The structure and stereochemistry of the alcohol that would result if 1, 2-epoxycyclohexane was reduced with Lithium aluminium deuteride are to be shown. Concept introduction: The nucleophilic attack of the deuderide ion on the epoxide will yield an alcohol. The attack takes places by S N 2 like backside attack. When both epoxide carbons are either primary or secondary the nucleophilic attack mainly occurs at the less highly substituted side. When one of the epoxide carbons is tertiary, the nucleophilic attack mainly occurs at the more highly substituted side. To give: The structure and stereochemistry of the alcohol that would result if 1, 2-epoxycyclohexane was reduced with Lithium aluminium deuteride.

Question

What is the products you expect from oxidation of 2-Hexanol with CrO3 and H3O+?

Answer 1

Question

Chapter 18.SE, Problem 52AP

Interpretation Introduction

Interpretation:

The structure and stereochemistry of the alcohol that would result if 1, 2-epoxycyclohexane was reduced with Lithium aluminium deuteride are to be shown.

Concept introduction:

The nucleophilic attack of the deuderide ion on the epoxide will yield an alcohol. The attack takes places by S_N² like backside attack. When both epoxide carbons are either primary or secondary the nucleophilic attack mainly occurs at the less highly substituted side. When one of the epoxide carbons is tertiary, the nucleophilic attack mainly occurs at the more highly substituted side.

To give:

The structure and stereochemistry of the alcohol that would result if 1, 2-epoxycyclohexane was reduced with Lithium aluminium deuteride.

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Answer 2

Question

Chapter 18.SE, Problem 52AP

Interpretation Introduction

Interpretation:

The structure and stereochemistry of the alcohol that would result if 1, 2-epoxycyclohexane was reduced with Lithium aluminium deuteride are to be shown.

Concept introduction:

The nucleophilic attack of the deuderide ion on the epoxide will yield an alcohol. The attack takes places by S_N² like backside attack. When both epoxide carbons are either primary or secondary the nucleophilic attack mainly occurs at the less highly substituted side. When one of the epoxide carbons is tertiary, the nucleophilic attack mainly occurs at the more highly substituted side.

To give:

The structure and stereochemistry of the alcohol that would result if 1, 2-epoxycyclohexane was reduced with Lithium aluminium deuteride.

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Answer 3

Question

Chapter 18.SE, Problem 52AP

Interpretation Introduction

Interpretation:

The structure and stereochemistry of the alcohol that would result if 1, 2-epoxycyclohexane was reduced with Lithium aluminium deuteride are to be shown.

Concept introduction:

The nucleophilic attack of the deuderide ion on the epoxide will yield an alcohol. The attack takes places by S_N² like backside attack. When both epoxide carbons are either primary or secondary the nucleophilic attack mainly occurs at the less highly substituted side. When one of the epoxide carbons is tertiary, the nucleophilic attack mainly occurs at the more highly substituted side.

To give:

The structure and stereochemistry of the alcohol that would result if 1, 2-epoxycyclohexane was reduced with Lithium aluminium deuteride.

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Answer 4

Question

Chapter 18.SE, Problem 52AP

Interpretation Introduction

Interpretation:

The structure and stereochemistry of the alcohol that would result if 1, 2-epoxycyclohexane was reduced with Lithium aluminium deuteride are to be shown.

Concept introduction:

The nucleophilic attack of the deuderide ion on the epoxide will yield an alcohol. The attack takes places by S_N² like backside attack. When both epoxide carbons are either primary or secondary the nucleophilic attack mainly occurs at the less highly substituted side. When one of the epoxide carbons is tertiary, the nucleophilic attack mainly occurs at the more highly substituted side.

To give:

The structure and stereochemistry of the alcohol that would result if 1, 2-epoxycyclohexane was reduced with Lithium aluminium deuteride.

Expert Solution & Answer

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Answer 5

Chapter 18.SE, Problem 52AP

Interpretation Introduction

Interpretation:

The structure and stereochemistry of the alcohol that would result if 1, 2-epoxycyclohexane was reduced with Lithium aluminium deuteride are to be shown.

Concept introduction:

The nucleophilic attack of the deuderide ion on the epoxide will yield an alcohol. The attack takes places by S_N² like backside attack. When both epoxide carbons are either primary or secondary the nucleophilic attack mainly occurs at the less highly substituted side. When one of the epoxide carbons is tertiary, the nucleophilic attack mainly occurs at the more highly substituted side.

To give:

The structure and stereochemistry of the alcohol that would result if 1, 2-epoxycyclohexane was reduced with Lithium aluminium deuteride.

Answer 6

Chapter 18.SE, Problem 52AP

Interpretation Introduction

Interpretation:

The structure and stereochemistry of the alcohol that would result if 1, 2-epoxycyclohexane was reduced with Lithium aluminium deuteride are to be shown.

Concept introduction:

The nucleophilic attack of the deuderide ion on the epoxide will yield an alcohol. The attack takes places by S_N² like backside attack. When both epoxide carbons are either primary or secondary the nucleophilic attack mainly occurs at the less highly substituted side. When one of the epoxide carbons is tertiary, the nucleophilic attack mainly occurs at the more highly substituted side.

To give:

The structure and stereochemistry of the alcohol that would result if 1, 2-epoxycyclohexane was reduced with Lithium aluminium deuteride.

Answer 7

Chapter 18.SE, Problem 52AP

Interpretation Introduction

Interpretation:

The structure and stereochemistry of the alcohol that would result if 1, 2-epoxycyclohexane was reduced with Lithium aluminium deuteride are to be shown.

Concept introduction:

The nucleophilic attack of the deuderide ion on the epoxide will yield an alcohol. The attack takes places by S_N² like backside attack. When both epoxide carbons are either primary or secondary the nucleophilic attack mainly occurs at the less highly substituted side. When one of the epoxide carbons is tertiary, the nucleophilic attack mainly occurs at the more highly substituted side.

To give:

The structure and stereochemistry of the alcohol that would result if 1, 2-epoxycyclohexane was reduced with Lithium aluminium deuteride.

Answer 8

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Answer 19

Ch. 18.1 - Name the following ethers:Ch. 18.2 - Why do you suppose only symmetrical ethers are...Ch. 18.2 - How would you prepare the following ethers using a...Ch. 18.2 - Review the mechanism of oxymercuration shown in...Ch. 18.2 - How would you prepare the following ethers? Use...Ch. 18.2 - Prob. 6P Ch. 18.3 - Prob. 7P Ch. 18.3 - Write the mechanism of the acid-induced cleavage...Ch. 18.3 - Why are HI and HBr more effective than HCl in...Ch. 18.4 - What product would you expect from Claisen...

Solution Summary: The author explains the structure and stereochemistry of the alcohol that would result if 1, 2-epoxycyclohexane was reduced with Lithium aluminium deuteride.

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