Concept explainers
(a)
Interpretation: The products formed by the Friedel-Craft alkylation of given compound with
Concept introduction: The replacement or substitution of one
(b)
Interpretation: The products formed by the Friedel-Craft alkylation of given compound with
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.
(c)
Interpretation: The products formed by the Friedel-Craft alkylation of given compound with
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.
(d)
Interpretation: The products formed by the Friedel-Craft alkylation of given compound with
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.
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ORGANIC CHEMISTRY-STUDY GDE./SOL.MAN.
- Synthesize each compound from benzene. Use a diazonium salt as one of the synthetic intermediates.arrow_forwardDraw the organic product(s) formed when CH3CH₂CH₂OH is treated with each reagent. a. H₂SO4 d. HBr g. TsCl, pyridine b. NaH h. [1] NaH; [2] CH₂CH₂Br e. SOCI₂, pyridine f. PBr3 c. HCI + ZnCl₂ Hint: NaH deprotonates the alcohol forming an alkoxidearrow_forwardWhich alcohols can be prepared as a single product by hydroboration–oxidation of an alkene? Which alcohols can be prepared as a singleproduct by the acid-catalyzed addition of H2O to an alkene?arrow_forward
- cis-Cyclohexane-1,2-diol can be synthesized from cyclohexene by using which reagent? a.O3 b.OsO4 c.H2SO4 d.mCPBAarrow_forwardOf the following structures, which is the most stable enol form?arrow_forwardWhich alcohols can be prepared as a single product by hydroboration– oxidation of an alkene? Which alcohols can be prepared as a single product by the acid-catalyzed addition of H2O to an alkene?arrow_forward
- What is the major organic product formed in the following reaction? A, B, C, or D?arrow_forwardDraw the products formed when each compound is treated with CH;CH,COCI, AICI3. CH(CH3)2 N(CH)2 Br CH3 CH(CH)2 a. b. C. d. е.arrow_forwardThese reagents can produce ketones with alkynes A. BH3, THF, H2O2 B. KMnO4 C. O3 D. H2SO4, H2O, HgSO4arrow_forward
- 10. Which of the following is the structure of the rearranged carbocation in the following dehydration? OH H₂SO4 A. B. C. D.arrow_forwardSeveral diamines are building blocks for the synthesis of pharmaceuticals and agro-chemicals. Show how both 1,3-propanediamine and 1,4-butanediamine can be prepared from acrylonitrile.arrow_forwardStarting with bromocyclohexane, how can each of the following compounds be prepared?arrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning