EBK GENERAL CHEMISTRY
11th Edition
ISBN: 9780134419022
Author: Bissonnette
Publisher: PEARSON CUSTOM PUB.(CONSIGNMENT)
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Textbook Question
Chapter 17, Problem 75IAE
At times a salt of a we base can be titrated by a strong base. Use apporopriate data from the text to sketch a titration curve for the titration of 10.00 mL of 0.0500 M
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Hh.87.
Imagine the diagram shown below is a 'good representation' of a titration curve for the titration of
20.0 mL of 0.10 M Na4A with 0.15 M HCI. Use this information to fill in the blanks below.
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A
D
pH
F
H
Volume of HCI (mL)
5:50 1
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Determine the mass of solid NaCH;COO that
must be dissolved in an existing 500.0 mL
solution of 0.200 M CH3COOH to form a buffer
with a pH equal to 5.00. The value of Ka for
CH-COОH is 1.8 х 10-5.
1
2
Let x represent the original concentration of
CH;COO in the water. Based on the given
values, set up the ICE table in order to
determine the unknown.
CH3COOH+ H20(1) =H;O*(aq) +CH3COO-(a
Initial (M)
Change (M)
Equilibrium
(M)
5 RESET
0.200
5.00
-5.00
1.0 x 10-9
-1.0 × 10-9
1.0 x 10-5
-1.0 x 10-5
1.8 x 10-5
-1.8 x 10-5
х+ 5.00
x - 5.00
x + 1.0 × 10-9
х - 1.0 х 10-9
1.0 x 10-5
x - 1.0 × 10-5
x + 1.8 × 10-5
х - 1.8 х 10-5
Chapter 17 Solutions
EBK GENERAL CHEMISTRY
Ch. 17 - For a solution that e 0.275M CH2CH2 COOH...Ch. 17 - For a solution that is 0164 U NH2 and 0.102MNH4Cl...Ch. 17 - Prob. 3ECh. 17 - In Example 16-4, we calculated the percent...Ch. 17 - Calculate [H2OOH-] in a solution that is (a)...Ch. 17 - Calculate [OH-] in a solution that is (a) 0.0062 U...Ch. 17 - What concentration of formate ion, [HCOO-], should...Ch. 17 - What concentration of ammonia. [NH2] , should be...Ch. 17 - Calculate the pH of a buffer that is a. 0.012 M...Ch. 17 - Lactic acid, CH2CH(OH)COOH , is found in sour...
Ch. 17 - Indicate which of the following aqueous solutions...Ch. 17 - The H2PO4-HPO4- combination plays a role in...Ch. 17 - What is the pH of a solution Obtained by adding...Ch. 17 - What the pH of solution prepared by dissolving...Ch. 17 - You wish to prepare a buffer solution w pH = 945...Ch. 17 - You prepare a buffer solution by dissolving 2.00 g...Ch. 17 - If 0.55 ml. of 12 M HCI is added to 0100 L of the...Ch. 17 - If 0.35 mL of 15 P.4 NH is added to 0750 L of the...Ch. 17 - You are asked to prepare e buffer solution why a...Ch. 17 - You are asked to reduce the pH of the 03001 of...Ch. 17 - Given 1.00 L of a solution that is 0.100 hl...Ch. 17 - Given 125mL of a solution that is 0.0500 M CH2NH2...Ch. 17 - A solution of volume 750 mL contars 15.5 mmol...Ch. 17 - A solution of volume 0.500 L contains 1.68 g NH...Ch. 17 - A handbook lets various procedures for preparing...Ch. 17 - An acetic acid-sodium acetate buffer can be...Ch. 17 - A handbook lists the following data: Which of...Ch. 17 - With reference to the indicators listed in...Ch. 17 - In use of acid—base indicators, a. Why is it...Ch. 17 - The indicator methyl red has a pKHIN=4.95 . It...Ch. 17 - Phenol red indicator changes from yellow to red in...Ch. 17 - Thymol blue indicator has two pH ranges. It...Ch. 17 - In the titration of 10.00 mL of 0.04050 M HCI with...Ch. 17 - Solution (a) is 1000 mL of 0.100 N HCI and...Ch. 17 - A 25.00 mL sample of H2PO4(aq) requires 31.15 mL...Ch. 17 - A 2000 ml sample of H2PO4(aq) requires 18.67 mL...Ch. 17 - Two aqueous