CHEMISTRY FOR TODAY+OWLV2  24 MO>IP<
CHEMISTRY FOR TODAY+OWLV2 24 MO>IP<
9th Edition
ISBN: 9780357107317
Author: Seager
Publisher: CENGAGE L
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Textbook Question
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Chapter 19, Problem 19.5E

Draw structural formulas for the following amino acids, identify the chiral carbon atom in each one, and circle the four different groups attached to the chiral carbon.

a. valine

b. glutamate

c. asparagine

d. cysteine

Expert Solution
Check Mark
Interpretation Introduction

(a)

Interpretation:

The structural formula for the amino acid, valine is to be drawn. The chiral carbon atom in it is to be identified. The four different groups attached to the chiral carbon atom are to be circled.

Concept introduction:

Amino acids are organic compounds which combine sequentially to generate a protein. They are known as the building blocks of the human body. The main elements present in amino acids are carbon, nitrogen and oxygen while the side chains attached to the chiral carbon atom contain other elements.

Answer to Problem 19.5E

The structural formula for the amino acid, valine is shown below.

CHEMISTRY FOR TODAY+OWLV2  24 MO>IP<, Chapter 19, Problem 19.5E , additional homework tip  1

The chiral carbon atom in it is shown below.

CHEMISTRY FOR TODAY+OWLV2  24 MO>IP<, Chapter 19, Problem 19.5E , additional homework tip  2

The four different groups attached to the chiral carbon atom are circled as shown below.

CHEMISTRY FOR TODAY+OWLV2  24 MO>IP<, Chapter 19, Problem 19.5E , additional homework tip  3

Explanation of Solution

Amino acids are formed by an amine and a carboxylic acid attached to a carbon atom with a characteristic side chain. The carboxylic acid in amino acids is usually in an ionic form and therefore, it is known as carboxylate group.

The structure of valine is given below.

CHEMISTRY FOR TODAY+OWLV2  24 MO>IP<, Chapter 19, Problem 19.5E , additional homework tip  4

Figure 1

The chiral carbon atom in it is shown below.

CHEMISTRY FOR TODAY+OWLV2  24 MO>IP<, Chapter 19, Problem 19.5E , additional homework tip  5

Figure 2

The four different groups attached to the chiral carbon atom are circled as shown below.

CHEMISTRY FOR TODAY+OWLV2  24 MO>IP<, Chapter 19, Problem 19.5E , additional homework tip  6

Figure 3

Conclusion

The structural formula for the amino acid, valine is shown in Figure 1. The chiral carbon atom in it is shown in Figure 2. The four different groups attached to the chiral carbon atom are shown in Figure 3.

Expert Solution
Check Mark
Interpretation Introduction

(b)

Interpretation:

The structural formula for the amino acid, glutamate is to be drawn. The chiral carbon atom in it is to be identified. The four different groups attached to the chiral carbon atom are to be circled.

Concept introduction:

Amino acids are organic compounds which combine sequentially to generate a protein. They are known as the building blocks of the human body. The main elements present in amino acids are carbon, nitrogen and oxygen while the side chains attached to the chiral carbon atom contain other elements.

Answer to Problem 19.5E

The structural formula for the amino acid, glutamate is shown below.

CHEMISTRY FOR TODAY+OWLV2  24 MO>IP<, Chapter 19, Problem 19.5E , additional homework tip  7

The chiral carbon atom in it is shown below.

CHEMISTRY FOR TODAY+OWLV2  24 MO>IP<, Chapter 19, Problem 19.5E , additional homework tip  8

The four different groups attached to the chiral carbon atom are circled as shown below.

CHEMISTRY FOR TODAY+OWLV2  24 MO>IP<, Chapter 19, Problem 19.5E , additional homework tip  9

Explanation of Solution

Amino acids are formed by an amine and a carboxylic acid attached to a carbon atom with a characteristic side chain. The carboxylic acid in amino acids is usually in an ionic form and therefore, it is known as carboxylate group.

The structure of glutamate is given below.

CHEMISTRY FOR TODAY+OWLV2  24 MO>IP<, Chapter 19, Problem 19.5E , additional homework tip  10

Figure 4

The chiral carbon atom in it is shown below.

