ORG.CHEMISTRY W/ACCESS+MODEL KIT PKG
ORG.CHEMISTRY W/ACCESS+MODEL KIT PKG
5th Edition
ISBN: 9781260701128
Author: SMITH
Publisher: MCG
bartleby

Concept explainers

bartleby

Videos

Textbook Question
Book Icon
Chapter 17, Problem 17.53P

How many 13 C NMR signals does each compound exhibit?

a. Chapter 17, Problem 17.53P, 17.53 How many  signals does each compound exhibit?
a. 	b.	c. 	d. 
 , example  1 bChapter 17, Problem 17.53P, 17.53 How many  signals does each compound exhibit?
a. 	b.	c. 	d. 
 , example  2. c. Chapter 17, Problem 17.53P, 17.53 How many  signals does each compound exhibit?
a. 	b.	c. 	d. 
 , example  3 d. Chapter 17, Problem 17.53P, 17.53 How many  signals does each compound exhibit?
a. 	b.	c. 	d. 
 , example  4

Expert Solution
Check Mark
Interpretation Introduction

(a)

Interpretation: The number of 13CNMR signals exhibited by the given compound is to be predicted.

Concept introduction: The 13CNMR spectroscopy is an important tool for the elucidation of organic structures of molecules. The physical basis for it is same as for 1HNMR. 13CNMR spectrum is comparatively easier to analyze than 1HNMR. Each type of carbon atom appears as one signal in 13CNMR spectrum.

Answer to Problem 17.53P

The number of 13CNMR signals exhibited by the given compound is five.

Explanation of Solution

The 13CNMR spectroscopy is an important tool for the elucidation of organic structures of molecules. The physical basis for it is same as for 1HNMR. 13CNMR spectrum is comparatively easier to analyze than 1HNMR. Each type of carbon atom appears as one signal in 13CNMR spectrum.

The given compound contains five different types of carbon atoms as follows.

ORG.CHEMISTRY W/ACCESS+MODEL KIT PKG, Chapter 17, Problem 17.53P , additional homework tip  1

Figure 1

Thus, the number of 13CNMR signals exhibited by the given compound is five.

Conclusion

The number of 13CNMR signals exhibited by the given compound is five.

Expert Solution
Check Mark
Interpretation Introduction

(b)

Interpretation: The number of 13CNMR signals exhibited by the given compound is to be predicted.

Concept introduction: The 13CNMR spectroscopy is an important tool for the elucidation of organic structures of molecules. The physical basis for it is same as for 1HNMR. 13CNMR spectrum is comparatively easier to analyze than 1HNMR. Each type of carbon atom appears as one signal in 13CNMR spectrum.

Answer to Problem 17.53P

The number of 13CNMR signals exhibited by the given compound is nine.

Explanation of Solution

The 13CNMR spectroscopy is an important tool for the elucidation of organic structures of molecules. The physical basis for it is same as for 1HNMR. 13CNMR spectrum is comparatively easier to analyze than 1HNMR. Each type of carbon atom appears as one signal in 13CNMR spectrum.

The given compound contains nine different types of carbon atoms as follows.

ORG.CHEMISTRY W/ACCESS+MODEL KIT PKG, Chapter 17, Problem 17.53P , additional homework tip  2

Figure 2

Thus, the number of 13CNMR signals exhibited by the given compound is nine.

Conclusion

The number of 13CNMR signals exhibited by the given compound is nine.

Expert Solution
Check Mark
Interpretation Introduction

(c)

Interpretation: The number of 13CNMR signals exhibited by the given compound is to be predicted.

Concept introduction: The 13CNMR spectroscopy is an important tool for the elucidation of organic structures of molecules. The physical basis for it is same as for 1HNMR. 13CNMR spectrum is comparatively easier to analyze than 1HNMR. Each type of carbon atom appears as one signal in 13CNMR spectrum.

Answer to Problem 17.53P

The number of 13CNMR signals exhibited by the given compound is three.

Explanation of Solution

The 13CNMR spectroscopy is an important tool for the elucidation of organic structures of molecules. The physical basis for it is same as for 1HNMR. 13CNMR spectrum is comparatively easier to analyze than 1HNMR. Each type of carbon atom appears as one signal in 13CNMR spectrum.

The given compound contains three different types of carbon atoms as follows.

ORG.CHEMISTRY W/ACCESS+MODEL KIT PKG, Chapter 17, Problem 17.53P , additional homework tip  3

Figure 3

Thus, the number of 13CNMR signals exhibited by the given compound is three.

Conclusion

The number of 13CNMR signals exhibited by the given compound is three.

Expert Solution
Check Mark
Interpretation Introduction

(d)

Interpretation: The number of 13CNMR signals exhibited by the given compound is to be predicted.

Concept introduction: The 13CNMR spectroscopy is an important tool for the elucidation of organic structures of molecules. The physical basis for it is same as for 1HNMR. 13CNMR spectrum is comparatively easier to analyze than 1HNMR. Each type of carbon atom appears as one signal in 13CNMR spectrum.