solutions are mixed 50.0 mL of 0.0150M...Ch. 17 - Two solutions are mixed 100.0 mL of HCI(aq) with...Ch. 17 - Calculate the pH at the points in the titration of...Ch. 17 - Calculate the pH at the points m the titration...Ch. 17 - Calculate the pH at the points in the titration of...Ch. 17 - Calculate the pH at the points lithe titration of...Ch. 17 - Explain why the volume of 0.100 M NeOH required to...Ch. 17 - Explain whether the equivalence point of each of...Ch. 17 - Sketch the titration curves of the following...Ch. 17 - Determine the blowing characteristeristics of the...Ch. 17 - In the titration of 2000 mL of 0175 M NaOH,...Ch. 17 - In the titration of 25.00mL of 0.100M CH2COOH ,...Ch. 17 - Sketch a titration curve (pH versus mL of titrant)...Ch. 17 - Sketch a titration curve (pH versus mL of titrant)...Ch. 17 - For me titration of 25.00 mL of 0.100M NaOH with...Ch. 17 - For the titration of 25.00 mL 0.100M NH2 with...Ch. 17 - Is a solution that is 0.10 M Na2S(aq) likely to be...Ch. 17 - Is a solution of sodium dihydrogen citrate,...Ch. 17 - Sodium phosphate Na2PO4 , is made commecie1y by...Ch. 17 - Both sodium hydrogen carbonate (sodium...Ch. 17 - The pH of a solution of 19.5 g of malonic acid in...Ch. 17 - The ionization constants of ortho-phthalic acid...Ch. 17 - What stoichimetric concentration of the indicated...Ch. 17 - What stocichiometric concentration of the...Ch. 17 - Using appropriate equilibrium constants but...Ch. 17 - Prob. 62ECh. 17 - Sodium hydrogen sulfate NaHSO4 , an acidic salt...Ch. 17 - You are given 250.0mL of 0.100M CH3 CH2 COOH...Ch. 17 - Even though the carbonic acid-hydrogen carbonate...Ch. 17 - Thymol blue in its acid range is not a suitable...Ch. 17 - Rather than calculate the pH for different volumes...Ch. 17 - Use the method of Exercise 67 to determine the...Ch. 17 - A buffer solution can be prepared by starting with...Ch. 17 - You are asked to prepare a KH2PO4-Na2HPO2 solution...Ch. 17 - You are asked to bring the pH of 0.500 L of 0.500...Ch. 17 - Because an acid-base indicator a weak acid, I can...Ch. 17 - The neutralization of NaOH 2by HCl is represented...Ch. 17 - The titration of a weak acid by a weak base a not...Ch. 17 - At times a salt of a we base can be titrated by a...Ch. 17 - Sulfuric acid is a diprotic acid, strong in the...Ch. 17 - Carbonic acid is a weak diprotic acid (H2CO2) with...Ch. 17 - Prob. 78IAECh. 17 - Complete the derivation of equation (17.10)...Ch. 17 - Explain why equation (17.10) fads when applied to...Ch. 17 - Prob. 81IAECh. 17 - Prob. 82IAECh. 17 - Prob. 83IAECh. 17 - Prob. 84IAECh. 17 - Prob. 85IAECh. 17 - Calculate the pH of a solution that is 0.050 U...Ch. 17 - Prob. 87IAECh. 17 - The Henderson-Hasselbalch equation can be written...Ch. 17 - The pH of ocean water depends on the amount of...Ch. 17 - A sample of water contains 23.0 g L1 of Na+ (aq),...Ch. 17 - Prob. 91IAECh. 17 - Prob. 92FPCh. 17 - In some cases the titration curve for a mature of...Ch. 17 - Amino acids contain both an acidic carboxylic acid...Ch. 17 - In your own words, define or explain the following...Ch. 17 - Prob. 96SAECh. 17 - Explain the important distinctions between each...Ch. 17 - Write equations to show how each of the following...Ch. 17 - Sketch the titration curves that you would expect...Ch. 17 - A 2500-mL sample of 0.0100M C8C5COOH (Kg=6.3103)...Ch. 17 - Prob. 101SAECh. 17 - Prob. 102SAECh. 17 - Prob. 103SAECh. 17 - Prob. 104SAECh. 17 - Prob. 105SAECh. 17 - Calculate the pH of a 0.5 M solution of Ca(HSe)2...Ch. 17 - Prob. 107SAECh. 17 - Prob. 108SAECh. 17 - Prob. 109SAECh. 17 - Prob. 110SAECh. 17 - Prob. 111SAE
