The synthetic procedures for the preparation of benzoic acid, labeled with 14 C by using benzene and the given compounds have to be described. Concept Introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The reaction of benzene with alkyl halide in the presence of Lewis acid results in the formation of a nucleophilic product.

Question

Want to see the full answer?

Answer 1

Question

Chapter 19, Problem 16P

Interpretation Introduction

Interpretation:

The synthetic procedures for the preparation of benzoic acid, labeled with 14C by using benzene and the given compounds have to be described.

Concept Introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction.

The reaction of benzene with alkyl halide in the presence of Lewis acid results in the formation of a nucleophilic product.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Several sulfonylureas, a class of compounds containing RSO2NHCONHR, are useful drugs as orally active replacements for injected insulin in patients with adult-onset diabetes. These drugs decrease blood glucose concentrations by stimulating b cells of the pancreas to release insulin and by increasing the sensitivity of insulin receptors in peripheral tissues to insulin stimulation. Tolbutamide is synthesized by the reaction of the sodium salt of p-toluenesulfonamide and ethyl N-butylcarbamate . Propose a mechanism for this step.

The sex pheromone of the common house fly has the molecular formula C23H46. It can be synthesized in the lab using the following synthetic sequence. Give the structures of the pheromone and the intermediates A and B. n-C13H27C≡CH + n-butyl lithium → A (C15H27Li) A + n-C8H17Br → B (C23H44) B + H2 with Lindlar catalyst → the pheromone

1. The ketone 2-heptanone has been identified as contributing to the odor of a number of dairy products, including condensed milk and cheddar cheese. Describe the synthesis of 2-heptanone from acetylene and any necessary organic and inorganic reagents. 2. Compound A has the molecular formula C14H25Br and was obtained by reaction of sodium acetylide (HC≡CNa) )with 1,12-dibromododecane. On treatment of compound A with sodium amide, it was converted to compound B (C14H24). Ozonolysis of compound B gave the diacid HO2C(CH2)12CO2H. Catalytic hydrogenation of compound B over Lindlar palladium gave compound C (C14H26), while hydrogenation over platinum gave compound D (C14H28). Sodium-ammonia reduction of compound B gave compound E (C14H26). Both C and E yielded O═CH(CH2)12CH═O on ozonolysis. Assign structures to compound A through E so as to be consistent with the observed transformations.