Answer to Problem 17.53P

The number of 13CNMR signals exhibited by the given compound is four.

Explanation of Solution

The 13CNMR spectroscopy is an important tool for the elucidation of organic structures of molecules. The physical basis for it is same as for 1HNMR. 13CNMR spectrum is comparatively easier to analyze than 1HNMR. Each type of carbon atom appears as one signal in 13CNMR spectrum.

The given compound contains four different types of carbon atoms as follows.

ORG.CHEMISTRY W/ACCESS+MODEL KIT PKG, Chapter 17, Problem 17.53P , additional homework tip  4

Figure 4

Thus, the number of 13CNMR signals exhibited by the given compound is four.

Conclusion

The number of 13CNMR signals exhibited by the given compound is four.

Want to see more full solutions like this?

Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!
Students have asked these similar questions
How many 1H NMR signals does each compound show?
(a) How many 1H NMR signals does each compound show? (b) Into how many peaks is each signal split?
How many 1H NMR Signals?

Chapter 17 Solutions

ORG.CHEMISTRY W/ACCESS+MODEL KIT PKG

Ch. 17 - Prob. 17.11PCh. 17 - Prob. 17.12PCh. 17 - Prob. 17.13PCh. 17 - Problem 17.14 Januvia, the trade name for...Ch. 17 - Prob. 17.15PCh. 17 - Problem 17.16 Rank the following compounds in...Ch. 17 - Problem 17.17 Draw the seven resonance structures...Ch. 17 - Prob. 17.18PCh. 17 - Prob. 17.19PCh. 17 - Prob. 17.20PCh. 17 - Prob. 17.21PCh. 17 - Problem 17.22 How many NMR signals does ...Ch. 17 - 17.23 Name each compound and state how many lines...Ch. 17 - Prob. 17.24PCh. 17 - Prob. 17.25PCh. 17 - Prob. 17.26PCh. 17 - 17.27 Give the IUPAC name for each compounds. a....Ch. 17 - 17.28 Draw a structure corresponding to each...Ch. 17 - 17.29 a. Draw the 14 constitutional isomers of...Ch. 17 - Prob. 17.30PCh. 17 - Prob. 17.31PCh. 17 - Prob. 17.32PCh. 17 - 17.33 Label each compound as aromatic,...Ch. 17 - Prob. 17.34PCh. 17 - 17.35 Pentalene, azulene, and heptalene are...Ch. 17 - 17.36 The purine heterocycle occurs commonly in...Ch. 17 - Prob. 17.37PCh. 17 - 17.38 How many electrons does C contain? How...Ch. 17 - Prob. 17.39PCh. 17 - 17.40 Explain the observed rate of reactivity of...Ch. 17 - 17.41 Draw a stepwise mechanism for the following...Ch. 17 - Prob. 17.42PCh. 17 - 17.43 Draw additional resonance structures for...Ch. 17 - Prob. 17.44PCh. 17 - Prob. 17.45PCh. 17 - 17.46 Which compound in each pair is the stronger...Ch. 17 - 17.47 Treatment of indene with forms its...Ch. 17 - Prob. 17.48PCh. 17 - 17.49 Draw the conjugate bases of pyrrole and...Ch. 17 - 17.50 a. Explain why protonation of pyrrole occurs...Ch. 17 - Prob. 17.51PCh. 17 - Prob. 17.52PCh. 17 - 17.53 How many signals does each compound...Ch. 17 - 17.54 Which of the diethylbenzene isomers (ortho,...Ch. 17 - 17.55 Propose a structure consistent with each...Ch. 17 - 17.56 Propose a structure consistent with each...Ch. 17 - 17.57 Thymol (molecular formula ) is the major...Ch. 17 - 17.58 You have a sample of a compound of molecular...Ch. 17 - 17.59 Explain why tetrahydrofuran has a higher...Ch. 17 - 17.60 Rizatriptan (trade name Maxalt) is a...Ch. 17 - 17.61 Zolpidem (trade name Ambien) promotes the...Ch. 17 - 17.62 Answer the following questions about...Ch. 17 - 17.63 Stanozolol is an anabolic steroid that...Ch. 17 - Prob. 17.64PCh. 17 - 17.65 Use the observed data to decide whether C...Ch. 17 - Prob. 17.66PCh. 17 - Prob. 17.67PCh. 17 - Prob. 17.68PCh. 17 - 17.69 Although benzene itself absorbs at in its ...
Knowledge Booster
Background pattern image
Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Recommended textbooks for you
Text book image
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Text book image
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Text book image
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Text book image
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Text book image
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Text book image
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY
NMR Spectroscopy; Author: Professor Dave Explains;https://www.youtube.com/watch?v=SBir5wUS3Bo;License: Standard YouTube License, CC-BY