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- A bottle of concentrated hydroiodic acid is 57% HI by weight and has a density of 1.70 g/mL. A solution of this strong and corrosive acid is made by adding exactly 10.0 mL to some water and diluting to 250.0 mL. If the information on the label is correct, what volume of 0.988 M NaOH is needed to neutralize the HI solution? Suggest an indicator for the titration.arrow_forwardDefine a buffer solution. What makes up a buffer solution? How do buffers absorb added H+ or OH with little pH change? Is it necessary that the concentrations of the weak acid and the weak base in a buffered solution be equal? Explain. What is the pH of a buffer when the weak acid and conjugate base concentrations are equal? A buffer generally contains a weak acid and its weak conjugate base, or a weak base and its weak conjugate acid, in water. You can solve for the pH by setting up the equilibrium problem using the K.a reaction of the weak acid or the Kb reaction of the conjugate base. Both reactions give the same answer for the pH of the solution. Explain. A third method that can be used to solve for the pH of a buffet solution is the HendersonHasselbalch equation. What is the HendersonHasselbalch equation? What assumptions are made when using this equation?arrow_forwardUnder what circumstances, if any, does a sample of solid AgCl completely dissolve in pure water?arrow_forward
- Weak base B has a pKb of 6.78 and weak acid HA has a pKa of 5.12. a Which is the stronger base, B or A? b Which is the stronger acid, HA or BH+? c Consider the following reaction: B(aq)+HA(aq)BH+(aq)+A(aq) Based on the information about the acid/base strengths for the species in this reaction, is this reaction favored to proceed more to the right or more to the left? Why? d An aqueous solution is made in which the concentration of weak base B is one half the concentration of its acidic salt, BHCl, where BH+ is the conjugate weak add of B. Calculate the pH of the solution. e An aqueous solution is made in which the concentration of weak acid HA twice the concentration of the sodium salt of the weak acid, NaA. Calculate the pH of the solution. f Assume the conjugate pairs B/BH+ and HA/A are capable of being used as color-based end point indicators in acidbase titrations, where B is the base form indicator and BH is the acid form indicator, and HA is the acid form indicator and A is the base form indicator. Select the indicator pair that would be best to use in each of the following titrations: (1) Titration of a strong acid with a strong base. (i) B/BH+ (ii) HA/A (2) Titration of a weak base with a strong acid. (i) B/BH+ (ii) HA/Aarrow_forwardSketch two pH curves, one for the titration of a weak acid with a strong base and one for a strong acid with a strong base. How are they similar? How are they different? Account for the similarities and the differences.arrow_forwardSketch a pH curve for the titration of a weak acid (HA) with a strong base (NaOH). List the major species, and explain how you would go about calculating the pH of the solution at various points, including the halfway point and the equivalence point.arrow_forward
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Acid-Base Titration | Acids, Bases & Alkalis | Chemistry | FuseSchool; Author: FuseSchool - Global Education;https://www.youtube.com/watch?v=yFqx6_Y6c2M;License: Standard YouTube License, CC-BY