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(a)
Interpretation: The Wittig reagent and carbonyl compound that are needed to prepare the given
Concept introduction: One should follow the two steps retrosynthesis to find out the starting materials that are needed to prepare the given alkene. The first step is cleaving of
(b)
Interpretation: The Wittig reagent and carbonyl compound that are needed to prepare the given alkene are to be predicted, and the preferred route is to be identified, if any.
Concept introduction: One should follow the two steps retrosynthesis to find out the starting materials that are needed to prepare the given alkene. The first step is cleaving of
(c)
Interpretation: The Wittig reagent and carbonyl compound that are needed to prepare the given alkene are to be predicted, and the preferred route is to be identified, if any.
Concept introduction: One should follow the two steps retrosynthesis to find out the starting materials that are needed to prepare the given alkene. The first step is cleaving of
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Chapter 18 Solutions
ORGANIC CHEMISTRY (LOOSELEAF)
- What Wittig reagent and carbonyl compound are needed to prepare each alkene? When two routes are possible, indicate which route, if any, is preferred.arrow_forwardDraw the products formed when each diene is treated with one equivalent of HCI. a. b. d.arrow_forwardWhich compound in each pair has the higher boiling point? Он a. or b. or A.arrow_forward
- Draw a stepwise mechanism for the sulfonation of an alkyl benzene such as A to form a substituted benzenesulfonic acid B. Treatment of B with base forms a sodium salt C that can be used as a synthetic detergent to clean away dirtarrow_forwardCompound that is most easily hydrolyzed by acid in water `NH A. В. F C. D.arrow_forwardDraw a stepwise mechanism for the following reaction that forms ether D. D can be converted to the antidepressant uoxetine (trade name Prozac) in a single step.arrow_forward
- identify the reagents needed to come up with the compounds given. a. b. c. d. e. f. g. h. i.arrow_forwardDraw a stepwise mechanism for the following reaction that forms ether D. D can be converted to the antidepressant fluoxetine (trade name Prozac) in a single step.arrow_forwardLabel each compound as aromatic, antiaromatic, or not aromatic. Assume all completely conjugated rings are planar. Å a. b. C. d.arrow_forward
- Draw a stepwise mechanism for the sulfonation of an alkyl benzene such as A to form asubstituted benzenesulfonic acid B. Treatment of B with base forms a sodium salt C that canbe used as a synthetic detergent to clean away dirt.arrow_forward2. How many different ß-hydroxyaldehydes and ß-hydroxyketones, including constitutional isomers and stereoisomers, are formed upon treatment of a mixture of acetone and benzaldehyde with base? a. b. 2 c. 3 d. 4arrow_forwardSynthesize each compound from cyclohexanol using any other organic or inorganic compounds. CH,OH a. g. (Each cyclohexane ring must come from cyclohexanol.) COOH b. d. h. сно CHs (Each cyclohexane ring must come from cyclohexanol.)arrow_forward
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