Organic Chemistry, Binder Ready Version
Organic Chemistry, Binder Ready Version
2nd Edition
ISBN: 9781118454312
Author: David R. Klein
Publisher: WILEY
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Chapter 17, Problem 41PP
Interpretation Introduction

Interpretation:

The given dienophiles should be ranked in terms of their reactivity (least to most) for Diels-Alder reaction.

Concept introduction:

  • Diels-Alder reaction is a [4+2] cycloaddition reaction, in which a π-system having four atoms (diene) and a π-system having two atoms (dienophile) are undergoing in cycloaddition reaction and producing a substituted cyclohexene.
  • The reactivity of dienophiles are depending upon the substituents attached to it, the electron-withdrawing substituent such as carbonyl groups activate the dienophile for Diels-Alder reaction by making the dienophiles more reactive to dienes.

To rank: the given dienophiles in terms of reactivity (least to most) for Diels-Alder reaction.

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Chapter 17 Solutions

Organic Chemistry, Binder Ready Version

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