Chemistry: An Atoms-Focused Approach
14th Edition
ISBN: 9780393912340
Author: Thomas R. Gilbert, Rein V. Kirss, Natalie Foster
Publisher: W. W. Norton & Company
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Chemistry: An Atoms-Focused Approach
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- 5-106 The normal boiling point of hexane, C6H14, is 69°C, and that of pentane, C5H12, is 36°C. Predict which of these compounds has a higher vapor pressure at 20°C.arrow_forwardOn the basis of intermolecular attractions, explain the differences in the boiling points of n butane (1 C) and chloroethane (12 C), which have similar molar masses.arrow_forwardSilane SiH4, phosphine (PH3), and hydrogen sulfide (H2S) melt at 185 C, 133 C, and 85 C, respectively. What does this suggest about the polar character and intermolecular attractions of the three compounds?arrow_forward
- Which would you expect to have the higher fusion enthalpy, N2 or I2? Explain your choice.arrow_forwardA tank of gas at 21C has a pressure of 1.0 atm. Using the data in the table, answer the following questions. Explain your answers. a If the tank contains carbon tetrafluoride, CF4, is the liquid state also present? b If the tank contains butane, C4H20, is the liquid state also present?arrow_forwardIn each of the following groups of substances, pick the one that has the given property. Justify your answer. a. highest boiling point: HBr, Kr, or Cl2 b. highest freezing point: H2O, NaCl, or HF c. lowest vapor pressure at 25C: Cl2, Br2, or I2 d. lowest freezing point: N2, CO, or CO2 e. lowest boiling point: CH4, CH3CH3, or CH3CH2CH3 f. highest boiling point: HF, HCl, or HBr g.arrow_forward
- 5-86 Using the phase diagram of water (Figure 5-20), describe the process by which you can sublime 1 g of ice at-10°C and at 1 atm pressure to water vapor at the same temperature.arrow_forwardMethane (CH4) cannot be liquefied at room temperature, no matter how high the pressure. Propane (C3H8), another simple hydrocarbon, has a critical pressure of 42 atm and a critical temperature of 96.7 C. Can this compound be liquefied at room temperature?arrow_forward
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