C.3AEChapter 16, Problem 16C.3BEChapter 16, Problem 16C.4AEChapter 16, Problem 16C.4BEChapter 16, Problem 16C.5AEChapter 16, Problem 16C.5BEChapter 16, Problem 16C.6AEChapter 16, Problem 16C.6BEChapter 16, Problem 16C.7AEChapter 16, Problem 16C.7BEChapter 16, Problem 16C.8AEChapter 16, Problem 16C.8BEChapter 16, Problem 16C.1PChapter 16, Problem 16C.2PChapter 16, Problem 16C.3PChapter 16, Problem 16C.5PChapter 16, Problem 16C.8PChapter 16, Problem 16C.10PChapter 16, Problem 16.1IA
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