CHEMISTRY FOR TODAY+OWLV2  24 MO>IP<, Chapter 19, Problem 19.5E , additional homework tip  11

Figure 5

The four different groups attached to the chiral carbon atom are circled as shown below.

CHEMISTRY FOR TODAY+OWLV2  24 MO>IP<, Chapter 19, Problem 19.5E , additional homework tip  12

Figure 6

Conclusion

The structural formula for the amino acid, glutamate is shown in Figure 4. The chiral carbon atom in it is shown in Figure 5. The four different groups attached to the chiral carbon atom are shown in Figure 6.

Expert Solution
Check Mark
Interpretation Introduction

(c)

Interpretation:

The structural formula for the amino acid, aspargine is to be drawn. The chiral carbon atom in it is to be identified. The four different groups attached to the chiral carbon atom are to be circled.

Concept introduction:

Amino acids are organic compounds which combine sequentially to generate a protein. They are known as the building blocks of the human body. The main elements present in amino acids are carbon, nitrogen and oxygen while the side chains attached to the chiral carbon atom contain other elements.

Answer to Problem 19.5E

The structural formula for the amino acid, aspargine is shown below.

CHEMISTRY FOR TODAY+OWLV2  24 MO>IP<, Chapter 19, Problem 19.5E , additional homework tip  13

The chiral carbon atom in it is shown below.

CHEMISTRY FOR TODAY+OWLV2  24 MO>IP<, Chapter 19, Problem 19.5E , additional homework tip  14

The four different groups attached to the chiral carbon atom are circled as shown below.

CHEMISTRY FOR TODAY+OWLV2  24 MO>IP<, Chapter 19, Problem 19.5E , additional homework tip  15

Explanation of Solution

Amino acids are formed by an amine and a carboxylic acid attached to a carbon atom with a characteristic side chain. The carboxylic acid in amino acids is usually in an ionic form and therefore, it is known as carboxylate group.

The structure of aspargine is given below.

CHEMISTRY FOR TODAY+OWLV2  24 MO>IP<, Chapter 19, Problem 19.5E , additional homework tip  16

Figure 7

The chiral carbon atom in it is shown below.

CHEMISTRY FOR TODAY+OWLV2  24 MO>IP<, Chapter 19, Problem 19.5E , additional homework tip  17

Figure 8

The four different groups attached to the chiral carbon atom are circled as shown below.

CHEMISTRY FOR TODAY+OWLV2  24 MO>IP<, Chapter 19, Problem 19.5E , additional homework tip  18

Figure 9

Conclusion

The structural formula for the amino acid, aspargine is shown in Figure 7. The chiral carbon atom in it is shown in Figure 8. The four different groups attached to the chiral carbon atom are shown in Figure 9.

Expert Solution
Check Mark
Interpretation Introduction

(d)

Interpretation:

The structural formula for the amino acid, cysteine is to be drawn. The chiral carbon atom in it is to be identified. The four different groups attached to the chiral carbon atom are to be circled.

Concept introduction:

Amino acids are organic compounds which combine sequentially to generate a protein. They are known as the building blocks of the human body. The main elements present in amino acids are carbon, nitrogen and oxygen while the side chains attached to the chiral carbon atom contain other elements.

Answer to Problem 19.5E

The structural formula for the amino acid, cysteine is shown below.

CHEMISTRY FOR TODAY+OWLV2  24 MO>IP<, Chapter 19, Problem 19.5E , additional homework tip  19

The chiral carbon atom in it is shown below.

CHEMISTRY FOR TODAY+OWLV2  24 MO>IP<, Chapter 19, Problem 19.5E , additional homework tip  20

The four different groups attached to the chiral carbon atom are circled as shown below.

CHEMISTRY FOR TODAY+OWLV2  24 MO>IP<, Chapter 19, Problem 19.5E , additional homework tip  21

Explanation of Solution

Amino acids are formed by an amine and a carboxylic acid attached to a carbon atom with a characteristic side chain. The carboxylic acid in amino acids is usually in an ionic form and therefore, it is known as carboxylate group.

The structure of cysteine is given below.

