Explanation The given equation for the chemical potential, μ i , is given below. μ i = − k T ln q N i Where, • k is the constant. • T is the temperature. • q is the partition function. • N i is the total number of particles. The above equation is derived is derived from the equation of entropy, S , given below. lim T → 0 S = N k ln g 0 Where, • g 0 is the ground state degeneracy

Bundle: Physical Chemistry, 2nd + Student Solutions Manual

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ISBN: 9781285257594

Author: David W. Ball

Publisher: Cengage Learning

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Question

Chapter 17, Problem 17.34E

Interpretation Introduction

Interpretation:

The restriction on the derivation of equation 17.46 is to be stated.

Concept introduction:

The measure of the total amount of randomness or disorder of molecules of the system is known as entropy. It is denoted by S. It is an extensive property of the thermodynamic system.

Expert Solution & Answer

Chapter 17 Solutions

Bundle: Physical Chemistry, 2nd + Student Solutions Manual

Ch. 17 - Prob. 17.1E Ch. 17 - Prob. 17.2E Ch. 17 - Prob. 17.3E Ch. 17 - Prob. 17.4E Ch. 17 - Prob. 17.5E Ch. 17 - Prob. 17.6E Ch. 17 - Prob. 17.7E Ch. 17 - Prob. 17.8E Ch. 17 - Prob. 17.9E Ch. 17 - Prob. 17.10E

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The restriction on the derivation of equation 17.46 is to be stated. Concept introduction: The measure of the total amount of randomness or disorder of molecules of the system is known as entropy. It is denoted by S . It is an extensive property of the thermodynamic system.

Solution Summary: The author states that the restriction on the derivation of equation 17.46 is that more than one particle leads to the non-zero value of the entropy, S of that system.

Interpretation:

The restriction on the derivation of equation 17.46 is to be stated.

Concept introduction:

The measure of the total amount of randomness or disorder of molecules of the system is known as entropy. It is denoted by S. It is an extensive property of the thermodynamic system.

Chapter 17 Solutions

The restriction on the derivation of equation 17.46 is to be stated. Concept introduction: The measure of the total amount of randomness or disorder of molecules of the system is known as entropy. It is denoted by S . It is an extensive property of the thermodynamic system.

Solution Summary: The author states that the restriction on the derivation of equation 17.46 is that more than one particle leads to the non-zero value of the entropy, S of that system.

Interpretation: The restriction on the derivation of equation 17.46 is to be stated. Concept introduction: The measure of the total amount of randomness or disorder of molecules of the system is known as entropy. It is denoted by S. It is an extensive property of the thermodynamic system.

Chapter 17 Solutions

Interpretation:

The restriction on the derivation of equation 17.46 is to be stated.

Concept introduction:

The measure of the total amount of randomness or disorder of molecules of the system is known as entropy. It is denoted by S. It is an extensive property of the thermodynamic system.