Organic Chemistry (Looseleaf) - With Access
Organic Chemistry (Looseleaf) - With Access
7th Edition
ISBN: 9780134325774
Author: Bruice
Publisher: PEARSON
bartleby

Concept explainers

Question
Book Icon
Chapter 17, Problem 71P

a.

Interpretation Introduction

Interpretation:

Write the three different sets of reagents (each set containing of a carbonyl compound and Grignard reagent that would be used to prepare each of the following tertiary alcohols.

Concept introduction:

So many number of reactions are involved in the Carbonyl group. The carbonyl group is electrophilic nature, therefore it undergoes nucleophilic addition reactions.

For example carbonyl group reacts with Grignard reagent, it undergoes nucleophilic addition reactions and form unstable tetrahedral intermediate by the elimination of leaving group.

Addition of hydrogen ion to the carbonyl carbon to form alkoxide ion.  By the protonation of alkoxide ion forms alcohol.

b.

Interpretation Introduction

Interpretation:

Write the three different sets of reagents (each set containing of a carbonyl compound and Grignard reagent that would be used to prepare each o the following tertiary alcohols.

Concept introduction:

So many number of reactions are involved in the Carbonyl group.  The carbonyl group is electrophilic nature, therefore it undergoes nucleophilic addition reactions.

For example carbonyl group reacts with Grignard reagent, it undergoes nucleophilic addition reactions and form unstable tetrahedral intermediate by the elimination of leaving group.

Addition of hydrogen ion to the carbonyl carbon to form alkoxide ion. By the protonation of alkoxide ion forms alcohol.

Blurred answer
Students have asked these similar questions
List three different sets of reagents (each set consisting of a carbonyl compound and a Grignard reagent) that could be used to prepare each of thefollowing tertiary alcohols:
What esters and Grignard reagent can be used to prepare the following alcohols?
Draw the structures of the Grignard reagent and carbonyl compound necessary to make the following alcohol via a grignard reaction.

Chapter 17 Solutions

Organic Chemistry (Looseleaf) - With Access

Ch. 17.4 - Show how the following compounds can be...Ch. 17.5 - Prob. 13PCh. 17.5 - Prob. 14PCh. 17.6 - In the mechanism for cyanohydrin formation, why is...Ch. 17.6 - Prob. 16PCh. 17.6 - Prob. 17PCh. 17.6 - Show two ways to convert an alkyl halide into a...Ch. 17.7 - Prob. 20PCh. 17.7 - Prob. 21PCh. 17.7 - Prob. 22PCh. 17.7 - Prob. 23PCh. 17.8 - Prob. 24PCh. 17.9 - What reducing agents should be used to obtain the...Ch. 17.9 - Prob. 26PCh. 17.9 - Prob. 27PCh. 17.10 - Prob. 28PCh. 17.10 - Prob. 29PCh. 17.10 - Prob. 30PCh. 17.10 - The pKa of protonated acetone is about 7.5. and...Ch. 17.10 - Prob. 32PCh. 17.10 - Prob. 33PCh. 17.10 - Prob. 34PCh. 17.10 - Excess ammonia must be used when a primary amine...Ch. 17.10 - The compounds commonly known as amino acids are...Ch. 17.11 - Hydration of an aldehyde is also catalyzed by...Ch. 17.11 - Which ketone forms the most hydrate in an aqueous...Ch. 17.11 - When trichloroacetaldehyde is dissolved in water,...Ch. 17.12 - Which of the following are a. hermiacetals? b....Ch. 17.12 - Prob. 41PCh. 17.12 - Explain why an acetal can be isolated but most...Ch. 17.13 - Prob. 43PCh. 17.13 - Prob. 44PCh. 17.13 - What products would be formed from the proceedings...Ch. 17.13 - a. In a six-step synthesis, what is the yield of...Ch. 17.13 - Show how each of the following compounds could be...Ch. 17.15 - Prob. 48PCh. 17.17 - Prob. 50PCh. 17.18 - Prob. 51PCh. 17.19 - Prob. 52PCh. 17 - Draw the structure for each of the following: a....Ch. 17 - Prob. 54PCh. 17 - Prob. 55PCh. 17 - a. Show the reagents required to form the primary...Ch. 17 - Prob. 57PCh. 17 - Using cyclohexanone as the starting material,...Ch. 17 - Prob. 59PCh. 17 - 60. Show how each of the following compounds could...Ch. 17 - Fill in the boxes:Ch. 17 - Prob. 62PCh. 17 - Identify A through O:Ch. 17 - Prob. 64PCh. 17 - Prob. 65PCh. 17 - Prob. 66PCh. 17 - How many signals would the product of the...Ch. 17 - Prob. 68PCh. 17 - Prob. 69PCh. 17 - Prob. 70PCh. 17 - Prob. 71PCh. 17 - Prob. 72PCh. 17 - Prob. 73PCh. 17 - Prob. 74PCh. 17 - Prob. 75PCh. 17 - Prob. 76PCh. 17 - Prob. 77PCh. 17 - A compound gives the following IR spectrum. Upon...Ch. 17 - a. Propose a mechanism for the following reaction:...Ch. 17 - Prob. 80PCh. 17 - Prob. 81PCh. 17 - Prob. 82PCh. 17 - Prob. 83PCh. 17 - Prob. 84PCh. 17 - In the presence of an acid catalyst, acetaldehyde...Ch. 17 - Prob. 86PCh. 17 - Prob. 87PCh. 17 - Prob. 88PCh. 17 - A compound reacts with methylmagnesium bromide...Ch. 17 - Show how each of the following compounds can be...Ch. 17 - Prob. 91PCh. 17 - Prob. 92PCh. 17 - The pKa values of the carboxylic acid groups of...Ch. 17 - The Baylis-Hillman reaction is a DABCO...Ch. 17 - Prob. 95PCh. 17 - Prob. 96P
Knowledge Booster
Background pattern image
Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
Text book image
EBK A SMALL SCALE APPROACH TO ORGANIC L
Chemistry
ISBN:9781305446021
Author:Lampman
Publisher:CENGAGE LEARNING - CONSIGNMENT