CHEMISTRY FOR TODAY+OWLV2  24 MO>IP<, Chapter 19, Problem 19.5E , additional homework tip  22

Figure 10

The chiral carbon atom in it is shown below.

CHEMISTRY FOR TODAY+OWLV2  24 MO>IP<, Chapter 19, Problem 19.5E , additional homework tip  23

Figure 11

The four different groups attached to the chiral carbon atom are circled as shown below.

CHEMISTRY FOR TODAY+OWLV2  24 MO>IP<, Chapter 19, Problem 19.5E , additional homework tip  24

Figure 12

Conclusion

The structural formula for the amino acid, cysteine is shown in Figure 10. The chiral carbon atom in it is shown in Figure 11. The four different groups attached to the chiral carbon atom are shown in Figure 12.

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Chapter 19 Solutions

CHEMISTRY FOR TODAY+OWLV2 24 MO>IP<

Ch. 19 - Prob. 19.11ECh. 19 - Write structural formulas to show the form the...Ch. 19 - Write structural formulas to show the form of the...Ch. 19 - Write ionic equations to show how serine acts as a...Ch. 19 - Write two reactions to represent the formation of...Ch. 19 - Write a complete structural formula and an...Ch. 19 - Write a complete structural formula and an...Ch. 19 - Prob. 19.18ECh. 19 - Write abbreviated formulas for the six isomeric...Ch. 19 - Prob. 19.20ECh. 19 - How many tripeptide isomers that contain one...Ch. 19 - What special role does the amino acid cysteine...Ch. 19 - Prob. 19.23ECh. 19 - Explain why the presence of certain proteins in...Ch. 19 - Prob. 19.25ECh. 19 - Explain why a protein is least soluble in an...Ch. 19 - Prob. 19.27ECh. 19 - Prob. 19.28ECh. 19 - Classify each of the following proteins into one...Ch. 19 - For each of the following two proteins listed in...Ch. 19 - Prob. 19.31ECh. 19 - Differentiate between simple and conjugate...Ch. 19 - Give one example of a conjugated protein that...Ch. 19 - Prob. 19.34ECh. 19 - Prob. 19.35ECh. 19 - Write the structure for a protein backbone. Make...Ch. 19 - Prob. 19.37ECh. 19 - Prob. 19.38ECh. 19 - Prob. 19.39ECh. 19 - Prob. 19.40ECh. 19 - Which amino acids have side-chain groups that can...Ch. 19 - Prob. 19.42ECh. 19 - Prob. 19.43ECh. 19 - A globular protein in aqueous surroundings...Ch. 19 - What is meant by the term quaternary protein...Ch. 19 - What types of forces give rise to quaternary...Ch. 19 - Describe the quaternary protein structure of...Ch. 19 - Prob. 19.48ECh. 19 - Prob. 19.49ECh. 19 - Prob. 19.50ECh. 19 - As fish is cooked, the tissue changes from a soft...Ch. 19 - Prob. 19.52ECh. 19 - Prob. 19.53ECh. 19 - Once cooked, egg whites remain in a solid form....Ch. 19 - Prob. 19.55ECh. 19 - Prob. 19.56ECh. 19 - A protein has a molecular weight of about 12,000u....Ch. 19 - Which amino acids could be referred to as...Ch. 19 - Prob. 19.59ECh. 19 - Prob. 19.60ECh. 19 - Prob. 19.61ECh. 19 - Some researchers feel that the high experienced by...Ch. 19 - Prob. 19.63ECh. 19 - Prob. 19.64ECh. 19 - Prob. 19.65ECh. 19 - Prob. 19.66ECh. 19 - Why must the protein drug insulin be given by...Ch. 19 - Prob. 19.68ECh. 19 - Prob. 19.69ECh. 19 - Prob. 19.70ECh. 19 - Prob. 19.71ECh. 19 - What functional groups are found in all amino...Ch. 19 - Which of the following are true concerning the...Ch. 19 - Rank the following components of hemoglobin in...Ch. 19 - Describe the quaternary protein structure of...Ch. 19 - Complete degradation of a protein into individual...Ch. 19 - Which is NOT a characteristic of proteins? a. They...Ch. 19 - Which of the following describes the primary...
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