Concept explainers
(a)
Interpretation: A stepwise mechanism for the formation of MOM ether from cyclohexanol is to be stated.
Concept introduction: An alkoxide salt is required to prepare ether. The alkoxide salts are prepared from alcohols through the Bronsted-Lowry acid-base reaction. In this reaction,
(b)
Interpretation: The
Concept introduction: Acetals are the groups in which carbon atom is bonded with two
(c)
Interpretation: The other products that are formed besides cyclohexanol from the aqueous hydrolysis of the MOM ether are to be predicted, and a stepwise mechanism for the formation of each product is to be drawn.
Concept introduction: Acetals are the groups in which carbon atom is bonded with two
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ORGANIC CHEMISTRY W/CONNECT & ALEKS
- 1. Write the structure of the major organic product for reactions a, b and e? H₂C b. H₂c- CH, CH₂ Cold KMnO, OH A KMnO, H c. CH3CH₂-CH=CH-CH₂CH3 + H₂SO4 →arrow_forward5. Describe an efficient synthesis of 1-methyl-1-cyclohexanol from cyclohexanol. Show the structure of the reagents, reactants and products from each step. Cyclohexanol -------> -----> 1-methyl-1-cyclohexanolarrow_forward4. Which of the following reactions can be used to prepare 11-diphenyl-1-propanol? OH I. II. III. CH₂CH₂C снене-ось CH₂CH₂C -OCH3 PO 1. 2. H₂00 1. ? 2. H30Ⓡ MgBr MgBr 1. CH3CH₂ MgBr 2. H30arrow_forward
- 10. Write chemical equations for the reaction of ethyl propanoate with each reagent below. a) LIAIH4/ H3O* b) NH3 d) NaOH c) C2H5NH2arrow_forwardShow the mecanism for the protection of the diol by forming an acetal with acetone. Remember this reaction occurs in an acidic environment CH3 CH3 с H D CH,COCH; tocamobor CH3 Н.С. OH B 10 11arrow_forwardIn an alkoxymercuration-demercuration reaction, an alcohol adds to an alkene double bond. We already have the alkene starting material, so we must prepare the alcohol starting material. Draw the product of the following acid-catalyzed hydration reaction. 1) BH, THF 2) H,O2, NaOH II N. Close NV OH H,C CI Br P. 1.arrow_forward
- 21. Provide the reagents necessary to carry out the following reaction. following conversion. CN 22. Provide the reactant for the NH₂ Ph3P=CHCH3 A. B. ܘܘܣ C. D. cyclohexanone cyclohexanecarbaldehyde cyclohexylpropanone 3-cyclohexylpropanalarrow_forwardA synthetic organic molecule, G, which contains both aldehyde and ether functional groups, is subjected to a series of reactions in a multi-step synthesis pathway. In the first step, G undergoes a Wittig reaction, leading to the formation of an alkene, H. Subsequently, H is treated with an ozone (O3) reagent followed by a reducing agent in an ozonolysis reaction, resulting in the formation of two different products, I and J. Considering the functional groups present in G and the nature of the reactions involved, what are the most probable structures or functional groups present in products I and J? A. I contains a carboxylic acid group, and J contains an aldehyde group. B. I contains a ketone group, and J contains an alcohol group. C. I and J both contain aldehyde groups. D. I contains an ester group, and J contains a ketone group. Don't use chat gpt.arrow_forwardWhich reagent(s) will complete the following reaction? NH2 1. NaNO2, H2S04 2. D3PO2 1. HNO3 2. D20 1. NaNO2, D2SO4 2. H3PO2 1. NaNO2, H2SO4 2. LIAID4 D30* II II IV V O a. I O b. II О с. Ш O d. IV О е. Varrow_forward
- Which of these alcohols is most likely NOT to have a rearranged alkyl halide as a product with HBr? CH3 но H3C. CH3 H,C, H3C H3C CH3 OH OH OH 1 3 Select one: а. 1 ОБ. 2 О с. 3 d. 4arrow_forward#16g. Provide the missing reactants, reagents, or products for the following reaction sequences below.arrow_forwardDraw the skeletal structures of all the final organic products formed when phenol (C6H5OH) is treated with the set of reagents given below: OH CH3CH2Cl Br. 2 AICI hvarrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning